The current manuscript overviews the potential of inimitable zero dimensional carbon nanoentities, i.e., nanodiamonds, in the form of hybrid nanostructures with allied nanocarbons such as graphene and carbon nanotube. Accordingly, two major categories of hybrid nanodiamond nanoadditives have been examined for nanocompositing, including nanodiamond-graphene or nanodiamond/graphene oxide and nanodiamond/carbon nanotubes. These exceptional nanodiamond derived bifunctional nanocarbon nanostructures depicted valuable structural and physical attributes (morphology, electrical, mechanical, thermal, etc.) owing to the combination of intrinsic features of nanodiamonds with other nanocarbons. Consequently, as per literature reported so far, noteworthy multifunctional hybrid nanodiamond-graphene, nanodiamond/graphene oxide, and nanodiamond/carbon nanotube nanoadditives have been argued for characteristics and potential advantages. Particularly, these nanodiamond derived hybrid nanoparticles based nanomaterials seem deployable in the fields of electromagnetic radiation shielding, electronic devices like field effect transistors, energy storing maneuvers namely supercapacitors, and biomedical utilizations for wound healing, tissue engineering, biosensing, etc. Nonetheless, restricted research traced up till now on hybrid nanodiamond-graphene and nanodiamond/carbon nanotube based nanocomposites, therefore, future research appears necessary for further precise design varieties, large scale processing, and advanced technological progresses.
With modern society and the ever-increasing consumption of polymeric materials, the way we look at products has changed, and one of the main questions we have is about the negative impacts caused to the environment in the most diverse stages of the life cycle of these materials, whether in the acquisition of raw materials, in manufacturing, distribution, use or even in their final disposal. The main methodology currently used to assess the environmental impacts of products from their origin to their final disposal is known as Life Cycle Assessment (LCA). Thus, the objective of this work is to evaluate how much the biodegradable polymer contributes to the environment in relation to the conventional polymer considering the application of LCA in the production mode. This analysis is configured through the Systematic Literature Review (SLR) method. In this review, 28 studies were selected for evaluation, whose approaches encompass knowledge on LCA, green biopolymer (from a renewable but non-biodegradable source), conventional polymer (from a non-renewable source) and, mainly, the benefits of using biodegradable polymers produced from renewable sources, such as: corn, sugarcane, cellulose, chitin and others. Based on the surveys, a comparative analysis of LCA applications was made, whose studies considered evaluating quantitative results in the application of LCA, in biodegradable and conventional polymers. The results, based on comparisons between extraction and production of biodegradable polymers in relation to conventional polymers, indicate greater environmental benefits related to the use of biodegradable polymers.
The history of organic polymers is a remarkable journey from the discovery of natural materials like rubber and silk to the development of sophisticated synthetic polymers that have transformed industries and modern life. This comprehensive review article presents a detailed account of the evolution of organic polymers. It begins with the early uses of natural polymers and explores key breakthroughs, including the invention of Bakelite, nylon, and neoprene. The theoretical foundations of polymer science, laid by Hermann Staudinger, are discussed, and the post-war surge in polymer development is examined, including the introduction of polyethylene, polypropylene, and PVC. Notable advances in polymer chemistry, such as isotactic polypropylene and silicone polymers, are highlighted. The article also delves into the development of high-performance polymers like Kevlar and carbon-based materials, offering insights into their applications. Moreover, it discusses the current trends in polymer science, emphasizing sustainability and biodegradability. As the world continues to rely on polymers for numerous applications, this review provides a historical perspective and a glimpse into the future of organic polymers, where innovations are expected to shape various aspects of technology, healthcare, and environmental protection.
New telechelic polymers functionalized with terminal ethyl xanthate or vinyl groups were synthesized via cationic ring-opening polymerization (CROP). The polymerization of 2-ethyl-2-oxazoline (Etoxa) and 2-methoxycarbonylethyl-2-oxazoline (Esteroxa) was initiated by 1,4-trans-dibromobutene in acetonitrile at 78 ℃, with termination using either potassium ethyl xanthate or 4-vinylbenzyl-piperazine. Structural characterization by 1H and 13C NMR and FTIR spectroscopy confirmed the telechelic architecture. 1H NMR analysis revealed degrees of polymerization (DP) of 24–29 for ethyl xanthate-terminated polymers and 22–23 for vinyl-terminated polymers, consistent with theoretical values. The molar compositions of Etoxa and Esteroxa in all telechelic polymers matched the initial monomer feed ratios. End-group functionalization efficiency was quantified as follows: Ethyl xanthate-terminated polymers: 64%–82%, and vinyl-terminated polymers: 69% and 98% (for respective batches).
Recent technological advances in the fields of biomaterials and tissue engineering have spurred interest in biopolymers for various biomedical applications. The advantage of biopolymers is their favorable characteristics for these applications, among which proteins are of particular importance. Proteins are explored widely for 3D bioprinting and tissue engineering applications, wound healing, drug delivery systems, implants, etc., and the proteins mainly available include collagen, gelatin, albumin, zein, etc. Zein is a plant protein abundantly present in corn endosperm, and it is about 80% of total corn protein. It is a highly renewable source, and zein has been reported to be applicable in different industrial applications. Lately, it has gained attention in biomedical applications. This research interest in zein is on account of its biocompatibility, non-toxicity, and certain unique physico-chemical properties. Zein comes under the GRAS category and is considered safe for biomedical applications. The hydrophobic nature of this protein gives it an added advantage and has wider applications in drug delivery. This review focuses on details about zein protein, its properties, and potential applications in biomedical sectors.
Fungi can be used to remove or degrade polluting compounds through a mycoremediation process. Sometimes even more efficiently than prokaryotes, they can therefore be used to combat pollution from non-biodegradable polymers. Cellulose acetate is a commonly used material in the manufacture of cigarette butts, so when discarded, it generates pollution. The fungus Pleurotus ostreatus has the ability to degrade cellulose acetate through the enzymes it secretes. The enzyme hydrolyzes the acetyl group of cellulose acetate, while cellulolytic enzymes degrade the cellulose backbone into sugars, polysaccharides, or cellobiose. In addition to cellulose acetate, this fungus is capable of degrading other conventionally non-biodegradable polymers, so it has the potential to be used to reduce pollution. Large-scale cultivation of the fungus has proven to be more economically viable than conventional methods for treating non-biodegradable polymers, which is an additional advantage.
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