The semiclassical boron–boron interatomic pair potential is constructed in an integral form allowing its converting into the analytical one. It is an ab initio B–B potential free of any semiempirical adjusting parameters, which would serve as an effective tool for the theoretical characterization of all-boron and boron-rich nanomaterials.
Knowledge of the state of fragmentation and transformation of a forested landscape is crucial for proper planning and biodiversity conservation. Chile is one of the world’s biodiversity hotspots; within it is the Nahuelbuta mountain range, which is considered an area of high biodiversity value and intense anthropic pressure. Despite this, there is no precise information on the degree of transformation of its landscape and its conservation status. The objective of this work was to evaluate the state of the landscape and the spatio-temporal changes of the native forests in this mountain range. Using Landsat images from 1986 and 2011, thematic maps of land use were generated. A 33% loss of native forest in 25 years was observed, mainly associated to the substitution by forest plantations. Changes in the spatial patterns of land cover and land use reveal a profound transformation of the landscape and advanced fragmentation of forests. We discuss how these patterns of change threaten the persistence of several endemic species at high risk of extinction. If these anthropogenic processes continue, these species could face an increased risk of extinction.
In the process of seeking sustainable development, enterprises have chosen international business strategy. The purpose of this study is to examine the relationship between the degree of internationalization of Chinese listed firms and financial reporting quality, as well as whether audit committees can moderate the impact of enterprise internationalization on financial reporting quality. The empirical analysis results of Chinese listed manufacturing firms from 2014 to 2018 show that: the degree of corporate internationalization has a significant U-shaped relationship with earnings management. This new finding solves the problem that scholars have inconsistent views on the internationalization of enterprises and the quality of financial reporting. The study also found that audit committees with experience working in accounting firms can inhibit firm earnings management behavior in the early stage of internationalization; audit committees with experience working overseas can inhibit firm earnings management behavior in the later stage of internationalization; the higher the remuneration of audit committee experts, the more it can inhibit firm earnings management behavior in the early stage of internationalization. In the later stage of internationalization, the higher the remuneration of audit committee experts, it helps the earnings management behavior of firms. This provides new evidence on the functioning of the audit committee’s role; however, the independence of the audit committee and the proportion of financial experts do not have a significant effect on the inhibition of earnings management.
In recent years, using novel nanomaterials to improve the antifouling and antibacterial performance of reverse osmosis membranes has received much attention. In this study, hydrophilic Ag@ZnO-hyperbranched polyglycerols nanoparticles were fabricated by ring-opening multibranched polymerization of glycidyl acid with the core-shell Ag@ZnO nanoparticles. The cellulose triacetate composite membranes were prepared by grafting Ag@ZnO-HPGs nanoparticles on the surface of cellulose triacetate membranes. The surface of the nanoparticles with active functional group –OH was confirmed by X-ray photoelectron spectroscopy and Fourier transform infrared spectroscopy. Surface morphology, charge, and hydrophilicity of the composite membranes were characterized by scanning electron microscope, zeta potential, and contact angle analysis. The results showed that grafting the Ag@ZnO-HPGs nanoparticles onto the cellulose triacetate membrane surface improved the physical and chemical properties of the cellulose triacetate composite membranes. The water flux of cellulose triacetate composite membranes increased while the salt rejection rate to NaCl slightly decreased. Meanwhile, the cellulose triacetate composite membranes showed excellent antifouling properties of having a high flux recovery. The antibacterial performance of the cellulose triacetate composite membrane against E. coli and S. aureus was prominent that the antibacterial rates were 99.50% and 92.38%, and bacterial adhesion rates were as low as 19.12% and 21.35%, respectively.
The use of different energy sources and the worry of running out of some of them in the modern world have made factors such as environmental pollution and even energy sustainability vital. Vital resources for humanity include water, environment, food, and energy. As a result, building strong trust in these resources is crucial because of their interconnected nature. Sustainability in security of energy, water and food, generally decreases costs and improves durability. This study introduces and describes the components of a system named “Desktop Energetic Dark Greenhouse” in the context of the quadruple nexus of water, environment, food, and energy in urban life. This solution can concurrently serve to strengthen the sustainable security of water, environment, food, and energy. For home productivity, a small-scale version of this project was completed. The costs and revenues for this system have been determined after conducting an economic study from the viewpoints of the investor and the average household. The findings indicate that the capital return period is around five years from the investor’s perspective. The capital return on investment for this system is less than 4 years from the standpoint of the households. According to the estimates, this system annually supplies about 20 kg of vegetables or herbs, which means about one third of the annual needs of a family.
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