The effect of isocyanate trimer on the flame retardancy mechanism of polyisocyanurate (PIR) foam was studied in three aspects, including the mechanism of thermal decomposition in the condensed phase, the barrier mechanism of carbon layer formation on the surface in the condensed phase, and the mechanism in the gaseous phase, by using infrared spectroscopy, scanning electron microscopy, thermal analysis, a cone calorimeter, and high-temperature pyrolysis gas chromatography mass spectrometry. The results show that the trimmer can improve the thermal stability of the PIR foam and is not easily decomposed in the combustion. The trimmer can increase the carbon content of the PIR foam to 29.9% of that of the polyurethane (PU) foam. The carbon layer formed is denser, and it can retard heat and oxygen and thus improve the flame retardant properties; trimer can reduce the release of flammable polyol gas, decompose into more carbon dioxide, which is an inert gas, and it has certain flame retardant effects in the gaseous phase.
Introduction, purpose of the study: In Central Europe, in Hungary, the state guarantees access to health care and basic health services partly through the Semmelweis Plan adopted in 2011. The Health Plan aims to optimize and transform the health system. The objectives of hospital integration, as set out in the Plan, started with the state ownership of municipal hospitals in 2012, continued with the launch of integration processes in 2012–2013 and culminated today. The transformation of a health system can have an impact on health services and thus on meeting the needs of the population. We aim to study the effectiveness of integration through access to CT diagnostic testing. Our hypothesis is that integration has resulted in increased access to modern diagnostic services. The specialty under study is computed tomography (CT) diagnostic care. Our research shows that the number of people receiving CT diagnostic care has increased significantly because of integration, which has also brought a number of positive benefits, such as reduced health inequalities, reduced travel time, costs and waiting lists. Test material and method: Our quantitative retrospective research was carried out in the hospital of Kalocsa through document analysis. The research material was comparing two time periods in the Kalocsa site of Bács-Kiskun County, Southern Hungary. The number of patients attending CT examinations by area of duty of care according to postal codes was collected: Pre-integration period 2014.01.01–2017.11.30. (Kalocsa did not have CT equipment, so patients who appeared in Kecskemét Hospital but were under the care of Kalocsa), post-integration period 2017.12.01–2019.12.31. (period after the installation of CT in Kalocsa). The target group of the study consisted of women and men together, aged 0–99 years, who appeared for a CT diagnostic examination. The study sample size was 6721 persons. Linear regression statistics were used to evaluate the results. Based on empirical experience, a SWOT analysis was carried out to further investigate the effectiveness of integration. Results: As a result of the integration, the CT scan machine purchased in the Kalocsa District Hospital has enabled an average of 129.7 patients per month to receive CT scans on site without travelling. The model used is significant, explaining 86% of the change in the number of patients served (F = 43.535; p < 0.001, adjusted R2 = 0.860). The variable of integration in the model is significant, with an average increase in the number of patients served of 129.7 per month (t = 22.686; p < 0.001) following the introduction of CT due to integration. None of the month variables representing seasonal effects were found to be significant, with no seasonal effect on care. The SWOT analysis has clearly identified the strengths, weaknesses, opportunities and threats related to the integration, the main outcome of which is the acquisition of a CT diagnostic tool. Conclusions: Although we only looked at one segment of the evidence for the effectiveness of hospital integration, integration in the study area has had a positive impact on CT availability, reducing disparities in care.
In order to study the temperature change trend of the surrounding geotechnical soil during the operation and thermal recovery of the medium-deep geothermal buried pipe and the influence of the geotechnical soil on the operational stability of the vertical buried pipe after thermal recovery. Based on the data of geological stratum in Guanzhong area and the actual engineering application of medium-deep geothermal buried pipe heating system in Xi’an New Area, the influence law of medium-deep geothermal buried pipe heat exchanger on surrounding geotechnical soil is simulated and analyzed by FLUENT software. The results show that: after four months of heating operation, in the upper layer of the geotechnical soil, the reverse heat exchange zone appears due to the higher fluid temperature; in the lower layer of the geotechnical soil, the temperature decreases more with the increase of depth and shows a linear increase in the depth direction; without considering the groundwater seepage, after eight months of thermal recovery of the geotechnical soil after heating, the maximum temperature difference after recovery is 3.02 ℃, and the average temperature difference after recovery is 1.30 ℃ The maximum temperature difference after recovery was 3.02 ℃ and the average temperature difference after recovery was 1.30 ℃. The geotechnical thermal recovery temperature difference has no significant effect on the long-term operation of the buried pipe, and it can be operated continuously and stably for a long time. Practice shows that due to the influence of various factors such as stratigraphic structure, stratigraphic pressure, radioactive decay and stratigraphic thermal conductivity, the actual stratigraphic temperature below 2000m recovers rapidly without significant temperature decay, fully reflecting the characteristics of the Earth’s constant temperature body.
Nanotransformations of a blanket at the fair dimensional combined processing with imposing of electric field the tool in the form of untied metal granules are considered. An object of researches are the figurine details applied in aviation, the missile and space equipment and in the oil and gas industry: driving wheels and a flowing part of cases of turbo-pump units, screws, krylchatka where there are sites of variable curvature with limited access of the tool in a processing zone.It is shown that the combination in the combined process of two-component technological environments of current carrying granules and the electroconductive liquid environment given with a high speed to a processing zone allows to receive the required quality of a blanket; action of electric field from a source with the increased tension allows to create at fair dimensional processingthe required peening from blows of firm granules. It gives the chance to raise a resource and durability of responsible knots of the aerospace equipment and oil and gas equipment, to expand the field of use of the combined processing with untied granules on a detailwith the sitesnot available to processing by a profile electrode.
To study the environment of the Kipushi mining locality (LMK), the evolution of its landscape was observed using Landsat images from 2000 to 2020. The evolution of the landscape was generally modified by the unplanned expansion of human settlements, agricultural areas, associated with the increase in firewood collection, carbonization, and exploitation of quarry materials. The problem is that this area has never benefited from change detection studies and the LMK area is very heterogeneous. The objective of the study is to evaluate the performance of classification algorithms and apply change detection to highlight the degradation of the LMK. The first approach concerned the classifications based on the stacking of the analyzed Landsat image bands of 2000 and 2020. And the second method performed the classifications on neo-images derived from concatenations of the spectral indices: Normalized Difference Vegetation Index (NDVI), Normalized Difference Building Index (NDBI) and Normalized Difference Water Index (NDWI). In both cases, the study comparatively examined the performance of five variants of classification algorithms, namely, Maximum Likelihood (ML), Minimum Distance (MD), Neural Network (NN), Parallelepiped (Para) and Spectral Angle Mapper (SAM). The results of the controlled classifications on the stacking of Landsat image bands from 2000 and 2020 were less consistent than those obtained with the index concatenation approach. The Para and DM classification algorithms were less efficient. With their respective Kappa scores ranging from 0.27 (2000 image) to 0.43 (2020 image) for Para and from 0.64 (2000 image) to 0.84 (2020 image) for DM. The results of the SAM classifier were satisfactory for the Kappa score of 0.83 (2000) and 0.88 (2020). The ML and NN were more suitable for the study area. Their respective Kappa scores ranged between 0.91 (image 2000) and 0.99 (image 2020) for the LM algorithm and between 0.95 (image 2000) and 0.96 (image 2020) for the NN algorithm.
The use of plant viruses as bioherbicides represents a fascinating and promising frontier in modern agriculture and weed management. This review article delves into the multifaceted world of harnessing plant viruses for herbicidal purposes, shedding light on their potential as eco-friendly, sustainable alternatives to traditional chemical herbicides. We begin by exploring the diverse mechanisms through which plant viruses can target and control weeds, from altering gene expression to disrupting essential physiological processes. The article highlights the advantages of utilizing plant viruses, such as their specificity for weed species, minimal impact on non-target plants, and a reduced environmental footprint. Furthermore, we investigate the remarkable versatility of plant viruses, showcasing their adaptability to various weed species and agricultural environments. The review delves into the latest advancements in genetic modification techniques, which enable the engineering of plant viruses for enhanced herbicidal properties and safety. In addition to their efficacy, we discuss the economic and ecological advantages of using plant viruses as bioherbicides, emphasizing their potential to reduce chemical herbicide usage and decrease the development of herbicide-resistant weeds. We also address the regulatory and safety considerations associated with the application of plant viruses in agriculture. Ultimately, this review article underscores the immense potential of plant viruses as bioherbicides and calls for further research, development, and responsible deployment to harness these microscopic agents in the ongoing quest for sustainable and environmentally friendly weed management strategies.
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