Tomato is one of the major solanaceous vegetables, which has a unique place in the global vegetable market. Instead of being a high-value crop, there is still a need to do improvement in its potential against various biotic and abiotic stressors that adequately demolish its real yield. Alternaria solani (causing early blight disease) is designated as one of the fatal organisms that may reduce tomato crop yield by up to 80%. There were lots of methods, viz., chemical, cultural and biological suggested to overcome it. However, chemical strategies are much in vogue, but they have several negative consequences for human health and the ecosystem. Enlightening this issue, the efficacy of various treatments, viz., chemical fungicides (Amistar Top^®, Nativo^®, and Contaf^®), biochar and fungal bioagent (Trichoderma viride) was assessed under both in vivo and in vitro conditions. Induced resistance is mediated by several regulating pathways, like salicylic acid and jasmonic acid. These mediating pathways manipulate different physiological processes like growth and development, stress tolerance, and defence mechanisms of the plant. The assessment of results revealed that among all treatments biochar at 3.25% by weight consistently displayed remarkable effectiveness against the early blight infection by triggering resistance and improving the overall performance of tomato plants. This result is attributed to improved soil health, fastening mineralization as well as absorption processes, and boosting the plant’s immunity with the use of a higher concentration of biochar. Hence, it could be recommended for the overall improvement of tomato crop and its sustainability.

Prepolymers containing isocyanates must be prevented from curing when exposed to moisture, which can be achieved by blocking the isocyanate groups with a suitable agent. The study carefully examines several blocking agents, including methyl ethyl ketoxime (MEKO), caprolactam, and phenol, and concludes that methyl ethyl ketoxime is the best choice. Spectroscopic and thermal analyses, as well as oven curing studies, are conducted with various blocking agents and isocyanate prepolymer to castor oil ratios, revealing MEKO to be the most effective blocking agent which gets unblocked at higher temperatures.

Nanomaterials stand as transformative elements across diverse domains, ranging from biotechnology, aircraft, aviation, and space exploration to medicine, health, environmental preservation, resources, energy, and aerospace. This issue, comprising nine original research articles and two insightful reviews, we embark on a journey to unravel the multifaceted uses of nanomaterials, with a special emphasis on their contributions to environmental protection and medicine. Delving into the unique traits of various nanomaterials, our aim is to provide readers with a comprehensive understanding that transcends conventional boundaries, fostering a deeper appreciation for the impact of nanomaterials.

In this paper, we deal with one of the most urgent and relevant topics nowadays, i.e., water pollution. The problem is finding a valid candidate for the absorption and removal of different kinds of pollutants commonly found in water. There are already some indications about graphene oxide as a potential candidate. In the present work, we take a step forward to show how graphene nanoplatelets (rather than the oxide form of this material) are capable of decontaminating water. In this starting step, we use a specific substance as a model pollutant, i.e., acetonitrile, leaving for the future steps, to extend the analysis to additional types of pollutants. In addition to laboratory-produced graphene nanoplatelets, we already examined in the past; now we wish to consider also commercially available ones, so that the new results will not be bound to a laboratory (low technology readiness level) material, but will become interesting also from the industrial point of view, thanks to the scalability of the nanoplatelets production. For this aim, we compare the performance of two types of filters based on two classes of nanomaterials, i.e., those produced by microwave and ultrasound assisted exfoliation, already analyzed in our earlier works, with those commercially distributed by an Italian company, i.e., NANESA, http://www.nanesa.com/. The latter is an innovative SME involved in the production of graphene-based nanomaterials. We focus here in the graphene nanoplatelets, commercially available in industrial batches (GXNan grades). The present study leads to determine which filtering membrane, among the various types of commercial graphene considered, shows the greatest stability, and the lack of breakage of the membrane, concentrating on such accessory features, given that all types of graphene showed excellent adsorption properties.

This paper aims to explain the administrative and the Environmental, Social and Governance (ESG) of the Indonesian Spaceport Project in Biak, Papua, Indonesia, under the Public-Private Partnerships (PPP) scheme, particularly from the protest to fear of environmental damage and traditional rights. This paper analyzes the factors that cause the local society’s reluctance to accept the development of Indonesia’s very first commercial spaceport. This paper uses a doctrinal methodology, which examines changes in the trend of ESG in implementing PPP projects. The method used is a qualitative systematic review of national and international studies. This paper finds that the lack of legal certainty for administrative and ESG as the main factor contributing to the pitfall of the PPP project in Biak Papua. No clear Government Contracting Agency (GCA), plus the fact that the Indonesian government puts too much weight on business consideration in PPP while Papuan people need more ESG, especially considering the historical conflict in the region, has been the epicenter of the problem. Given the ESG-PPP regulatory failure of spaceport development in Biak, more focused studies using comparative study methodology are needed to propose a more robust and customized ESG in PPP regulations in a politically and historically sensitive area. The authors forward a regulatory reform to balance administration, ESG, and business considerations in PPP projects for a spaceport.