Our environment has been significantly impacted by man-made pollutants, primarily due to industries making substantial use of synthetic chemicals, resulting in significant environmental consequences. In this research investigation, the co-precipitation approach was employed for the synthesis of cellulose-based ferric oxide (Fe₂O₃/cellulose) and copper oxide nanoparticles (CuO_x-NPs). Scanning electron microscopy (SEM) analyses were conducted to determine the properties of the newly synthesised nanoparticles. Furthermore, the synthesized nanoparticles were employed for eliminating chromium from aqueous media under various conditions, including temperature, contact time, adsorbent concentration, adsorbate concentration, and pH. Additionally, the synthesised materials were used to recover Cr(VI) ions from real samples, including tap water, seawater, and industrial water, and the adsorptive capacity of both materials was evaluated under optimal conditions. The synthesis of Fe₂O₃/cellulose and CuO_x-NPs proved to be effective, as indicated by the outcomes of the study. 

In recent years, using novel nanomaterials to improve the antifouling and antibacterial performance of reverse osmosis membranes has received much attention. In this study, hydrophilic Ag@ZnO-hyperbranched polyglycerols nanoparticles were fabricated by ring-opening multibranched polymerization of glycidyl acid with the core-shell Ag@ZnO nanoparticles. The cellulose triacetate composite membranes were prepared by grafting Ag@ZnO-HPGs nanoparticles on the surface of cellulose triacetate membranes. The surface of the nanoparticles with active functional group –OH was confirmed by X-ray photoelectron spectroscopy and Fourier transform infrared spectroscopy. Surface morphology, charge, and hydrophilicity of the composite membranes were characterized by scanning electron microscope, zeta potential, and contact angle analysis. The results showed that grafting the Ag@ZnO-HPGs nanoparticles onto the cellulose triacetate membrane surface improved the physical and chemical properties of the cellulose triacetate composite membranes. The water flux of cellulose triacetate composite membranes increased while the salt rejection rate to NaCl slightly decreased. Meanwhile, the cellulose triacetate composite membranes showed excellent antifouling properties of having a high flux recovery. The antibacterial performance of the cellulose triacetate composite membrane against E. coli and S. aureus was prominent that the antibacterial rates were 99.50% and 92.38%, and bacterial adhesion rates were as low as 19.12% and 21.35%, respectively.

With the increasing call for sustainable development, cities’ demand for green innovation has also been growing. However, relatively little research summarizes the influencing factors of urban green innovation. In this study, we conducted a visual analysis of 1193 research articles on green innovation in cities from the Web of Science core database using bibliometrics and visualization analysis. By analyzing co-occurrence, co-citation, and high-frequency keywords in the literature, we explored the current research status and development trends of influencing factors of urban green innovation and summarized the research in this field. The study found that collaboration among authors and institutions in this field needs to be strengthened to a certain extent. In addition, the study identified the research hotspots and frontiers in the field of urban green innovation, including “management”, “diffusion”, “smart city”, “indicator”, “sustainable city”, “governance”, and “environmental regulation”. Among them, “management”, “governance”, “indicator”, and “internet” are the research frontiers in this field, which are expected to have profound impacts on the future development of urban green innovation. The co-citation analysis results found that China has the highest research output in this field, followed by the United States, England, Australia, and Italy. In conclusion, this study uses CiteSpace software to identify important influencing factors and development trends of urban green innovation. Urban green innovation has gradually become a norm for social and collective behavior in the process of concretization, interdisciplinary development, and technological innovation. These findings have important reference value for promoting research and practice of urban green innovation.

The landlocked and fragile countries’ ability to create a sustainable path to economic growth and poverty reduction is inextricably linked to their export diversification potential, itself related to their connectivity within themselves, in the region, and other external markets. Mali, Chad, and Niger are first challenged by their geography—their landlocked nature with their vast and thinly populated space serves to isolate the most vulnerable communities from external and internal markets. Adding to these geographic disadvantages non-landlocked is incentive environment—defined by high and variable customs common external tariff regimes resulting from multiple overlapping regional trade arrangements—places a wedge between domestic and international prices, provides a disincentive to exports in favor of non-tradable and domestic-oriented sectors. By bringing greater coherence and convergence between the many common external tariff regimes in operation and the rationalization of their structures, and improving connectivity within and between markets, Mali, Chad, Niger, and Guinea can better promote the reallocation of resources toward tradable goods and services, putting the countries on a path toward greater economic inclusion and sustainable growth.