In this paper, we modeled and simulated two tandem solar cell structures (a) and (b), in a two-terminal configuration based on inorganic and lead-free absorber materials. The structures are composed of sub-cells already studied in our previous work, where we simulated the impact of defect density and recombination rate at the interfaces, as well as that of the thicknesses of the charge transport and absorber layers, on the photovoltaic performance. We also studied the performance resulting from the use of different materials for the electron and hole transport layers. The two structures studied include a bottom cell based on the perovskite material CsSnI3 with a band gap energy of 1.3 eV and a thickness of 1.5 µm. The first structure has an upper sub-cell based on the CsSnGeI3 material with an energy of 1.5 eV, while the second has an upper sub-cell made of Cs2TiBr6 with a band gap energy of 1.6 eV. The theoretical model used to evaluate the photocurrent density, current-voltage characteristic, and photovoltaic parameters of the constituent sub-cells and the tandem device was described. Current matching analysis was performed to find the ideal combination of absorber thicknesses that allows the same current density to be shared. An efficiency of 29.8% was obtained with a short circuit current density Jsc = 19.92 mA/cm2, an open circuit potential Voc = 1.46 V and a form factor FF = 91.5% with the first structure (a), for a top absorber thickness of CsSnGeI3 of 190 nm, while an efficiency of 26.8% with Jsc = 16.74, Voc = 1.50 V and FF = 91.4% was obtained with the second structure (b), for a top absorber thickness of Cs2TiBr6 of 300 nm. The objective of this study is to develop efficient, low-cost, stable and non-toxic tandem devices based on lead-free and inorganic perovskite.
One-dimensional unsteady theoretical models of three different photovoltaic module installation modes are established. Through MATLAB modeling and simulation, the influence of photovoltaic modules on roof heat transfer in different layout modes is compared. Comparing with ordinary roof, the shading effect of photovoltaic roof in summer and heat preservation effect in winter was analyzed. The results show that the PV roof layout with ventilation channel is better in summer. The proof layout with closed flow channel is better in winter.
Electricity generation around the world is mainly produced by using non-renewable energy sources especially in the commercial buildings. However, Rooftop solar Photovoltaic (PV) system produced a significant impact on environmental and economical benefits in comparison to the conventional energy sources, thus contributing to sustainable development. Such PV’s system encourages the production of electricity without greenhouse gas emissions that leads to a clean alternative to fossil fuels and economic prosperity even in less developed areas. However, efficiency of rooftop solar PV systems depends on many factors, the dominant being geographical (latitude, longitude, and solar intensity), environmental (temperature, wind, humidity, pollution, dust, rain, etc.) and the type of PV (from raw material extraction and procurement, to manufacturing, disposal, and/or recycling) used. During the feasibility analysis of the environment, geographical conditions are keep in well consideration, but the pollution level of the city is always overlooked, which significantly influences the performance of the PV installations.
Therefore, this research work focused on the performance of rooftop solar PV installed in one of the most polluted city in India. Here, the loss in power generation of rooftop solar PV has been studied for the effect of deposited dust particles, wind velocity before and after the cleaning of the panels. The actual data has been utilized for the calculation of the energy efficiency and power output of the PV systems. According to the results, it has been concluded that dust deposition, wind speed and pollution level in city significantly reduces the efficiency of solar photovoltaic panel. Hence, an overview of social and environmental impacts of PV technologies is presented in this paper along with potential benefits and pitfalls.
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