Knowledge of the presence of heavy metals in soils of agricultural areas is important to prevent their accumulation in cultivated plants. The objective of the present investigation was to evaluate the total concentrations and fractions of heavy metals Cd, Pb, Zn, Fe, Mn, Ni, Cu, Cr and Co in the tobacco-growing area of Pinar del Río, Cuba and their relationship with the physicochemical properties of soil. For the study, 59 samples of three types of soils were collected at 20 cm depth. The pseudo-total concentrations of metals in the soils are low and lower than the prevention values registered for Cuban soils. In general, the heavy metals studied present a high affinity for the most stable fractions of the soil, which means a low risk of transfer to the tobacco crop or accumulation in groundwater. The pseudo-total concentrations of heavy metals were low, below the alert values established for soils in the region. The heavy metals studied were mainly associated with the residual fraction, the second fraction with the highest association with metals was that linked to manganese and iron oxides. The principal component analysis showed that their main source is pedogenetic and that these elements are closely related to cation exchange capacity and calcium content.
Rambutan (Nephelium lappaceum L.) was introduced to Mexico in 1959. Currently there is an estimated planted area of 835.96 ha and a production of 8,730.27 tons. The fruit is mainly consumed fresh, but quickly loses its external appearance due to dehydration and browning, which limits its commercialization, an alternative may be minimal processing and adjuvant treatments that extend the shelf life. The objective of this work was to evaluate the effect of coating with cactus mucilage (Opuntia ficus-indica), in the preservation of minimally processed rambutan stored at 5 °C, in two types of packaging. The rambutan was sanitized with chlorinated water (80 ppm), the epicarp was removed and batches were formed for each treatment. The factors were type of container (polyethylene bag and polystyrene container), coating (with and without coating) and time (0, 3, 6, 6, 10 and 12 d). The coating consisted of mucilage obtained from developing cladodes (15–21 cm), applied by dipping. All treatments were stored at 5 ℃. Total soluble solids (TSS), firmness (N) and color (L*, a*, b*, chroma and hue angle) were evaluated at each storage period. Also, 40 untrained judges (47% male and 53% female) evaluated sensory acceptability, consumption intention and acceptance/rejection. The results showed significant effect (p ≤ 0.05) of package type on firmness, chroma and hue angle. Coating had an effect on L* value and product acceptability. Consumption intention was higher, and was maintained for 10 days, in fruits with coating and packaged in polyethylene bags, stored at 5 ℃.
The structure, thermodynamic stability, ionization potential (IP) and electron affinity (EA) energy level difference (Eg) and tension of lowest unoccupied orbit (LUMO) and highest occupied orbit (HOMO) of armchair single wall carbon nanotubes (C-NTs), BN hybrid carbon nanotubes (BC2N-NTs) and all BN nanotubes (BN-NTs) were systematically studied with AM1 method in this paper. Calculation results show that when n value is constant, (n, n) C-NTs (n = 3,4,5,6) has the largest diameter and BN-NTs has the smallest diameter; (n, n) the values of Eg (HOMO-LUMO) and n of C-NTs and BC2N-NTs are related; POAV analysis shows that different hybrid atoms have different contributions to the hybrid mode of nanotube atoms and the tension of nanotubes.
With the purpose of strengthening the knowledge and prevention of landslide disasters, this work develops a methodology that integrates geomorphological mapping with the elaboration of landslide susceptibility maps using geographic information systems (GIS) and the multiple logistic regression method (MLR). In Mexico, some isolated works have been carried out with GIS to evaluate slope stability. However, to date, no practical and standardized method has been developed to integrate geomorphological maps with landslide inventories using GIS. This paper shows the analysis carried out to develop a multitemporal landslide inventory together with the morphometric analysis and mapping technique for the El Estado River basin where, selected as the study area, is located on the southwestern slope of the Citlaltepetl or Pico de Orizaba volcano. The geological and geomorphological factors in combination with the high seasonal precipitation, the high degree of weathering and the steep slopes predispose its surfaces to landslides. To assess landslide susceptibility, a landslide inventory map was prepared using aerial photographs, followed by geomorphometric mapping (altimetry, slopes and geomorphology) and field work. With this information, landslide susceptibility was modeled using multiple logistic regression (MLR) within a GIS platform and the landslide susceptibility map was obtained.
The wide distribution of the common beech (Fagus sylvatica) in Europe reveals its great adaptation to diverse conditions of temperature and humidity. This interesting aspect explains the context of the main objective of this work: to carry out a dendroclimatic analysis of the species Fagus sylvatica in the Polaciones valley (Cantabria), an area of transition with environmental conditions from a characteristic Atlantic type to more Mediterranean, at the southern limit of its growth. The methodology developed is based on the analysis of 25 local chronologies of growth rings sampled at different altitudes along the valley, generating a reference chronology for the study area. Subsequently, the patterns of growth and response to climatic variations are estimated through the response and correlation function, and the most significant monthly variables in the annual growth of the species are obtained. Finally, these are introduced into a Geographic Information System (GIS) where they are cartographically modeled in the altitudinal gradient through multivariate analysis, taking into account the different geographic and topographic variables that influence the zonal variability of the species response. The results of the analyses and cartographic models show which variables are most determinant in the annual growth of the species and the distribution of its climatic response according to the variables considered.
Magnetite magnetic nanoparticles (MNP) exhibit superparamagnetic behavior, which gives them important properties such as low coercive field, easy superficial modification and acceptable magnetization levels. This makes them useful in separation techniques. However, few studies have experimented with the interactions of MNP with magnetic fields. Therefore, the aim of this research was to study the influence of an oscillating magnetic field (OMF) on polymeric monolithic columns with vinylated magnetic nanoparticles (VMNP) for capillary liquid chromatography (cLC). For this purpose, MNP were synthesized by coprecipitation of iron salts. The preparation of polymeric monolithic columns was performed by copolymerization and aggregation of VMNP. Taking advantage of the magnetic properties of MNP, the influence of parameters such as resonance frequency, intensity and exposure time of a OMF applied to the synthesized columns was studied. As a result, a better separation of a sample according to the measured parameters was obtained, so that a column resolution (Rs) of 1.35 was achieved. The morphological properties of the columns were evaluated by scanning electron microscopy (SEM). The results of the chromatographic properties revealed that the best separation of the alkylbenzenes sample occurs under conditions of 5.5 kHz and 10 min of exposure in the OMF. This study constitutes a first application in chromatographic separation techniques for future research in nanotechnology.
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