In this study, the influence of sewage sludge ash (SSA) waste particle contents on the mechanical properties and interlaminar fracture toughness for mode I and mode II delamination of S-glass fiber-reinforced epoxy composites was investigated. Composite laminate specimens for tensile, flexural double-cantilever beam (DCB), and end-notched fracture (ENF) tests were prepared and tested according to ASTM standards with 5, 10, 15, and 20 wt% SSA-filled S-glass/epoxy composites. Property improvement reasons were explained based on optical and scanning electron microscopy. The highest improvement in tensile and flexural strength was obtained with a 10 wt% content of SSA. The highest mode I and mode II interlaminar fracture toughness’s were obtained with 15 wt% content of SSA. The mode I and mode II interlaminar fracture toughness improved by 33% and 63.6%, respectively, compared to the composite without SSA.
The problem of the synthesis of new type nanomaterials in the form of nano-coatings with sub-nanometric heterogeneity has been formulated. It has been presented an analysis of influences of physical vapor deposition in ultrahigh vacuum on the process of intermixing a film with a substrate, including the results, which has been obtained under the formation of transition metal – silicon interface. The generalization of the obtained experimental results develops an approach to the development of new nano-coatings with low-dimensional heterogeneity. The principles of constructing such low-dimensional nano-coatings, their properties and possible applications are considered.
A metakaolin-based geopolymer was fabricated with 5 ratios of two different nanomaterials. On the one hand, silicon carbide nanowhiskers and, on the other hand, titanium dioxide nanoparticles. Both were placed in water and received ultrasonic energy to be dispersed. The effects on mechanical properties and reaction kinetics were analyzed. Compared to the reference matrix, the results showed a tendency to increase the flexural strength. Probably due to the geometry of the SiC nanowhiskers and the pore refinement by the nano-TiO2 particles. The calorimetry curves showed that incorporating TiO2 nanoparticles resulted in a 92% reduction in total heat, while SiC nanowhiskers produced a 25% reduction in total heat.
Root turnover is a key process of terrestrial ecosystem carbon cycle, which is of great significance to the study of soil carbon pool changes and global climate change. However, because there are many measurement and calculation methods of root turnover, the results obtained by different methods are quite different, and the current research on root turnover of forest ecosystem on the global regional scale is not sufficient, so the change law of root turnover of global forest ecosystem is still unclear. By collecting literature data and unifying the calculation method of turnover rate, this study integrates the spatial pattern of fine root turnover of five forest types in the world, and obtains the factors affecting fine root turnover of forest ecosystem in combination with soil physical and chemical properties and climate data. The results showed that there were significant differences in fine root turnover rate among different forest types, and it gradually decreased with the increase of latitude; the turnover rate of fine roots in forest ecosystem is positively correlated with annual average temperature and annual average precipitation; fine root turnover rate of forest ecosystem is positively correlated with soil organic carbon content, but negatively correlated with soil pH value. This study provides a scientific basis for revealing the law and mechanism of fine root turnover in forest ecosystem.
Despite Cameroon’s immense sand reserves, several enterprises continue to import standardized sands to investigate the properties of concretes and mortars and to guarantee the durability of built structures. The present work not only falls within the scope of import substitution but also aims to characterize and improve the properties of local sand (Sanaga) and compare them with those of imported standardized sand widely used in laboratories. Sanaga sand was treated with HCl and then characterized in the laboratory. The constituent minerals of Sanaga sand are quartz, albite, biotite, and kaolinite. The silica content (SiO2) of this untreated sand is 93.48 wt.%. After treatment, it rose 97.5 wt.% for 0.5 M and 97.3 wt.% for 1 M HCl concentration. The sand is clean (ES, 97.67%–98.87%), with fineness moduli of 2.45, 2.48, and 2.63 for untreated sand and sand treated with HCl concentrations of 0.5 and 1 M respectively. The mechanical strengths (39.59–42.4 MPa) obtained on mortars made with untreated Sanaga sand are unsatisfactory compared with those obtained on mortars made with standardized sand and with the expected strengths. The HCl treatment used in this study significantly improved these strengths (41.12–52.36 MPa), resulting in strength deficiencies of less than 10% after 28 curing days compared with expected values. Thus, the treatment of Sanaga sand with a 0.5 M HCl concentration offers better results for use as standardized sand.
The agronomic use of mushroom post-harvest substrates (SPCHs) in horticultural seedbeds could be an interesting alternative for the reuse of these wastes in line with the European circular economy strategy. This work evaluates the potential use of four treatments with different SPCHs, mushroom (-Ch), mushroom (-St), mushroom compost (-CO), and a mixture (SPCH-Ch and SPCH-St) as substrates for lettuce and chili pepper seed germination. The trial was carried out in a germination chamber using commercial compost as a control treatment. The evaluation was based on its chemical (salinity, N and C content), physical (bulk and real density, porosity and water retention) and plant effect (germination and biomass) characteristics. Of the chemical properties studied, the high salinity in SPCH-Ch and SPCH-CO was a limiting factor for the development of the horticultural species evaluated (electrical conductivity 1:2.5; p/v; ~11 dS m-1), and low germination percentages were observed. Regarding physical properties, porosity and water retention, the SPCH-CO, SPCH-St and mixture treatments presented some values outside the optimal range established for germination substrates. In the case of SPCH-St, its high C/N ratio could be a limitation for supplying N to the crop. In relation to biomass production (aerial and root) of lettuce and chili pepper, all the treatments evaluated obtained similar values to the control treatment. The mixed treatment presented the highest biomass values, significantly higher in the lettuce crop. In general, the mixed treatment proved to be the best alternative for use in the seedbed.
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