An α, α′-dipyridyl adduct of a complex compound hexaaquatribenzene-1,2,4,5-tetracarbonatotetra iron (III) with porous structure was synthesized for the first time. According to the results of elemental, X-ray, IR-spectroscopic and differential-thermal analyses the individuality, chemical formula, thermal destruction, and form of coordination of acidic anion and dipyridyl were established. During interaction of a complex compound with dipyridyl, it completely loses all crystallization molecule of water resulting in a compound with a chemical formula of Fe4(C6H2(COO)4)3(dpy)2(dipyridyl). Using the identification of diffraction pattern the parameters of lattice cell of the complex compound were determined.
Heat conduction theory stipulates that two thermo-physical properties of materials: the thermal conductivity “k” and the thermal diffusivity “α” influence the temperature evolution in regular and irregular bodies as a response to various cooling/heating conditions. The traditional statement involving the two thermo-physical properties is examined at length in the present study for the case of a semi-infinite region. The primary objective of the present study is to investigate the influence of the less known thermo-physical property called the thermal effusivity “e” on the incipient surface temperature rise in a semi-infinite body affected by uniform surface heat flux. The secondary objective of the study is to identify a key figure of merit named the dimensionless threshold time that separates the incipient temperature elevation in a semi-infinite region from the incipient temperature elevation in a large wall of finite thickness under the same uniform surface heat flux. The outcome of the methodical analysis suggests that the accurate estimate for the dimensionless threshold time τth in the semi-infinite region should be 0.10.
In order to study the temperature change trend of the surrounding geotechnical soil during the operation and thermal recovery of the medium-deep geothermal buried pipe and the influence of the geotechnical soil on the operational stability of the vertical buried pipe after thermal recovery. Based on the data of geological stratum in Guanzhong area and the actual engineering application of medium-deep geothermal buried pipe heating system in Xi’an New Area, the influence law of medium-deep geothermal buried pipe heat exchanger on surrounding geotechnical soil is simulated and analyzed by FLUENT software. The results show that: after four months of heating operation, in the upper layer of the geotechnical soil, the reverse heat exchange zone appears due to the higher fluid temperature; in the lower layer of the geotechnical soil, the temperature decreases more with the increase of depth and shows a linear increase in the depth direction; without considering the groundwater seepage, after eight months of thermal recovery of the geotechnical soil after heating, the maximum temperature difference after recovery is 3.02 ℃, and the average temperature difference after recovery is 1.30 ℃ The maximum temperature difference after recovery was 3.02 ℃ and the average temperature difference after recovery was 1.30 ℃. The geotechnical thermal recovery temperature difference has no significant effect on the long-term operation of the buried pipe, and it can be operated continuously and stably for a long time. Practice shows that due to the influence of various factors such as stratigraphic structure, stratigraphic pressure, radioactive decay and stratigraphic thermal conductivity, the actual stratigraphic temperature below 2000m recovers rapidly without significant temperature decay, fully reflecting the characteristics of the Earth’s constant temperature body.
To gain a deep understanding of maintenance and repair planning, investigate the weak points of the distribution network, and discover unusual events, it is necessary to trace the shutdowns that occurred in the network. Many incidents happened due to the failure of thermal equipment in schools. On the other hand, the most important task of electricity distribution companies is to provide reliable and stable electricity, which minimal blackouts and standard voltage should accompany. This research uses seasonal time series and artificial neural network approaches to provide models to predict the failure rate of one of the equipment used in two areas covered by the greater Tehran electricity distribution company. These data were extracted weekly from April 2019 to March 2021 from the ENOX incident registration software. For this purpose, after pre-processing the data, the appropriate final model was presented with the help of Minitab and MATLAB software. Also, average air temperature, rainfall, and wind speed were selected as input variables for the neural network. The mean square error has been used to evaluate the proposed models’ error rate. The results show that the time series models performed better than the multi-layer perceptron neural network in predicting the failure rate of the target equipment and can be used to predict future periods.
The current study provides a comprehensive analysis of MHD hybrid nanofluids and stagnation point flow toward a porous stretched cylinder in the presence of thermal radiation. Here, alumina (Al2O3) and copper (Cu) are considered the hybrid nanoparticles, while water (H2O) is the base fluid. To begin, the required similarity transformations are applied to transform the nonlinear coupled PDEs into nonlinear coupled ODEs. The obtained highly nonlinear sets of ODEs are then solved analytically by using the HAM procedure. The calculations of the thermal radiation term in the energy equation are done based on the Roseland approximation. The result of various embedded variables on temperature and velocity profiles is drawn and explained briefly. Aside from that, the numerical solution of well-known physical quantities, like skin friction and the Nusselt number, is computed by means of tables for the modification of the relevant parameter. The analysis shows that the magnetic field has opposite behavior on θ(η) and f'(η) profiles. It is seen that more magnetic factors M decline f'(η) and upsurge θ(η). Moreover, the behavior of skin friction and the Nusselt number are the same for the magnetic parameter M. Meanwhile, a higher Reynolds number Re declines temperature profile and skin friction while upsurging the local Nusselt number. There are many applications of this study that are not limited to engineering and manufacturing, such as polymer industry, crystal growth, tumor therapy, plasma, fusing metal in electric heaters, nuclear reactors, asthma treatment, gastric medication, cooling of atomic systems, electrolytic biomedicine, helical coil heat exchangers, axial fan design, polymer industry, plane counter jets, and solar collectors.
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