This paper is devoted to the determination of the dispersive component of the surface energy of two boron materials such as h-BN and BPO4 surfaces by using the inverse gas chromatography (IGC) at infinite dilution. The specific interactions and Lewis’s acid-base parameters of these materials were calculated on the light of the new thermal model concerning the dependency of the surface area of organic molecules on the temperature, and by using also the classical methods of the inverse gas chromatography as well as the different molecular models such as Van der Waals, Redlich-Kwong, Kiselev, geometric, Gray, spherical, cylindrical and Hamieh models. It was proved that h-BN surface exhibits higher dispersive surface energy than BPO4 material.
The specific properties of interaction of the two boron materials were determined. The results obtained by using the new thermal model taking into account the effect of the temperature on the surface area of molecules, proved that the classical IGC methods, gave inaccurate values of the specific parameters and Lewis’s acid base constants of the solid surfaces. The use of the thermal model allowed to conclude that h-BN surface has a Lewis basicity twice stronger than its acidity, whereas, BPO4 surface presents an amphoteric character.
In view of the large energy consumption of the regeneration process in the chemical absorption decarburization process, on the basis of the enrichment classification flow process, the nanoscale ceramic film is used as a new heat exchanger between the enriched liquid and the regeneration gas. The porous ceramic film is capable of coupling thermal-mass transfer to effectively recover part of the water vapor and the heat carried in the regeneration gas, so as to reduce the regenerative energy consumption of the system. The effects of parameters such as regeneration temperature, flow rate, molar fraction of water vapor, and MEA enrichment temperature, flow rate, and MEA concentration of shunt on the hydrothermal recovery effect of ceramic membranes of different pore sizes and lengths were studied by using the heat recovery flux and water recovery rate as the indicators. The results show that the hydrothermal recovery performance of the ceramic membrane increases with the increase of MEA enrichment flow, but decreases significantly with the increase of the enrichment temperature. At the same time, with the increase of regenerative gas velocity and the molar fraction of water vapor in the regenerative gas, the heat recovery flux will increase. The heat recovery performance of the 10 nm ceramic membrane is better than that of the 20 nm ceramic membrane.
To gain a deep understanding of maintenance and repair planning, investigate the weak points of the distribution network, and discover unusual events, it is necessary to trace the shutdowns that occurred in the network. Many incidents happened due to the failure of thermal equipment in schools. On the other hand, the most important task of electricity distribution companies is to provide reliable and stable electricity, which minimal blackouts and standard voltage should accompany. This research uses seasonal time series and artificial neural network approaches to provide models to predict the failure rate of one of the equipment used in two areas covered by the greater Tehran electricity distribution company. These data were extracted weekly from April 2019 to March 2021 from the ENOX incident registration software. For this purpose, after pre-processing the data, the appropriate final model was presented with the help of Minitab and MATLAB software. Also, average air temperature, rainfall, and wind speed were selected as input variables for the neural network. The mean square error has been used to evaluate the proposed models’ error rate. The results show that the time series models performed better than the multi-layer perceptron neural network in predicting the failure rate of the target equipment and can be used to predict future periods.
The Cu2–xSe nanoparticles were synthesized by high temperature pyrolysis, modified with aminated polyethylene glycol in aqueous solution and loaded with compound 2,2′–azobis[2–(2–imidazolin–2–yl)propane] dihydrochloride (AIPH). The obtained nanomaterials can induce photothermal effect and use heat to promote the generation of toxic AIPH radicals under the irradiation of near-infrared laser (808 nm), which can effectively kill cancer cells. A series of in vitro experiments can preliminarily prove that Cu2–xSe–AIPH nanomaterials have strong photothermal conversion ability, good biocompatibility and anticancer properties.
Recent research efforts have increasingly concentrated on creating innovative biomaterials to improve bone tissue engineering techniques. Among these, hybrid nanomaterials stand out as a promising category of biomaterials. In this study, we present a straightforward, cost-efficient, and optimized hydrothermal synthesis method to produce high-purity Ta-doped potassium titanate nanofibers. Morphological characterizations revealed that Ta-doping maintained the native crystal structure of potassium titanate, highlighting its exciting potential in bone tissue engineering.
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