The co-hydrothermal carbonization of biomasses has shown many advantages on charcoal yield, carbonization degree, thermal-stability of hydrocar and energy recovered. The goal of this study is to investigate the effect of co-combustion of cattle manure and sawdust on energy recovered. The results show that ash content ranged between 10.38%–20.00%, indicating that the proportion of each variable influences energy recovered. The optimum is obtained at 51% cattle manure and 49% sawdust revealing 37% thermal efficiency and 3.9 kW fire power. These values are higher compared to cattle manure individually which gives values of 30% and 2.3 kW respectively for thermal efficiency and fire power. Thus, the mixture of biomasses enhances energy recovered both in combustion and hydrothermal carbonization. Volatile matter is lower in mixture predicting that the flue gas releases is lower during combustion. Fixed carbon is higher in mixture predicting that energy recovered increases during the combustion of mixture than cattle manure individually. Higher Carbon content was noticed in mixture than cattle manure indicating that the incorporation of sawdust enhances heating value. The incorporation of sawdust in cattle manure can also enhance energy recovered and is more suitable for domestic and industrial application.

This paper concerns a miniature gasifier fed with a constant ambient-pressure flow of air to study the pyrolysis and subsequent combustion stage of a single wood pellet at T = 800 ℃. The alkali release and the concentration of simple gases were recorded simultaneously using an improved alkali surface ionisation detector and a mass spectrometer in time steps of 1 s and 1.2 s, respectively. It showed alkali release during both stages. During combustion, the MS data showed almost complete oxidation of the charred pellet to CO₂. The derived alkali release, “O₂ consumed”, and “CO₂ produced” conversion rates all indicated very similar temporal growth and coalescence features with respect to the varying char pore surface area underlying the original random pore model of Bhatia and Perlmutter. But, also large, rapid signal accelerations near the end and marked peak-tails with O₂ and CO₂ after that, but not with the alkali release data. The latter features appear indicative of alkali–deprived char attributable to the preceding pyrolysis with flowing air. Except for the peak-tails, all other features were reproduced well with the modified model equations of Struis et al. and the parameter values resembled closely those reported for fir charcoal gasified with CO₂ at T = 800 ℃.

This study examined the impact of aluminium doping on the structural, electrical, and magnetic properties of Li_(0.5)Co_(0.75)Al_xFe_(2−x)O₄ spinel ferrites (x =0.15 to 0.60). The samples were synthesised using the sol-gel auto-combustion technique, and they were examined using X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FTIR), dielectric measurements, and vibrating sample magnetometry (VSM). All samples possessed a single-phase cubic spinel structure with Fd-3m space group, according to XRD analyses. SEM images showed the creation of homogeneous particles with an average size of about 21 nm. All samples had spinel ferrite phases, confirmed from FTIR spectra. DC electrical conductivity studies showed that the conductivity increased with increasing aluminium content up to x = 0.45 before dropping at x = 0.60. The maximum saturation magnetization value was found at x = 0.45, according to VSM measurements, which demonstrated that the magnetic characteristics were strongly correlated with the amount of aluminium.