Plant growth-promoting rhizobacteria (PGPR) offer eco-friendly alternatives to chemical fertilizers, promoting sustainable agriculture by enhancing soil fertility, reducing pathogens, and aiding in stress resistance. In agriculture, they play a crucial role in plant growth promotion through the production of agroactive compounds and extracellular enzymes to promote plant health and protection against phytopathogens. In the rhizosphere, diverse microbial interactions, including those with bacteria and fungi, influence plant health by production of antimicrobial compounds. The antagonism displayed by rhizobacteria plays a crucial role in shaping microbial communities and has potential applications in developing a natural and environmentally friendly approach to pest control. The rhizospheric microbes showcase their ecological importance and potential for biotechnological applications in the context of plant-microbe interactions. The extracellular enzymes produced by rhizospheric microbes like amylases, chitinases, glucanases, cellulases, proteases, and ACC deaminase contribute to plant processes and stress response emphasizing their importance in sustainable agriculture. Moreover, this review highlights the new paradigm including artificial intelligence (AI) in sustainable horticulture and agriculture as a harmonious interaction between ecological networks for promoting soil health and microbial diversity that leads to a more robust and self-regulating agricultural system for protecting the environment in the future. Overall, this review emphasizes microbial interactions and the role of rhizospheric microbial extracellular enzymes which is crucial for developing eco-friendly approaches to enhance crop production and soil health.

No less than 60% of timber production in Peru’s natural forests is the result of informal or illegal extractive activities that, by definition, are not sustainable. This article aims to demonstrate that even legitimate timber, such as timber harvested in more than 6 million hectares of forest concessions, does not meet the basic requirements of sustainable forest management. Forestry legislation itself, which does not emphasize forest management, institutional weaknesses and the socioeconomic environment are the main causes. In addition, the cutting cycles and the authorized minimum diameters, among other practices, do not allow the renewal of the resource and increase its degradation.

In this study, robust and defect-free thin film composite (TFC) forward osmosis (FO) membranes have been successfully fabricated using ceramic hollow fibers as the substrate. Polydopamine (PDA) coating under controlled conditions is effective in reducing the surface pores of the substrate and making the substrate smooth enough for interfacial polymerization. The pure water permeability (A), solute permeability (B), and structural parameter (S) of the resultant FO membrane are 0.854 L·m^–2·h⁻¹·bar⁻¹ (LMH/Bar), 0.186 L·m^–2·h⁻¹ (LMH), and 1720 µm, respectively. The water flux and reverse draw solute flux are measured using NaCl and proprietary ferric sodium citrate (FeNaCA) draw solutions at low and high osmotic pressure ranges. As the osmotic pressure increases, a higher water flux is obtained, but its increase is not directly proportional to the increase in the osmotic pressure. At the membrane surface, the effect of dilutive concentration polarization is much less serious for FeNaCA-draw solutions. At an osmotic pressure of 89.6 bar, the developed TFC membrane generates water fluxes of 11.5 and 30.0 LMH using NaCl and synthesized FeNaCA draw solutions. The corresponding reverse draw solute flux is 7.0 g·m^–2·h⁻¹ (gMH) for NaCl draw solution, but it is not detectable for FeNaCA draw solution. This means that the developed TFC FO membranes are defect-free and their surface pores are at the molecular level. The performance of the developed TFC FO membranes is also demonstrated for the enrichment of BSA protein.

Smallholder paprika farmers in Zimbabwe contribute to local economies and food security but face supply chain challenges like limited market access and poor infrastructure which lead to post harvest losses and unpredictable prices. To survive, these farmers must adopt sustainable value networks to reduce operational costs and improve performance. This study sought to establish the effect of sustainable value networks on the operational performance of smallholder paprika farming in Zimbabwe. This study, using a positivist research philosophy and a quantitative approach, surveyed 288 smallholder paprika farmers in Zimbabwe. Exploratory factor analysis and partial least squares structural equation modelling were used to validate the constructs and test the hypothesised relationships. Results demonstrate a moderate level of implementation of value networks in smallholder paprika farming characterised by successes and challenges. The findings illustrated resource sharing among smallholder farmers, facilitated by initiatives, such as recycled seed exchanges and financial support through village savings and loan associations. However, results show that challenges persist, particularly with market access and financial support. Results indicate that there is a significant awareness and implementation of green supply chain management practices among smallholder paprika farmers even though they do not have access to resources and live in rural areas. The findings demonstrate that value networks significantly influence the adoption of green supply chain management practices, which in turn positively impact operational performance, environmental performance, and social performance. Green supply chain management practices were found to mediate the relationship between value networks and environmental performance, social performance, and operational performance, underlining the critical role of sustainable practices in enhancing performance outcomes. While environmental performance showed a positive effect on operational performance, the direct influence of social performance on operational performance was found to be statistically insignificant, suggesting the need for further exploration of the factors linking social benefits to operational efficiency. The research contributes to both theory and practice by presenting a sustainable value network model for smallholder paprika farmers, integrating value network, green supply chain management practices and environmental performance to enhance operational performance. Practical implications include policy recommendations to strengthen collaboration between smallholder farmers and other stakeholdersand address power imbalances with intermediaries. Future research should extend the study to other agricultural sectors and incorporate more diverse stakeholder perspectives to validate and generalise the proposed sustainable value network model.

Twenty-two tomato (Solanum lycopersicum L.) genotypes were examined for correlation and path analysis in the randomized block design under open field conditions. Total fruit yield showed a significant positive correlation with the number of fruits per plant, average fruit weight, lycopene content, and percent seedling survival in the field at both the genotypic and phenotypic levels. A strong correlation between these characters revealed that selection based on these characters would consequently improve the total fruit yield. Path analysis showed that the number of fruits per plant, average fruit weight, percent seedling survival in the nursery, and number of locules per fruit exhibited high positive direct phenotypic effects on total fruit yield, whereas the number of fruits per plant, average fruit weight, percent seedling survival in the field, and pollen viability had very high positive direct genotypic effects. Therefore, to increase the yield, it would be profitable to prioritize these traits in the selection program.

This comprehensive review explores the forefront of nanohybrid materials, focusing on the integration of coordination materials in various applications, with a spotlight on their role in the development of flexible solar cells. Coordination material-based nanohybrids, characterized by their unique properties and multifunctionality, have garnered significant attention in fields ranging from catalysis and sensing to drug delivery and energy storage. The discussion investigates the synthesis methods, properties, and potential applications of these nanohybrids, underscoring their versatility in materials science. Additionally, the review investigates the integration of coordination nanohybrids in perovskite solar cells (PSCs), showcasing their ability to enhance the performance and stability of next-generation photovoltaic devices. The narrative further expands to encompass the synthesis of luminescent nanohybrids for bioimaging purposes and the development of layered, two-dimensional (2D) material-based nanostructured hybrids for energy storage and conversion. The exploration culminates in an examination of the synthesis of conductive polymer nanostructures, elucidating their potential in drug delivery systems. Last but not least, the article discusses the cutting-edge realm of flexible solar cells, emphasizing their adaptability and lightweight design. Through a systematic examination of these diverse nanohybrid materials, this review sheds light on the current state of the art, challenges, and prospects, providing valuable insights for researchers and practitioners in the fields of materials science, nanotechnology, and renewable energy.