Broad-spectrum antibiotics, such as tetracyclines, are used to treat and manage a range of infectious disorders. Since the kidneys are the primary organs responsible for excreting tetracyclines, clinicians should refrain from prescribing them to patients who have renal failure. Tetracyclines are one of the clinical waste products of today. One of the biggest problems in the field of pollution of the environment today is the persistence of different pharmaceutical residues, drug residues, pesticides, and metal ion species of the new-generation pollutants in surfaces and groundwater. In the present work, carboxymethyl cellulose (CMC)-CuO nanoparticles (CMC-CuO NPs) were synthesized using CuO NPs within different amounts of CMC (0.5, 1.0, 1.5 and 2.0 g) at 85 °C. The synthesized nanoparticles were characterized by XRD, FT IR, SEM, and TG-DTA analysis. According to XRD and SEM, the crystallize size and morphology influenced the dosage of CMC. FT-IR analysis confines the layer of CMC to the CuO nanoparticle surface. TG-DTA results indicated that the CMC content of CMC-CuO NPs was between the range of 69% and 75% by weight. The effects of some parameters such as initial concentration, pH, adsorbent dosage, and contact time on the adsorption of tetracycline from aqueous model solutions on CMC-CuO NPs were investigated with batch studies. It was found that the removal of tetracycline was obtained about 80% with optimized parameters of 10 mg/L concentration, 180 min contact time, 5 pH, and 0.3 g/25 mL dose. The synthesized CMC-CuO NPs nanocomposite may be a promising material for the removal of tetracycline in environmental pollution and toxicology.

Three-dimensionally cross-linked polymer nanocomposite networks coated nano sand light-weight proppants (LWPs) were successfully prepared via ball-milling the macro sand and subsequently modifying the resultant nano sand with sequential polymer nanocomposite coating. The modified nano sand proppants had good sphericity and roundness. Thermal analyses showed that the samples can withstand up to 411 ℃. Moreover, the proppant samples’ specific gravity (S.G.) was 1.02–1.10 g/cm³ with excellent water dispersibility. Therefore, cross-linked polymer nanocomposite networks coated nano sand particles can act as potential candidates as water-carrying proppants for hydraulic fracturing operations.

This article refers to Hallstatt in Austria and Ioannina in Greece. The goals analyze the two locations that have similarities in geometric shape, digital elevation model (DEM), and geomorphology. Firstly, Hallsatt’s advances were more technical than aesthetic. There is a general tendency towards extravagance and baroque and Greco-Oriental influences. Secondly, Ioannina is a mountainous city located around Lake Pamvotis. The geometry develops parallel to the lake. The city experiences many cultures. The ancient city had an urban planning that characterized the Ottoman Empire. In the old part, there is the castle, old stone streets, wooden houses, and the house of the Greek Muslim Ali Pasha. The author obtains numerous aerial photographs using Google Earth software. The photographs were received dynamically for all the perimeters of the regions. In short, the cartographer has between 15 and 20 photographs. The next step is to align the photographs in Zephyr photogrammetry software. Configuring resolutions, distance, camera locations, contrast, and brightness is essential. The final products are the 3D texture, 3D model, and orthophotos from Hallstatt and Ioannina. Digital products are suitable for measuring areas, circumferences, and heights. Furthermore, digital products represent a digital archiving practice: conservation and visualization are crucial factors today as they share, represent, promote, and document urban planning, historical memory, and the natural environment.

By carrying out a laboratory experiment, the influence of priming methods, including ZnSO4, BSN, and hydropriming was evaluated on the seed germination of hybrid AS71 corn. Then, the main and interaction effects of the priming methods, planting dates, and weed interference levels were surveyed on the vegetative growth traits, yield, and yield components of corn in a field experiment. Based on the lab experiment, although the maximum germination percentage (100%) was observed in the treated plots by hydropriming 22 h after treatment (HAT), the greatest seedling vigor index (122.99) was recorded with treated seeds by ZnSO4 (0.03 mg L–1) at 8 HAT. The greatest emergence index was observed in the treated plots by hydropriming on both planting dates of June 1 and 11. The interaction of planting dates and weed interference levels revealed that the highest emergence index (14%–17%) occurred in the weed-free plots on both planting dates. BSN recorded the greatest corn 1000-grain weight that was significantly higher than the control plots by 28%. Furthermore, BSN enhanced the corn grain yield compared with the control plots by 63% and 24.9% on the planting dates of June 1 and 11, respectively. BSN, as a nutri-priming approach, by displaying the highest positive effects in boosting the corn grain yield in both weedy and weed-free plots as well as both planting dates, could be a recommendable option for growers to improve the crop yield production.