Endosulfan (6,7,8,9,10,10-Hexachloro-1,5,5a,6,9,9a-hexahydro-6,9-methano-2,4,3-benzodioxathiepine-3-oxide) is an off-patent insecticide used in agricultural farms. Its usage as a pesticide has become highly controversial over the last few decades. This is due to its reported hazardous nature to health and side effects like growth retardation, hydrocephalus, and undesired changes in the male and female hormones leading to complications in sexual maturity. Endosulfan is the main culprit among all pesticide poisoning incidents around the world. Though the usage of this dreaded pesticide is banned by most countries, the high stability of this molecule to withstand degradation for a long period poses a threat to mankind even today. So, it has become highly essential to detect the presence of this poisonous pesticide in the drinking water and milk around these places. It is also advisable to check the presence of this toxic material in the blood of the population living in and around these places so that an early and appropriate management strategy can be adopted. With this aim, we have developed a sensor for endosulfan that displayed high selectivity and sensitivity among all other common analytes in water and biological samples, with a wide linear concentration range (2 fM to 2 mM), a low detection limit (2 fM), and rapid response. A citrate-functionalized cadmium-selenium quantum dot was used for this purpose, which showed a concentration-dependent fluorescence enhancement, enabling easy and sensitive sensing. This sensor was utilized to detect endosulfan in different sources of water, human blood serum, and milk samples with good recoveries. It is also noted that the quantum dot forms a stable complex with endosulfan and is easy to separate from the contaminated source, paving the way for purifying the contaminated water. More detailed tests and validation of the sensor are needed to confirm these observations.
Water splitting has been one of the potential techniques as a clean and renewable energy resource for the fulfillment of world energy demands. One of the major aspects of this procedure is the exploitation of efficient and inexpensive electrocatalysts due to the fact that the water oxidation procedure is accompanied by a delayed reaction. In this research, ZnO-CoFe2O4 nanostructure was successfully synthesized via the green method and green resources from cardamom seeds and ginger peels for oxygen evolution reaction (OER). The modified Glassy carbon electrode (GCE) with ZnO-CoFe2O4 is effective for the electrochemical water oxidation interaction since it has sufficient electrical strength and excellent catalytic performance. The creation of rice-like and small granular structures of ZnO-CoFe2O4 nano-catalysts was confirmed by characterization methods such as XRD, FESEM, EDS and MAP. According to the achieved results, in the electrolysis of water, with in-cell voltage of 1.40 V and 50 mA cm–2 for current density in a 0.1 M KOH electrolyte and OER only has 170 mV overpotentials.
In the process of constructing and building the industry English curriculum system in the new era, higher education institutions should clarify the corresponding curriculum teaching focus and direction, analyze, optimize, and improve the defects and deficiencies in the English curriculum teaching system. They should also combine refined and beneficial teaching ideas and strategies, innovate existing teaching methods, and integrate more ideological and political elements into curriculum teaching, to achieve more efficient teaching guidance for students. This article briefly analyzes and explores the strategies for constructing the English course system for waterway transportation and maritime management majors at present.
Herein, we report a facile preparation of super-hydrophilic sand by coating the sand particles with cross-linked polyacrylamide (PAM) hydrogels for enhanced water absorption and controlled water release aimed at desert agriculture. To prepare the sample, 4 wt% of aqueous PAM solution is mixed with organic cross-linkers of hydroquinone (HQ) and hexamethylenetetramine (HMT) in a 1:1 weight ratio and aqueous potassium chloride (KCl) solution. A specific amount of the above solution is added to the sand, well mixed, and subsequently cured at 150 °C for 8 h. The prepared super-hydrophilic sands were characterized by Fourier-transform infrared spectroscopy (FT-IR) for chemical composition and X-ray diffraction (XRD) for successful polymer coating onto the sand. The water storage for the samples was studied by absorption kinetics at various temperature conditions, and extended water release was studied by water desorption kinetics. The water swelling ratio for the super-hydrophilic sand has reached a maximum of 900% (9 times its weight) at 80 °C within 1 h. The desorption kinetics of the samples showed that the water can be stored for up to a maximum of 3 days. Therefore, super-hydrophilic sand particles were successfully prepared by coating them with PAM hydrogels, which have great potential to be used in sustainable desert agriculture.
In the present stage of the construction of application-oriented undergraduate "golden course", schools and teachers must understand that this work can play a role in the cultivation of talents In addition, the teaching should reflect more application-oriented characteristics, whether in the course content, course teachers, course teaching, The two characteristics of "golden course" construction should be highlighted as much as possible, one is application-oriented and the other is General characteristics can maximize the characteristics of these two aspects into advantages, so that the application of undergraduate "golden course" can achieve success.
The paper deals with the issues of the influence of forest cover on the average annual runoff of rivers in the Pripyat River basin. In the study area, under the influence of solar radiation, the temperature of the air and the soil surface increases, evaporation from the water surface also increases, and the moisture content of the upper layers of the soil decreases. In general, with an increase in forest cover, the annual layer of the runoff of the studied rivers increases, as well as with an increase in the amount of precipitation (in contrast to the runoff of short-term floods). However, with a forest cover of more than 20%–30% and a relatively small amount of precipitation, the runoff decreases, which is associated with the retention of part of the precipitation by the forest cover. With a large amount of precipitation and low forest cover, the runoff also decreases, which is probably due to the loss of precipitation water for evaporation, etc. The conducted studies show that, just as the forest affects water resources, the flow of moisture to watersheds also affects the state of forest systems. Moreover, this interaction is expressed by evaporation from forests. Under influence of change of a climate growth of evaporation is observed.
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