Work is reported on thermal-induced redshifts of quantum particle plasmon. The redshifts are predicted to be caused indirectly by the quantum size effects. The particles are enlarged when temperature increases, and consequently, quantum size effects modify the plasmon but not the band structure. It has been modeled for metallic quantum particles. The results are also instructive to other quantum systems, such as complex molecules. Every electron inside the quantum particle is taken into account. Tiny quantum size effects are harvested, and the redshift becomes significant. Experimental evidence is also given for the spectral redshift. Faujasite zeolites were synthesized. Optical spectroscopy has been carried out, and the resulting spectra showed a significant redshift with the increase in temperature.

Afforestation is a main tool for preventing desertification and soil erosion in arid and semiarid regions of Iran. Large-scale afforestation, however, has poorly understood consequences for the future ecosystems in the term of ecosystems protection. The objective of the present study is to identify changes in soil properties following different intervals of planting of Ailanthus altissima (tree of heaven) in semiarid afforestation of Iran (Chitgar Forest Park, Tehran). For this purpose, sand, silt and clay ratios, bulk density, soil moisture, pH, electrical conductivity, phosphorus, potassium, magnesium, calcium, sodium, total soil N, and total carbon was measured. Our study highlighted the potential of the invasive trees by A. altissima, to alter soil properties along chronosequence. Almost all soil quality attributes showed a declining trend with stand age. A continuous decline in soil quality indicated that the present land management may not be sustainable. Therefore, an improved management practice is imperative to sustain soil quality and maintain long-term productivity of plantation forests. Thinning activity will be required to reduce the number of trees competing for the same nutrients especially in a older stand to protect forest soils.

The regulation of compressor extraction and energy storage can improve the performance of gas turbine energy system. In order to make the gas turbine system match the external load more flexibly and efficiently, a gas turbine cogeneration system with solar energy coupling compressor outlet extraction and energy storage is proposed. By establishing the variable condition mathematical model of air turbine, waste heat boiler and solar collector, we use Thermoflex software to establish the variable condition model of gas turbine compressor outlet extraction, and analyze the variable condition of the coupling system to study the changes of thermal parameters of the system in the energy storage, energy release and operation cycle. Taking the hourly load of a hotel in South China as an example, this paper analyzes the case of the cogeneration system of solar energy coupling compressor outlet extraction and energy storage, and compares it with the benchmark cogeneration system. The results show that taking a typical day as a cycle, the primary energy utilization rate of the system designed in this paper is 3.2% higher than that of the traditional cogeneration system, and the efficiency is 2.4% higher.

Small watershed ecological compensation is an important economic means to solve the contradiction between protecting the ecological environment and developing the economy. Taking the Changtian small watershed in the Xixiu District of Anshun City as an example, this paper uses the ecological service function value method to roughly calculate the ecological service function value of the small watershed ecosystem: the ecological service function value of the Changtian small watershed is 913.586 million yuan, and the total amount of ecological compensation is 11.6245 million yuan, of which the farmland system compensation is 1.3194 million yuan, the forest system compensation is 7.5336 million yuan, and the water system compensation is 256,000 yuan, The compensation for the fruit forest system is 2,515,500 yuan. Based on the value of ecosystem service function, the compensated and non-compensated ecosystem service functions are distinguished, and the equivalent factors that different ecosystems can provide compensated ecosystem functions are expressed, so that the determination of ecological compensation amount is scientific and more accurate, and then provides a basis for the determination of ecological compensation standard of the small watershed.

The effects of Zn2+ stress on seed germination, seedling growth and chlorophyll content were studied in order to better understand the effect of heavy metal Zn on the growth and development of green plants. The concentration gradient of Zn2+ was 20, 50,100,150,200,300,500,700mg / L, and deionized water was used as control. The results showed that under the Zn2+ stress condition, the germination index of the rhubarb seeds increased with the increase of Zn2+ concentration. Germination potential, germination rate and germination index were the highest when Zn2+concentration was 100mg / L, the conductivity was the lowest at zinc concentration of 100mg / L, the root length, stem length and chlorophyll content of Zn2+ gradually reduced. The results showed that the amount of Zn2+ could promote seed germination, but the root length, bud length and chlorophyll content of seedlings could be affected by different degrees. The zinc fertilizer should be used in the production.

Alginate-silver nanocomposites in the form of spherical beads and films were prepared using a green approach by using the aqueous extract of Ajwa date seeds. The nanocomposites were fabricated by in situ reduction and gelation by ionotropic crosslinking using calcium ions in solution. The rich phytochemicals of the date seed extract played a dual role as a reducing and stabilizing agent in the synthesis of silver nanoparticles. The formation of silver nanoparticles was studied using UV-Vis absorption spectroscopy, and a distinct surface plasmon resonance peak at 421 nm characteristic of silver nanoparticles confirmed the green synthesis of silver nanoparticles. The morphology of the nanocomposite beads and film was compact, with an even distribution of silver nanoclusters. The catalytic property of the nanocomposite beads was evaluated for the degradation of 2-nitrophenol in the presence of sodium borohydride. The degradation followed pseudo-first-order kinetics with a rate constant of 1.40 × 10⁻³ s⁻¹ at 23 ℃ and an activation energy of 18.45 kJ mol⁻¹. The thermodynamic parameters, such as changes in enthalpy and entropy, were evaluated to be 15.22 kJ mol⁻¹ and −197.50 J mol⁻¹ K⁻¹, respectively. The nanocomposite exhibited properties against three clinically important pathogens (gram-positive and gram-negative bacteria).