Water splitting has gained significant attention as a means to produce clean and sustainable hydrogen fuel through the electrochemical or photoelectrochemical decomposition of water. Efficient and cost-effective water splitting requires the development of highly active and stable catalysts for the oxygen evolution reaction (OER) and hydrogen evolution reaction (HER). Carbon nanomaterials, including carbon nanotubes, graphene, and carbon nanofibers, etc., have emerged as promising candidates for catalyzing these reactions due to their unique properties, such as high surface area, excellent electrical conductivity, and chemical stability. This review article provides an overview of recent advancements in the utilization of carbon nanomaterials as catalysts or catalyst supports for the OER and HER in water splitting. It discusses various strategies employed to enhance the catalytic activity and stability of carbon nanomaterials, such as surface functionalization, hybridization with other active materials, and optimization of nanostructure and morphology. The influence of carbon nanomaterial properties, such as defect density, doping, and surface chemistry, on electrochemical performance is also explored. Furthermore, the article highlights the challenges and opportunities in the field, including scalability, long-term stability, and integration of carbon nanomaterials into practical water splitting devices. Overall, carbon nanomaterials show great potential for advancing the field of water splitting and enabling the realization of efficient and sustainable hydrogen production.

A geologic and geomorphologic study aimed at solving some geological and geotechnical problems, regarding the massive seepage of meteoric waters in the coastal cliffs of the Island of Procida (Naples Bay, Southern Italy) composed of both tuffs and loose pyroclastic deposits, has been carried out in the geosites of Terra Murata (Middle Ages village and coastal cliff towards the Corricella Bay) and Centane-Panoramica (coastal cliff facing on the Tyrrhenian Sea).

A detailed geologic and geomorphologic survey has allowed to suggest solutions to the applied geological and geotechnical problems related to the occurrence of massive seepages of waters at the physical interface between pyroclastic rocks and loose pyroclastic deposits, characterized by different density, permeability and porosity and also controlled by a dense network of fractures, involving the pyroclastic deposits cropping out in the selected areas.

Field sampling and geotechnical laboratory analyses have been carried out to calculate the values of main geotechnical parameters of the yellow tuffs cropping out at the Terra Murata Promontory. At the same time, a detailed monitoring of the seepages of waters has been carried out through a detailed geological survey of the tuff outcrops of the promontory. The obtained results have suggested a strong control from both the geomorphologic instability of the coastal cliff and tectonic setting. At the Centane-Panoramica geosite, the geological survey, coupled with geotechnical analyses and standard penetrometric tests, has accordingly evidenced that the geomorphologic instability was mainly concentrated in the sectors of the tuff coastal cliffs facing seawards towards the Tyrrhenian Sea.

Broad-spectrum antibiotics, such as tetracyclines, are used to treat and manage a range of infectious disorders. Since the kidneys are the primary organs responsible for excreting tetracyclines, clinicians should refrain from prescribing them to patients who have renal failure. Tetracyclines are one of the clinical waste products of today. One of the biggest problems in the field of pollution of the environment today is the persistence of different pharmaceutical residues, drug residues, pesticides, and metal ion species of the new-generation pollutants in surfaces and groundwater. In the present work, carboxymethyl cellulose (CMC)-CuO nanoparticles (CMC-CuO NPs) were synthesized using CuO NPs within different amounts of CMC (0.5, 1.0, 1.5 and 2.0 g) at 85 °C. The synthesized nanoparticles were characterized by XRD, FT IR, SEM, and TG-DTA analysis. According to XRD and SEM, the crystallize size and morphology influenced the dosage of CMC. FT-IR analysis confines the layer of CMC to the CuO nanoparticle surface. TG-DTA results indicated that the CMC content of CMC-CuO NPs was between the range of 69% and 75% by weight. The effects of some parameters such as initial concentration, pH, adsorbent dosage, and contact time on the adsorption of tetracycline from aqueous model solutions on CMC-CuO NPs were investigated with batch studies. It was found that the removal of tetracycline was obtained about 80% with optimized parameters of 10 mg/L concentration, 180 min contact time, 5 pH, and 0.3 g/25 mL dose. The synthesized CMC-CuO NPs nanocomposite may be a promising material for the removal of tetracycline in environmental pollution and toxicology.

Branched micro/nano Se was prepared by the redaction of L-Cys•HCl and H₂SeO₃ in hydrothermal method, as β-CD was used as soft template. The structures of products were characterized by SEM, TEM and XRD. Some important factors influencing the morphology of products were studied and discussed, including the amounts of soft template, the reaction temperature and the reaction time. The results showed that external causes had a potent effect on the morphology of micro/nano Se. The uniform branched micro/nano Se prepared under the optimal reaction condition was rhombohedral trigonal selenium t-Se⁰, but its crystallinity degree was low.

The electrospinning precursor solution was prepared by dissolving polyvinyl pyrrolidone as template, tetrabutyl titanate as titanium source, and acetic acid as inhibitor. The TiO₂ nanofilms were prepared by precursor solution electrospinning and subsequent calcination. Thermal gravimetric analysis (TG), scanning electron microscopy (SEM), X-ray powder diffraction (XRD), and transmission electron microscopy (TEM) were used to characterize and analyze the samples. The influence of technological parameters on spinning fiber morphology was also studied. The results indicate that the TiO₂ nanofibers morphology is good when the parameters are as follows: voltage 1.4×10⁴ V，spinning distance 0.2 m，translational velocity 2.5×10^-3 m·s^-1, flow rate 3×10^-4 m·s^-1, and needle diameter 3×10^-4 m. The diameter of the fibers is about 150 nm. With the 1×10^-4 mol·L^-1 methylene blue solution used as simulated degradation target, the degradation rate is 95.8% after 180 minutes.

Banana (Musa spp.) productivity is limited by sodic soils, which impairs root growth and nutrient uptake. Analyzing root traits under stress conditions can aid in identifying tolerant genotypes. This study investigates the root morphological traits of banana cultivars under sodic soil stress conditions using Rhizovision software. The pot culture experiment was laid out in a Completely Randomized Design (CRD) under open field conditions, with treatments comprising the following varieties: Poovan (AAB), Udhayam (ABB), Karpooravalli (ABB), CO 3 (ABB), Kaveri Saba (ABB), Kaveri Kalki (ABB), Kaveri Haritha (ABB), Monthan (ABB), Nendran (AAB), and Rasthali (AAB), each replicated thrice. Parameters such as the number of roots, root tips, diameter, surface area, perimeter, and volume were assessed to evaluate the performance of different cultivars. The findings reveal that Karpooravali and Udhayam cultivars exhibited superior performance in terms of root morphology compared to other cultivars under sodic soil stress. These cultivars displayed increased root proliferation, elongation, and surface area, indicating their resilience to sodic soil stress. The utilization of Rhizovision software facilitated precise measurement and analysis of root traits, providing valuable insights into the adaptation mechanisms of banana cultivars to adverse soil conditions.