Recent research efforts have increasingly concentrated on creating innovative biomaterials to improve bone tissue engineering techniques. Among these, hybrid nanomaterials stand out as a promising category of biomaterials. In this study, we present a straightforward, cost-efficient, and optimized hydrothermal synthesis method to produce high-purity Ta-doped potassium titanate nanofibers. Morphological characterizations revealed that Ta-doping maintained the native crystal structure of potassium titanate, highlighting its exciting potential in bone tissue engineering.
Nanoparticle V2O5 is prepared by the measurement of X-ray diffraction (XRD) and atomic force microscopy (AFM) analyses. The crystallite size = 19.59 nm, optical energy gap = 2.6 eV, an average particle size of 29.58 nm and, RMS roughness of ~6.8 nm. Also, Fourier transformer infrared spectrophotometer (FTIR) showed a porous free morphology with homogeneity and uniformity on the sample surface. The film surface exhibited no apparent cracking and, the grains exhibited large nicely separated conical columnar growth combined grains throughout the surface with coalescence of some columnar grains at a few places. The fabrication of a thin film of V2O5 NPs/PSi heterojunction photodetector was characterized and investigated.
Disease epidemics may spread quickly and easily throughout nations and continents in our current global environment, having a devastating effect on public health and the world economy. There are over 513 million people worldwide who have been infected, and more than 6.2 million have died due to SARS-CoV-2. There are treatments but no cures for most viruses. Nevertheless, the spread of viruses can be limited by introducing antiviral coatings on public area surfaces and personal protective equipment (e.g., face masks). This work aims to fabricate a polymer-based coating with acrylic resin as a binder that possesses great antiviral activity against the Feline coronavirus (FCov). The chosen polymer, polyethylene glycol (PEG), is used as an antiviral agent because it contains “green” chemistry benefits such as non-toxicity, being inexpensive, readily recyclable, safe, natural, non-flammable, biocompatible, and biodegradable. The PEG/acrylic coating systems of different weight percentages were coated on the glass substrates by the spray-coating method and cured at room temperature for 24 hours. The developed PEG/acrylic coating system that contains 20 wt% of PEG exhibits the highest anti-viral activities (99.9% against FCov) compared to the other weight percentages. From this study, it has been observed that the hydrophilicity of the coating plays an important role in its antiviral activity. The developed coating has a hydrophilic property, in which the contact angle was measured at 83.28 ± 0.5°. The FTIR reveals that there are no existing toxic components or new components contained in the coating samples.
In the present work, a series of butyl methacrylate/1-hexene copolymers were synthesized, and their efficiency as viscosity index improvers, pour point depressants, and shear stabilizers of lube oil was investigated. The effect of 1-hexene molar ratio, type, and concentration of Lewis acids on the incorporation of 1-hexene into the copolymer backbone was investigated. The successful synthesis of the copolymers was confirmed through FTIR and 1H NMR spectroscopy. Results obtained from quantitative 1H NMR and GPC revealed that an increase in the molar ratio of 1-hexene to butyl methacrylate, along with concentration of Lewis acids led to an increase in 1-hexene incorporation and a reduction in Mn and Ð. Similar trends were observed when the Lewis acid changed from AlCl3 to organometallic acids. The maximum 1-hexene incorporation (26.4%) was achieved for sample BHY3, with a [1-hexene/BMA] ratio of 4 mol% and a [Yb(OTf)3/BMA] ratio of 2.5 mol%. Evaluation of the synthesized copolymers as lube oil additives demonstrated that the viscosity index was more significantly influenced by samples with higher molecular weight. Sample BHA13 represents maximum VI of 137. The copolymer containing Yb(OTf)3 as a catalyst exhibited superior efficiency as a pour point depressant. Furthermore, sample BHY3 showed the lowest shear stability index (6.4).
Water splitting has been one of the potential techniques as a clean and renewable energy resource for the fulfillment of world energy demands. One of the major aspects of this procedure is the exploitation of efficient and inexpensive electrocatalysts due to the fact that the water oxidation procedure is accompanied by a delayed reaction. In this research, ZnO-CoFe2O4 nanostructure was successfully synthesized via the green method and green resources from cardamom seeds and ginger peels for oxygen evolution reaction (OER). The modified Glassy carbon electrode (GCE) with ZnO-CoFe2O4 is effective for the electrochemical water oxidation interaction since it has sufficient electrical strength and excellent catalytic performance. The creation of rice-like and small granular structures of ZnO-CoFe2O4 nano-catalysts was confirmed by characterization methods such as XRD, FESEM, EDS and MAP. According to the achieved results, in the electrolysis of water, with in-cell voltage of 1.40 V and 50 mA cm–2 for current density in a 0.1 M KOH electrolyte and OER only has 170 mV overpotentials.
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