In order to explore the influence of the ferroelectric surface on the structure and properties of semiconductor oxides, the growth of CdS nanocrystals was regulated and controlled by taking single-crystal perovskite PbTiO3 nanosheets as the substrate through a simple hydrothermal method. Through composition design, a series of PbTiO3-CdS nanocomposite materials with different loading concentrations were prepared, and their microstructure and photocatalytic properties were systematically analyzed. Studies show that in the prepared product, CdS nanoparticles selectively grow on the surfaces of PbTiO3 nanosheets, and their morphology is affected by the exposed surfaces of PbTiO3 nanosheets. There is a clear interface between the PbTiO3 substrate and CdS nanoparticles. The concentration of the initial reactant and the time of hydrothermal reaction also significantly affect the crystal morphology of CdS. Photocatalysis studies have shown that the prepared PbTiO3-CdS nanocomposite material has a significant degradation effect on 10 mg/L of Rhodamine B aqueous solution. The degradation efficiency rises with the increase of CdS loading concentration. When degrading 10 mg/L Rhodamine B aqueous solution, the PbTiO3-CdS sample with a mass fraction of 3% can reach a degradation rate of 72% within 120 min.
In order to scientifically evaluate the germplasm resources of Momordica charantia in southern China, the diversity, correlation and cluster analysis were carried out on the main botanical characters of 56 Momordica charantia varieties, such as melon length, melon transverse diameter, single melon weight, internode length, stem diameter, leaf length and leaf width. The results showed that the variation coefficients of 7 agronomic characters of 56 Momordica charantia varieties ranged from 8.81% to 19.44%, the average variation coefficient was 14.21%, the maximum variation coefficient of single melon weight was 19.44%, and the minimum variation coefficient of melon cross diameter was 8.81%. The correlation analysis showed that there were correlations among the agronomic traits. The positive correlation coefficient between leaf length and leaf width was up to 0.978, and the negative correlation coefficient between single melon weight and internode length was up to 0.451. The 56 varieties were divided into 3 groups by cluster analysis, of which 92.86% of the materials were concentrated in the first and second groups, and there were only 4 materials in the third group. The results can provide a reference for the cultivation, utilization and genetic improvement of Momordica charantia resources in southern China.
The effects of different storage temperatures (2, 4 and 8 ℃) and their corresponding optimal heat treatment conditions on the quality, physiological and biochemical indexes of Cucumber Fruits during storage were studied by using the quadratic regression orthogonal rotation combination design. The effects of different storage temperatures (2, 4 and 8 ℃) and their corresponding optimal heat treatment conditions on the chilling injury, hardness, weightlessness rate, polyphenol oxidase (PPO), catalase (CAT), peroxidase (POD), H2O2, super oxygen anion free radical (O2-), ASA and GSH were determined. The results showed that heat treatment could inhibit chilling injury, while heat treatment combined with 4 ℃ low temperature storage could effectively inhibit the decline of fruit hardness and weight loss rate, delay the increase of peroxidase (POD) and polyphenol oxidase (PPO) activities, inhibit the increase of H2O2 and superoxide anion free radical O2- and significantly inhibit the browning of cucumber, delay the decline of ascorbic acid and maintain the content of GSH, it was beneficial to adjust the balance of active oxygen system. The results showed that under the storage condition of 4 ℃, the hot water treatment condition of cucumber was 39.4 ℃ and 24.3 min, which could delay the senescence of cucumber fruit and better maintain the quality of cucumber fruit.
Surface-enhanced Raman scattering (SERS) spectrum has the characteristics of fast-detection, high-sensitivity and low-requirements for sample pretreatment. It plays a more and more important role in the detection of organic pollutants. In this study, MIL-101 and Au nanoparticles were prepared by hydrothermal method and aqueous solution reduction method respectively, and MIL-101/Au composite nanoparticles were prepared by electrostatic interaction. The SERS properties of the composite substrate were optimized by adjusting the size of Au nanoparticles and the surface distribution density of MIL-101 nanoparticles. The detection limit of Rhodamine 6G (R6G) for the composite substrate with the optimal ratio was investigated, which was as low as 10–11 M. It is proved that MIL-101/Au composite nanoparticles have high sensitivity to probe molecules. When they are applied to the detection of persistent organic pollutants, the detection limit for fluoranthene can reach 10–9 M and for 3,3’,4,4’-tetrachlorobiphenyl (PCB-77) can reach 10–5 M.
Based on Landsat–7ETM + images of 2007 and 2012 and Landsat–8 images of 2018, this study took Fuyang City, Anhui Province (Yingzhou District, Yingdong District, Yingquan District) as the research object, and made a quantitative analysis of land use/cover change in Fuyang City from 2007 to 2018 with the Environment for Visualizing Images (ENVI) software. According to the data of land use types in three phases, the article analyzes the development trend of various land use types and the main reasons for the changes of land use, which provides a certain basis for the urban planning and environmental construction of Fuyang City. The results show that with the rapid economic development and continuous improvement of the urbanization level in Fuyang City during 11 years, the area of various land types in the study area has changed greatly. The area of construction land area changed by 448.27 km2, with an increase of 543.57%; the area of arable land changed by 597.52 km2, with a decrease of 34.74%; the area of bare land changed by 26.00 km2, with a decrease of 80.68%. The changes were closely related to the rapid economic and social development in the study area. Under the influence of environmental protection policies and environmental awareness, the area of forest land changed by 85.00 km2, with an increase of 97.58%; the water area changed by 84.35 km2, with an increase of 201.39%.
The structure, thermodynamic stability, ionization potential (IP) and electron affinity (EA) energy level difference (Eg) and tension of lowest unoccupied orbit (LUMO) and highest occupied orbit (HOMO) of armchair single wall carbon nanotubes (C-NTs), BN hybrid carbon nanotubes (BC2N-NTs) and all BN nanotubes (BN-NTs) were systematically studied with AM1 method in this paper. Calculation results show that when n value is constant, (n, n) C-NTs (n = 3,4,5,6) has the largest diameter and BN-NTs has the smallest diameter; (n, n) the values of Eg (HOMO-LUMO) and n of C-NTs and BC2N-NTs are related; POAV analysis shows that different hybrid atoms have different contributions to the hybrid mode of nanotube atoms and the tension of nanotubes.
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