For five different regions in Kırklareli province, heavy metals; such as Pb, Ni, Cu, Mn, Cd, Cr, Co, Zn, Mo, and Fe in the mixture of leaves and flowers from linden trees (Tilia tomentosa L.) were analyzed by using flame atomic absorption spectroscopy after the samples were dissolved with microwave method. Also, organochloride pesticides; such as ∑BHC: [α-BHC, β-BHC, γ-BHC, and δ-BHC], ∑DDT: [4,4’-DDD, 4,4’-DDE, and 4,4’-DDT], α-Endosulfan, β-Endosulfan, Endosulfan sulfate, Heptachlor, Heptachlor-endo-epoxide, Aldrin, Dieldrin, Endrin aldehyde, Endrin ketone, Endrin and Methoxychlor in these samples were determined by utilizing gas chromatography mass spectroscopy after the samples were prepared for analyses by using QuEChERS method. The metal concentrations in the samples were in the range of 45.3 to 268 mg/kg for Mn, 0.25 to 18.8 mg/kg for Cu, 11.5 to 46.1 mg/kg for Zn, 128 to 1310 mg/kg for Fe, 10.4 to 38.6 mg/kg for Mo, 0.82 to 1.34 mg/kg for Cd, 0 to 6.45 mg/kg for Ni, 0 to 19.2 mg/kg for Pb, and 0 to 8.25 mg/kg for Cr. Moreover, the concentrations of organochloride pesticides in samples were usually determined to be lower than their maximum residue level values given the pesticide residue limit regulation of Turkish Food Codex.
The performance of five cauliflower cultivars in conventional and alternative phytosanitary management—without the use of synthetic pesticides—was evaluated. Two experiments were conducted at Epagri, Ituporanga Experimental Station in February 2018 and 2019. A randomized block design with four repetitions was adopted, with twenty plants of each cultivar as plots. The seedlings were transplanted on millet and mucuna straw at a spacing of 0.5 m × 0.8 m. We evaluated agronomic yield, inflorescence quality, pest damage and plant diseases, especially bacterial and fungal rots. The cauliflower hybrids Vera, Verona and Serena stood out in productivity and quality, being the most indicated for sowing in off-season crops, in the Alto Vale do Itajaí region. The most productive cultivars were less damaged by bacterial diseases and defoliating caterpillars and without interference of whitefly infestation on yield. The results also reveal that it is possible to control pests and diseases with phytosanitary products of lower toxicity, i.e., with lower residues of synthetic pesticides.
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