Cobalt-ion batteries are considered a promising battery chemistry for renewable energy storage. However, there are indeed challenges associated with co-ion batteries that demonstrate undesirable side reactions due to hydrogen gas production. This study demonstrates the use of a nanocomposite electrolyte that provides stable performance cycling and high Co2+ conductivity (approximately 24 mS cm−1). The desirable properties of the nanocomposite material can be attributed to its mechanical strength, which remains at nearly 68 MPa, and its ability to form bonds with H2O. These findings offer potential solutions to address the challenges of co-dendrite, contributing to the advancement of co-ion batteries as a promising battery chemistry. The exceptional cycling stability of the co-metal anode, even at ultra-high rates, is a significant achievement demonstrated in the study using the nanocomposite electrolyte. The co-metal anode has a 3500-cycle current density of 80 mA cm−2, which indicates excellent stability and durability. Moreover, the cumulative capacity of 15.6 Ah cm−2 at a current density of 40 mA cm−2 highlights the better energy storage capability. This performance is particularly noteworthy for energy storage applications where high capacity and long cycle life are crucial. The H2O bonding capacity of the component in the nanocomposite electrolyte plays a vital role in reducing surface passivation and hydrogen evolution reactions. By forming strong bonds with H2O molecules, the polyethyne helps prevent unwanted reactions that can deteriorate battery performance and efficiency. This mitigates issues typically associated with excess H2O and ion presence in aqueous Co-ion batteries. Furthermore, the high-rate performance with excellent stability and cycling stability performance (>500 cycles at 8 C) of full Co||MnO2 batteries fabricated with this electrolyte further validates its effectiveness in practical battery configurations. These results indicate the potential of the nanocomposite electrolyte as a valuable and sustainable option, simplifying the development of reliable and efficient energy storage systems and renewable energy applications.
The regulation of compressor extraction and energy storage can improve the performance of gas turbine energy system. In order to make the gas turbine system match the external load more flexibly and efficiently, a gas turbine cogeneration system with solar energy coupling compressor outlet extraction and energy storage is proposed. By establishing the variable condition mathematical model of air turbine, waste heat boiler and solar collector, we use Thermoflex software to establish the variable condition model of gas turbine compressor outlet extraction, and analyze the variable condition of the coupling system to study the changes of thermal parameters of the system in the energy storage, energy release and operation cycle. Taking the hourly load of a hotel in South China as an example, this paper analyzes the case of the cogeneration system of solar energy coupling compressor outlet extraction and energy storage, and compares it with the benchmark cogeneration system. The results show that taking a typical day as a cycle, the primary energy utilization rate of the system designed in this paper is 3.2% higher than that of the traditional cogeneration system, and the efficiency is 2.4% higher.
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