Synthesis and structural-chemical studies of adduct of coordination supramolecular porous polymer hexaaquatribenzene-1,2,4,5-tetracarbonato-tetrairon(III) with dipyridyl

Usubaliyev Beybala Taji ,Taghiyev D. B. ,Munshiyeva M. K. ,Aliyeva G. M. ,Aliyeva F. B. ,Rzayeva A. K. ,Hasanova M. M. ,Safarova P. S. ,Mammadova G. Z.

doi:10.24294/jpse.v4i1.894

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Synthesis and structural-chemical studies of adduct of coordination supramolecular porous polymer hexaaquatribenzene-1,2,4,5-tetracarbonato-tetrairon(III) with dipyridyl

Usubaliyev Beybala Taji

Taghiyev D. B.

Munshiyeva M. K.

Aliyeva G. M.

Aliyeva F. B.

Rzayeva A. K.

Hasanova M. M.

Safarova P. S.

Mammadova G. Z.

Journal of Polymer Science and Engineering 2021, 4(1); https://doi.org/10.24294/jpse.v4i1.894

Submitted：11 Jun 2018

Accepted：22 Jun 2018

Published：16 Dec 2021

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Abstract

An α, α^′-dipyridyl adduct of a complex compound hexaaquatribenzene-1,2,4,5-tetracarbonatotetra iron (III) with porous structure was synthesized for the first time. According to the results of elemental, X-ray, IR-spectroscopic and differential-thermal analyses the individuality, chemical formula, thermal destruction, and form of coordination of acidic anion and dipyridyl were established. During interaction of a complex compound with dipyridyl, it completely loses all crystallization molecule of water resulting in a compound with a chemical formula of Fe₄(C₆H₂(COO)₄)₃(dpy)₂(dipyridyl). Using the identification of diffraction pattern the parameters of lattice cell of the complex compound were determined.

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References

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