Adsorption is a widely used method for the treatment of dissolved contaminants. Various agro-industrial wastes have been explored as potential adsorbents, showing high efficiency in dye removal. Each adsorbate-adsorbent pair needs kinetic, and equilibrium models to scale up this process. In this work, the equilibrium, kinetics and thermodynamics of the corn Tuza-Red 40 system were evaluated under batch system at ph = 2.0 at temperatures of 25, 40, and 55 °C. The Langmuir, Freundlich and Temkin models were selected for the isotherm representation, while the Lagergren, Ho, and Elovich equations for the kinetics of the process. The Freundlich model presented the best fit to the isotherms, the adsorption kinetics was best described by the Ho equation, and the values for Gibbs free energy and entropy indicated the spontaneity and feasibility of the process.

Shore line change is considered as one of the most dynamic processes, which were mapped along the coast of Tiruvallur district by using topographic maps of 1976 and multi-temporal satellite images. The satellite images pertaining to 1988, 1991, 2006, 2010, 2013 and 2016 were used to extract the shorelines. It is important to map and monitor the HTL (High Tide Line) at frequent time intervals as the shoreline was demarcated by using visual interpretation technique from satellite images and topographic maps. Followed by this, an overlay analysis was performed to calculate areas of erosion and accretion in the study area. The results revealed that the coast of Tiruvallur district lost 603 ha and gained 630 ha due to erosion and accretion respectively. It was confirmed after the ground truth survey carried out in the study area. The high accretion of 178 ha was found nearby Pulicat Lake and low accretion of 19 ha was seen between Pulicat Lake and Kattupali Port. The high erosion area was found along the Pulicat Lake, Kattupali and Ennore ports, and Ennore creek mouth and southern Ennore such as Periya Kuppam, Chinna Kuppam, Kasi Koil Kuppam, and Thyagarajapuram. It may be concluded that the coastal erosion and accretion in the study area were mainly caused by anthropogenic and natural factors, which altered the coastal environment.

The nylon 66/nano-CaCO3 composites were prepared by melt blending on a twin-screw extruder. Scanning electron microscopy (SEM), polarized light microscopy (PLM), thermal loss (TGA) and differential scanning calorimetry (DSC) The effects of nanometer calcium carbonate on the polycrystalline behavior and thermal properties of nylon 66/nano CaCO3 composites were investigated. The results show that the nanometer calcium carbonate particles are dispersed in the nylon 66 matrix and exist in the form of aggregates. The nanometer calcium carbonate has the effect of heterogeneous nucleation, which can reduce the size of the spherules. The decomposition temperature of the nylon 66 is 400 ℃, the addition of nano-CaCO3 to reduce the decomposition temperature. At the same time, DSC test showed that the β-crystalline form in the material reduced the melting temperature of the material. The addition of nano-CaCO3 in the nylon 66 matrix resulted in the decrease of the crystallization temperature and the increase of the half-height width of the endothermic peak. The lower the crystallization temperature, the wider the crystallization temperature range.

This research focused on the design and implementation of the flipped classroom approach for higher mathematics courses in medical colleges. Out of 120 students, 60 were assigned to the experimental group and 60 to the control group. In the continuous assessment, which included homework and quizzes, the average score of the experimental group was 85.5 ± 5.5, while that of the control group was 75.2 ± 8.1 (P < 0.05). For the final examination, the average score in the experimental group was 88.3 ± 6.2, compared to 78.1 ± 7.3 in the control group (P < 0.01). The participation rate of students in the experimental group was 80.5%, significantly higher than the 50.3% in the control group (P < 0.001). Regarding autonomous learning ability, the experimental group spent an average of 3.2 hours per week on self-study, compared to 1.5 hours in the control group (P < 0.005). Other potential evaluation indicators could involve the percentage of students achieving high scores (90% or above) in problem-solving tasks (25.8% in the experimental group vs. 10.3% in the control group, P < 0.05), and the improvement in retention of key concepts after one month (70.2% in the experimental group vs. 40.5% in the control group, P < 0.01). In conclusion, the flipped classroom approach holds substantial promise in elevating the learning efficacy of higher mathematics courses within medical colleges, offering valuable insights for educational innovation and improvement.