Due to rising global environmental challenges, air/water pollution treatment technologies, especially membrane techniques, have been focused on. In this context, air or purification membranes have been considered effective for environmental remediation. In the field of polymeric membranes, high-performance polymer/graphene nanocomposite membranes have gained increasing research attention. The polymer/graphene nanomaterials exposed several potential benefits when processed as membranes. This review explains the utilization of polymer and graphene-derived nanocomposites towards membrane formation and water or gas separation or decontamination properties. Here, different membrane designs have been developed depending upon the polymer types (poly(vinyl alcohol), poly(vinyl chloride), poly(dimethyl siloxane), polysulfone, poly(methyl methacrylate), etc.) and graphene functionalities. Including graphene in polymers influences membrane microstructure, physical features, molecular permeability or selectivity, and separations. Polysulfone/graphene oxide nanocomposite membranes have been found to be most efficient with an enhanced rejection rate of 90%–95%, a high water flux >180 L/m2/h, and a desirable water contact angle for water purification purposes. For gas separation membranes, efficient membranes have been reported as polysulfone/graphene oxide and poly(dimethyl siloxane)/graphene oxide nanocomposites. In these membranes, N2, CO2, and other gases permeability has been found to be higher than even >99.9%. Similarly, higher selectivity values for gases like CO2/CH4 have been observed. Thus, high-performance graphene-based nanocomposite membranes possess high potential to overcome the challenges related to water or gas molecular separations.
Naturally occurring radionuclides can be categorized into two main groups: primordial and cosmogenic, based on their origin. Primordial radionuclides stem from the Earth’s crust, occurring either individually or as part of decay chains. Conversely, cosmogenic radionuclides originate from extraterrestrial sources such as space, the sun, and nuclear reactions involving cosmic radiation and the Earth’s atmosphere. Gamma-ray spectrometry is a widely employed method in Earth sciences for detecting naturally occurring radioactive materials (NORM). Its applications vary from environmental radiation monitoring to mining exploration, with a predominant focus on quantifying the content of uranium (U), thorium (Th), and potassium (K) in rocks and soils. These elements also serve as tracers in non-radioactive processes linked to NORM paragenesis. Furthermore, the heat generated by radioactive decay within rocks plays a pivotal role in deciphering the Earth’s thermal history and interpreting data concerning continental heat flux in geophysical investigations. This paper provides a concise overview of current analytical and measuring techniques, with an emphasis on state-of-the-art mass spectrometric procedures and decay measurements. Earth scientists constantly seek information on the chemical composition of rocks, sediments, minerals, and fluids to comprehend the vast array of geological and geochemical processes. The historical precedence of geochemists in pioneering novel analytical techniques, often preceding their commercial availability, underscores the significance of such advancements. Geochemical analysis has long relied on atomic spectrometric techniques, such as X-ray fluorescence spectrometry (XRFS), renowned for its precision in analyzing solid materials, particularly major and trace elements in geological samples. XRFS proves invaluable in determining the major constituents of silicate and other rock types. This review elucidates the historical development and methodology of these techniques while showcasing their common applications in various geoscience research endeavors. Ultimately, this review aims to furnish readers with a comprehensive understanding of the fundamental concepts and potential applications of XRF, HPGes, and related technologies in geosciences. Lastly, future research directions and challenges confronting these technologies are briefly discussed.
Water scarcity, particularly in arid and semi-arid regions, is a critical issue affecting forest management. This study investigates the effects of drought stress on the water requirement and morphological characteristics of two important tree species Turkish pine and Chinaberry. Using a factorial design, the study examines the impact of three age stages (one-year-old, three-year-old, and five-year-old plants) and three levels of drought stress on these species. Microlysimeters of varying sizes were employed to simulate different drought conditions. Soil moisture was monitored to show the effect of the various irrigation schedules. The study also calculated reference crop evapotranspiration (ET0) using the PMF-56 method and developed plant coefficients (Kc) for the species. Results showed that evapotranspiration increased with soil moisture, peaking during summer and decreasing in winter. Turkish pine exhibited higher plant ET than Chinaberry, particularly among one-year-old seedlings. Drought stress significantly reduced evapotranspiration and water uses for both species, highlighting the importance of efficient water management in afforestation projects. The findings underscore the necessity of selecting drought-resistant species and optimizing irrigation practices to enhance the sustainability of green spaces in arid regions. These insights are crucial for improving urban forestry management and mitigating the impacts of water scarcity in Iran and similar climates globally.
Flood risk analysis is the instrument by which floodplain and stormwater utility managers create strategic adaptation plans to reduce the likelihood of flood damages in their communities, but there is a need to develop a screening tool to analyze watersheds and identify areas that should be targeted and prioritized for mitigation measures. The authors developed a screening tool that combines readily available data on topography, groundwater, surface water, tidal information for coastal communities, soils, land use, and precipitation data. Using the outputs of the screening tool for various design storms, a means to identify and prioritize improvements to be funded with scarce capital funds was developed, which combines the likelihood of flooding from the screening tool with a consequence of flooding assessment based on land use and parcel size. This framework appears to be viable across cities that may be inundated with water due to sea-level rise, rainfall, runoff upstream, and other natural events. The framework was applied to two communities using the 1-day 100-year storm event: one in southeast Broward County with an existing capital plan and one inland community with no capital plan.
Soil salinity is a major abiotic stress that drastically hinders plant growth and development, resulting in lower crop yields and productivity. As one of the most consumed vegetables worldwide, tomato (Solanum lycropersicum L.) plays a key role in the human diet. The current study aimed to explore the differential tolerance level of two tomato varieties (Rio Grande and Agata) to salt stress. To this end, various growth, physiological and biochemical attributes were assessed after two weeks of 100 mM NaCl treatment. Obtained findings indicated that, although the effects of salt stress included noticeable reductions in shoots’ and roots’ dry weights and relative growth rate as well as total leaf area, for the both cultivars, Rio Grande performed better compared to Agata variety. Furthermore, despite the exposure to salt stress, Rio Grande was able to maintain an adequate tissue hydration and a high leaf mass per area (LMA) through the accumulation of proline. However, relative water content, LMA and proline content were noticeably decreased for Agata cultivar. Likewise, total leaf chlorophyll, soluble proteins and total carbohydrates were significantly decreased; whereas, malondialdehyde was significantly accumulated in response to salt stress for the both cultivars. Moreover, such negative effects were remarkably more pronounced for Agata relative to Rio Grande cultivar. Overall, the current study provided evidence that, at the early growth stage, Rio Grande is more tolerant to salt stress than Agata variety. Therefore, Rio Grande variety may constitute a good candidate for inclusion in tomato breeding programs for salt-tolerance and is highly recommended for tomato growers, particularly in salt-affected fields.
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