Water splitting has gained significant attention as a means to produce clean and sustainable hydrogen fuel through the electrochemical or photoelectrochemical decomposition of water. Efficient and cost-effective water splitting requires the development of highly active and stable catalysts for the oxygen evolution reaction (OER) and hydrogen evolution reaction (HER). Carbon nanomaterials, including carbon nanotubes, graphene, and carbon nanofibers, etc., have emerged as promising candidates for catalyzing these reactions due to their unique properties, such as high surface area, excellent electrical conductivity, and chemical stability. This review article provides an overview of recent advancements in the utilization of carbon nanomaterials as catalysts or catalyst supports for the OER and HER in water splitting. It discusses various strategies employed to enhance the catalytic activity and stability of carbon nanomaterials, such as surface functionalization, hybridization with other active materials, and optimization of nanostructure and morphology. The influence of carbon nanomaterial properties, such as defect density, doping, and surface chemistry, on electrochemical performance is also explored. Furthermore, the article highlights the challenges and opportunities in the field, including scalability, long-term stability, and integration of carbon nanomaterials into practical water splitting devices. Overall, carbon nanomaterials show great potential for advancing the field of water splitting and enabling the realization of efficient and sustainable hydrogen production.
Banana (Musa spp.) productivity is limited by sodic soils, which impairs root growth and nutrient uptake. Analyzing root traits under stress conditions can aid in identifying tolerant genotypes. This study investigates the root morphological traits of banana cultivars under sodic soil stress conditions using Rhizovision software. The pot culture experiment was laid out in a Completely Randomized Design (CRD) under open field conditions, with treatments comprising the following varieties: Poovan (AAB), Udhayam (ABB), Karpooravalli (ABB), CO 3 (ABB), Kaveri Saba (ABB), Kaveri Kalki (ABB), Kaveri Haritha (ABB), Monthan (ABB), Nendran (AAB), and Rasthali (AAB), each replicated thrice. Parameters such as the number of roots, root tips, diameter, surface area, perimeter, and volume were assessed to evaluate the performance of different cultivars. The findings reveal that Karpooravali and Udhayam cultivars exhibited superior performance in terms of root morphology compared to other cultivars under sodic soil stress. These cultivars displayed increased root proliferation, elongation, and surface area, indicating their resilience to sodic soil stress. The utilization of Rhizovision software facilitated precise measurement and analysis of root traits, providing valuable insights into the adaptation mechanisms of banana cultivars to adverse soil conditions.
BiVO4 was hydrothermally synthesized under different preparing conditions and characterized by XRD, SEM, Raman spectrum and BET specific surface area. The influence of different pH value and annealing temperature and hydrothermal time on the morphologies and structures of the BiVO4 samples was investigated systematically. It can be found that annealing would eliminate the effects caused by the pH of precursor, heating temperature and heating time, but preparing conditions still influenced the size and specific surface area of samples. Furthermore, the photocatalytic activities of the fabricated BiVO4 were also evaluated by the degradation of methyl blue in aqueous solution under UV and visible light irradiation.
This study examined the impact of aluminium doping on the structural, electrical, and magnetic properties of Li(0.5)Co(0.75)AlxFe(2−x)O4 spinel ferrites (x =0.15 to 0.60). The samples were synthesised using the sol-gel auto-combustion technique, and they were examined using X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FTIR), dielectric measurements, and vibrating sample magnetometry (VSM). All samples possessed a single-phase cubic spinel structure with Fd-3m space group, according to XRD analyses. SEM images showed the creation of homogeneous particles with an average size of about 21 nm. All samples had spinel ferrite phases, confirmed from FTIR spectra. DC electrical conductivity studies showed that the conductivity increased with increasing aluminium content up to x = 0.45 before dropping at x = 0.60. The maximum saturation magnetization value was found at x = 0.45, according to VSM measurements, which demonstrated that the magnetic characteristics were strongly correlated with the amount of aluminium.
The Guacimal River catchment has an area of 181 km2 and is located in the NW of Costa Rica, between the coordinates 84.745° W-10.016° N and 84.909° W-10.325° N. In this territory, as in most of the country, detailed geomorphological studies are scarce; therefore, the objective of this paper is to present the geomorphological mapping at a scale of 1:25,000 of the Guacimal River, which allows us to explain the dynamics of the agents involved in the modeling of the catchment. The work methodology consisted of three stages: pre-mapping, field activity and post-mapping, which resulted in a map in which ten relief forms are represented, ordered according to their morphogenesis in endogenous modeled and exogenous (fluvial, gravitational and littoral). This document will be the base line for land use planning, both continental and coastal, and for local risk management.
The electrospinning precursor solution was prepared by dissolving polyvinyl pyrrolidone as template, tetrabutyl titanate as titanium source, and acetic acid as inhibitor. The TiO2 nanofilms were prepared by precursor solution electrospinning and subsequent calcination. Thermal gravimetric analysis (TG), scanning electron microscopy (SEM), X-ray powder diffraction (XRD), and transmission electron microscopy (TEM) were used to characterize and analyze the samples. The influence of technological parameters on spinning fiber morphology was also studied. The results indicate that the TiO2 nanofibers morphology is good when the parameters are as follows: voltage 1.4×104 V,spinning distance 0.2 m,translational velocity 2.5×10-3 m·s-1, flow rate 3×10-4 m·s-1, and needle diameter 3×10-4 m. The diameter of the fibers is about 150 nm. With the 1×10-4 mol·L-1 methylene blue solution used as simulated degradation target, the degradation rate is 95.8% after 180 minutes.
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