Cobalt-based sulfides have emerged as promising candidates for next-generation high-performance anode materials for lithium-ion batteries (LIBs) due to their high theoretical specific capacity and reversible conversion reaction mechanisms. However, their practical application is hindered by volume expansion effects and relatively low rate performance. Guided by theoretical principles, this study synthesizes nanoscale Bi/CoS-C and Bi/Co4S3-C (denoted as Bi/CS-C) composite materials using Co and Bi2S3 as precursors via a solid-state ball milling method. The electrochemical properties of these materials were systematically investigated. When employed as anodes for LIBs, Bi/CoS-C and Bi/CS-C exhibit excellent rate capabilities. At current densities of 0.1, 0.5, 1, 4, and 10 A/g, the reversible capacities of Bi/CoS-C were 939.2, 730.7, 655.6, 508.1, and 319 mAh/g, respectively. In contrast, Bi/CS-C exhibited reversible capacities of 760.4, 637.6, 591.9, 484.3, and 295.4 mAh/g, respectively. Moreover, Co4S3, as an active component, enables superior long-cycle performance compared to CoS. After 300 cycles at 0.2 A/g, the Bi/CoS-C and Bi/CS-C electrodes retained capacities of 193.1 and 788.8 mAh/g, respectively. This study demonstrates that nanostructure design and carbon-based composite materials can effectively mitigate the volume expansion issue of cobalt-based sulfides, thereby enhancing their rate performance and cycling stability. This strategy provides new insights for the development of high-performance anode materials for lithium-ion batteries and is expected to accelerate their practical application in next-generation energy storage devices.
Nanoscale zero-valent iron (nZVI) is thought to be the most effective remediation material for contaminated soil, especially when it comes to heavy metal pollutants. In the current high-industrial and technologically advanced period, water pollution has emerged as one of the most significant causes for concern. In this instance, silica was coated with zero-valent iron nanoparticles at 650 and 800 ℃. Ferric iron with various counter-ions, nitrate (FN) and chloride (FC), and sodium borohydride as a reducing agent were used to create nanoscale zero-valent iron in an ethanol medium with nitrogen ambient conditions. X-ray diffraction (XRD) and field emission scanning electron microscopy (FE-SEM) techniques were employed to describe the structures of the generated zero-valent iron nanoparticles. Further, we investigated the electrical properties and adsorption characteristics of dyes such as alizarin red in an aqueous medium. As a result, zero-valent nano iron (nZVI), a core-shell environmental functional material, has found extensive application in environmental cleanup. The knowledge in this work will be useful for nZVI-related future research and real-world applications.
A fresh interest has been accorded to metal iodides due to their fascinating physicochemical properties such as high ionic conductivity, variable optical properties, and high thermal stabilities in making micro and macro devices. Breakthroughs in cathodic preparation and metallization of metal iodides revealed new opportunities for using these compounds in various fields, especially in energy conversion and materials with luminescent and sensory properties. In energy storage metal iodides are being looked at due to their potential to enhance battery performance, in optoelectronics the property of the metal iodides is available to create efficient LEDs and solar cells. Further, their application in sensing devices, especially in environmental and medical monitoring has been quite mentioned due to their response towards environmental changes such as heat or light. Nevertheless, some challenges are still in question, including material stability, scale-up opportunities, and compatibility with other technologies. This work highlights the groundbreaking potential of metal iodide-based nanomaterials, emphasizing their transformative role in innovation and their promise for future advancements.
Using the Intercultural Competence and Inclusion in Education Scale (ICIES), this study examines variations in intercultural competence and inclusion between mainstream and multiethnic high schools. The sample consisted of 384 high school students, aged 17 to 18, from both rural and urban areas in Western Romania, enrolled in grades 11 and 12. The ICIES demonstrated strong reliability, with a Cronbach’s alpha of 0.721. Exploratory factor analysis revealed three distinct dimensions: Intercultural opportunities and activities, Comfort in diverse settings, and Cultural reflection and values. Independent samples t-tests identified significant differences between mainstream and multiethnic schools across several items, with students in multiethnic schools reporting higher levels of intercultural competence and inclusion. These findings highlight the critical role of multicultural educational settings in fostering students’ cultural awareness and inclusive attitudes. This study provides actionable insights for enhancing multicultural education practices and policies, including teacher training programs, inclusive curricula, and extracurricular initiatives that promote intercultural engagement and reduce intergroup biases.
Since 2013, the state has introduced a number of policies to strictly control the number and scale of public hospitals and to control the rapid expansion of public hospitals. After the introduction of this series of policies, the number of public hospitals in China did not continue to grow, but the number of beds in public hospitals continued to grow. This paper uses difference-in-difference (DID) method to analyze the number of public hospitals with the corresponding data of the development of private hospitals after the introduction of the policy, and the results proves that the introduction of relevant policies has an impact on the number of public hospitals, but has a limited impact on the expansion of the scale of public hospitals. At the end of the article, positive policy suggestions are given to the development of hospitals in China, such as controlling the expansion of public hospitals, strictly controlling the number of beds in public hospitals, and vigorously developing private hospitals. Promoting the development of private hospitals is an important economic supplement to China’s health care.
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