Surface-enhanced Raman scattering (SERS) spectrum has the characteristics of fast-detection, high-sensitivity and low-requirements for sample pretreatment. It plays a more and more important role in the detection of organic pollutants. In this study, MIL-101 and Au nanoparticles were prepared by hydrothermal method and aqueous solution reduction method respectively, and MIL-101/Au composite nanoparticles were prepared by electrostatic interaction. The SERS properties of the composite substrate were optimized by adjusting the size of Au nanoparticles and the surface distribution density of MIL-101 nanoparticles. The detection limit of Rhodamine 6G (R6G) for the composite substrate with the optimal ratio was investigated, which was as low as 10–11 M. It is proved that MIL-101/Au composite nanoparticles have high sensitivity to probe molecules. When they are applied to the detection of persistent organic pollutants, the detection limit for fluoranthene can reach 10–9 M and for 3,3’,4,4’-tetrachlorobiphenyl (PCB-77) can reach 10–5 M.
This paper argues for a novel approach to financing infrastructure needs in Arab countries. It first describes the context of rising public debt in the region, contrasting it with the vast infrastructure needs. It then discusses the challenges in meeting these needs with traditional financing. The paper then makes the case for maximizing finance for development by using public-private partnerships and presents a few successful examples in Arab countries. Finally, the paper explores the way forward and concludes on the need for strong state capacity and integrity to promote the “maximizing finance for development” approach.
This paper uses Public Choice analysis to examine the case for and experience with Public-Private Partnerships (PPPs). A PPP is a contractual platform which connects a governmental body and a private entity. The goal is to provide a public sector program, service, or asset that would normally be provided exclusively by a public sector entity. This paper focuses on PPPs in developed countries, but it also draws on studies of PPPs in developing countries. The economics literature generally defines PPPs as long-term contractual arrangements between a public authority (local or central government) and a private supplier for the delivery of services. The private sector supplier takes responsibility for building infrastructure components, securing financing of the investment, and then managing and maintaining this facility.
However, in addition to those formed through contracts, PPPs may take other forms such as those developed in response to tax subvention or coercion, as in the case of regulatory mandates. A key element of PPP is that the private partner takes on a significant portion of the risk through a schedule of specified remuneration, contingency payments, and provision for dispute resolution. PPPs typically are long-term arrangements and involve large corporations on the private side, but may also be limited to specific phases of a project.
The types of PPPs discussed in this paper exclude arrangements which may result from government mandates such as the statutory emission mandates imposed on automobile manufacturers and industrial facilities (e.g., power plants). It also excludes PPP-like organizations resulting from US section 501(c)(3) of the Internal Revenue Code, which provides tax subsidies for certain public charities, scientific research organizations, and organizations whose goals are to prevent cruelty to animals or erect public monuments at no expense to the government. This paper concludes that an array of Public Choice tools are applicable to understanding the emergence, success, or failure of PPPs. Several short case studies are provided to illustrate the practicalities of PPPs.
Agroforestry holds the key in providing alternative economically viable livelihood development and to support mountainous farmers to adapt to climate change. Innovative agroforestry interventions integrating animal production, horticulture etc into cropping systems exist that can help farmers improve yields and build resilience for supporting livelihoods particularly among marginal communities. But, the lack of knowledge, technical know-how and other information among the farmers are major barriers in adoption of agroforestry. Millions of the farmers of mountainous regions are already wrestling with water scarcity, which would be more severe in climate change scenario. The Himalayan regions are have been considered to be highly sensitive to climate change. Indeed, Innovative agroforestry interventions have the potential to conserve natural resources, improve productivity and provide resilience to climate change. The present paper highlights the need for developing innovative agroforestry interventions to promote various alternate livelihood options through diversification, adoption of high yielding varieties and development of innovative products from forest resources. Of these spice based agroforetry, silvi-medicinal systems, Van silk cultivation, bamboo and ringal cultivation and development and use of farm resources based products like bamboo based composite structures, Seabuckthorn herbal tea, Ghingaroo juice (Crataegus crenulata) and incense products etc holds a promising potential to be explored as better options for future scenario.
It increased the demands on ground-water supplies that prolonged drought and improper maintenance of water resources. So it is necessary to evaluate ground-water resources in the hard rock terrain. In recent years, Remote-Sensing methods have been increasingly recognized as a means of obtaining crucial geoscientific data for both regional and site-specific investigations. This work aims to develop and apply integrated methods combining the information obtained by geo-hydrological field mapping and those obtained by analyzing multi-source remotely sensed data in a GIS environment for better understanding the Groundwater condition in hard rock terrain. In this study, digitally enhanced Landsat ETM+ data was used to extract information on geology, geomorphology. The Hill-Shading techniques are applied to SRTM DEM data to enhance terrain perspective views, and extract Geomorphological features and morphologically defined structures through the means of lineament analysis. A combination of Spectral information from Landsat ETM+ data plus spatial information from SRTM-DEM data is used to address the groundwater potential of alluvium, colluvium, and fractured crystalline rocks in the study area. The spatial distribution of groundwater potential zones shows regional patterns related to lithologies, lineaments, drainage systems, and landforms. High-yielding wells and springs are often related to large lineaments and corresponding structural features such as dykes. The results show that the combination of remote sensing, GIS, traditional fieldwork, and models provide a powerful tool for water resources assessment and management, and groundwater exploration planning.
Polymers obtained from renewable sources are gaining popularity over their petroleum based counter parts in recent years due to their capability to address the environmental pollution related concerns emanating from the widespread usage of synthetic polymers. Even though the polymers from renewable sources are attractive in an environmental point of view, some of the property limitations and the high cost of these materials pose limitations for their extensive commercial applications. These aspects opened the door for a large chunk of research activities in development of polyblends and composites containing polymers from renewable sources as one of the components. Poly (lactic acid) (PLA) is one of the most discussed and commercialized polymer originated from renewable resources. Even though it has many useful properties, certain disadvantages like high brittleness, low impact resistance etc. limit the wide spread commercialization of PLA. In this review article, the recent research activities which are aimed to fill this gap by various modifications of PLA are discussed with special emphasis on the latest research advancements in the field of biodegradable and non biodegradable systems containing PLA.
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