Zinc oxide (ZnO) hollow spheres are gaining attention due to their exceptional properties and potential applications in various fields. This study investigates the impact of different zinc precursors Zinc Chloride (ZnCl2), Zinc Nitrate [Zn(NO3)2], and Zinc Acetate [Zn(CH3COO)2] on the hydrothermal synthesis of ZnO hollow spheres. A comprehensive set of characterization techniques, including Field Emission Scanning Electron Microscopy (FE-SEM), X-ray Diffraction (XRD), Thermogravimetric analysis (TGA), and Brunauer-Emmett-Teller (BET) analysis, was utilized to assess the structural and morphological features of the synthesized materials. Our findings demonstrate that all samples exhibit a high degree of crystallinity with a wurtzite structure, and crystallite sizes range between 34 to 91 nm. Among the different precursors, ZnO derived from Zinc Nitrate showed markedly higher porosity and a well-defined mesoporous structure than those obtained from Zinc Acetate and Zinc Chloride. This research underscores the significance of precursor selection in optimizing the properties of ZnO hollow spheres, ultimately contributing to advancements in the design and application of ZnO-based nanomaterials.
The expanding blue economy, marked by its focus on sustainable use of ocean resources, offers enormous opportunity for Small and Medium-sized Enterprises (SMEs). However, for SMEs to properly integrate and succeed in this economy, they must first have a thorough awareness of the sector’s challenges and prospects. This research used a scoping review and a qualitative study to identify the challenges and opportunities facing SMEs operating in the blue economy. The study discovered recurring themes and gaps in the existing literature by conducting an extensive examination of scholarly publications. The key challenges identified include complicated regulatory frameworks, restricted access to funding, infrastructure restrictions, talent deficiencies, government support, and market outreach. In-depth interviews with Malaysian SME leaders, industry stakeholders, and policymakers were conducted to decipher these findings. The results of interviews confirmed the relevance of the regulatory framework, infrastructure restrictions, talent deficit, and market access challenges in the Malaysian context. In particular, the study revealed emerging opportunities for Malaysian blue SMEs in sectors such as renewable energy, sustainable fisheries, marine biotechnology, and ecotourism. The study emphasizes the importance of an encouraging policy framework, knowledge-sharing platforms, and capacity building activities. It finishes by underlining the ability of SMEs to drive a sustainable and thriving blue economy, if challenges are systematically handled, and opportunities are appropriately capitalized.
Some developmental projects are created by people-private partnerships (PPP), particularly where recovery is acquirable by levying the users. Such PPPs are successful for construction of roads, bridges, running toilet facilities and conveyance facility in mode of use and pay. Likewise, public-scientist partnerships (PSPs) will be successful, where monitored impacts can be used to derive benefit. But such example cases are not so popular in utilizing new research results and derive benefits from natural resources and enhance productivity. There is a demand for similar partnership projects in research area. In this study modality of the PSP to create boost engine for natural resource conservation and bring economic prosperity is established. A novel PSP launch was synthesized on useful food crop viz. finger millet (Elusiane corcona (l)), which has been known since long past, and now is regaining popularity. It was possible to enhance additional annual production of 5.755 million tonnes of finger millet grain, equivalent to additional income of Rs 11,510 crores. Against this the scientist partnership share was 0.49x million tonnes grain and economic equivalency of Rs 992 crores, which was just 7–8%, with same level of input in agriculture. Additional benefits were sustainability of production and resources consecration, reduction of greenhouse gas emission (GHGs), particularly nitrous oxide (N2O), largely emanating from agriculture and responsible for depletion of ozone layer. The finger millet stiff stem will be useable for production of ply-board filling material that will be innovative building material for housing and infrastructure developments and making furniture.
Bangladesh’s coastal regions are rich in saline water resources. The majority of these resources are still not being used to their full potential. In the southern Bangladeshi region of Patuakhali, research was conducted to investigate the effects of mulching and drip irrigation on tomato yield, quality, and blossom-end rot (BER) at different soil salinity thresholds. There were four distinct treatments applied: T1= drip irrigation with polythene mulch, T2 = drip irrigation with straw mulch, T3 = drip irrigation without mulch, and T4 = standard procedure. While soil salinity was much greater in treatment T3 (1.19–8.42 dS/m) fallowed by T4 (1.23–8.63 dS/m), T1 treatments had the lowest level of salinity and the highest moisture retention during every development stage of the crops, ranging from 1.28–4.29 dS/m. Treatment T3 exhibited the highest soil salinity levels (ranging from 1.19 to 8.42 dS/m), followed by T4 with a range of 1.23 to 8.63 dS/m. In contrast, T1 treatments consistently maintained the lowest salinity levels (ranging from 1.28 to 4.29 dS/m) and the highest moisture retention throughout all stages of crop development. In terms of yield, drip irrigation with no mulch treatment (T3) provided the lowest output (13.37 t/ha), whereas polyethylene mulching treatment (T1) produced the maximum yield (46.04 t/ha). According to the study, conserving moisture in tomato fields and reducing soil salinity may both be achieved with drip irrigation combined with polythene mulch. The research suggests that employing drip irrigation in conjunction with polythene mulch could effectively preserve moisture in tomato fields and concurrently decrease soil salinity.
Based on the research on 31 provincial-level administrative regions at the end of 2022, we used the geographic concentration index, geographic imbalance index, SPSS and ARCGIS spatial analysis techniques to study the spatial distribution, distribution factor correlation, and accessibility of national 5A-level scenic spots. The research results show that the overall distribution of my country's 5A-level scenic spots is unbalanced, with a low degree of concentration, showing a pattern of denseness in the east and sparseness in the west, with large inter-provincial differences. The density of traffic highways is positively correlated with the distribution density of 5A-level scenic spots. The traffic lines in the central and eastern regions are dense, and there are a large number of 5A-level scenic spots, especially the Beijing-Tianjin-Hebei region, the Yangtze River Delta region, and the middle and lower reaches of the Yangtze River and Yellow River. Therefore, the spatial distribution of China's 5A-level tourist attractions is mainly affected by the interaction of economic, transportation and social factors, among which GDP, transportation network and attraction of scenic spots are the most critical factors. These research results can provide a reference for optimizing the spatial layout of China's scenic resources and promoting regional socio-economic development.
Public-private partnerships (PPPs) are vital for infrastructure development in developing countries, integrating private efficiency with public oversight. However, PPP models often face risks, particularly in Indonesia’s water sector, due to its unique geographical and regulatory challenges. This study aims to identify and evaluate risk factors specific to drinking water PPP projects in Indonesia. Using a quantitative approach, structured questionnaires were distributed to experts in the sector, and the data was analyzed using a fuzzy evaluation method. Risks were categorized into location, design and construction, financial, operational, revenue, and political. The study emphasizes that effective risk management, including identification, analysis, and mitigation, is essential for project success. It highlights the importance of stakeholder involvement and flexible risk management strategies. Comprehensive and proactive risk management is key to the success of drinking water infrastructure projects. The research suggests that an integrated and collaborative approach among stakeholders can enhance risk management effectiveness. These findings provide valuable insights for policymakers, project managers, investors, and other stakeholders, underscoring the necessity for adaptable regulatory frameworks and robust policy guidelines to improve the sustainability and efficacy of future water-related PPPs.
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