A metakaolin-based geopolymer was fabricated with 5 ratios of two different nanomaterials. On the one hand, silicon carbide nanowhiskers and, on the other hand, titanium dioxide nanoparticles. Both were placed in water and received ultrasonic energy to be dispersed. The effects on mechanical properties and reaction kinetics were analyzed. Compared to the reference matrix, the results showed a tendency to increase the flexural strength. Probably due to the geometry of the SiC nanowhiskers and the pore refinement by the nano-TiO2 particles. The calorimetry curves showed that incorporating TiO2 nanoparticles resulted in a 92% reduction in total heat, while SiC nanowhiskers produced a 25% reduction in total heat.
Atom transfer radical polymerization (ATRP) is a kind of controllable reactive radical polymerization method with potential application value. The modification of graphene oxide (GO) by ATRP reaction can effectively control various graft polymer molecules Chain length and graft density, giving GO different functionality, such as good solvent dispersibility, environmental sensitive stimulus responsiveness, biocompatibility, and the like. In this paper, ATRP reaction and GO surface non-covalent bonding ATRP polymer molecular chain were directly initiated from GO surface immobilization initiator. The ATRP reaction modified GO was reviewed, and the process conditions and research methods of ATRP modification reaction were summarized, as well as pointed out the functional characteristics and application prospect of GO functionalized composites.
The purpose of this work is to present the model of a Parabolic Trough Solar Collector (PTC) using the Finite Element Method to predict the thermal behavior of the working fluid along the collector receiver tube. The thermal efficiency is estimated based on the governing equations involved in the heat transfer processes. To validate the model results, a thermal simulation of the fluid was performed using Solidworks software. The maximum error obtained from the comparison of the modeling with the simulation was 7.6% at a flow rate of 1 L/min. According to the results obtained from the statistical errors, the method can effectively predict the fluid temperature at high flow rates. The developed model can be useful as a design tool, in the optimization of the time spent in the simulations generated by the software and in the minimization of the manufacturing costs related to Parabolic Trough Solar Collectors.
Research into electro-conductive textiles based on conductive polymers like polypyrrole has increased in recent years due to their high potential applications in various fields. Conductive polymers behave like insulators in their neutral states, with typical electrical conductivity in the range 10–10 to 10–25 Scm–1. These neutral polymers can be converted into semi-conductive or conductive states with conductivities ranging from 1 Scm–1 to 10–4 Scm–1 through chemical or electro-chemical redox reactions. By applying these polymers to a textile surface, we can obtain novel composites that are strong, flexible, lightweight, and highly electroconductive. These textile composites are suitable for applications such as heating pads, sensors, corrosion-protecting materials, actuators, electrochromic devices, EMI shielding, etc. The methods of application of conductive polymers onto the textile surface, such as in-situ chemical, in-situ electrochemical, in-situ vapor phase, in-situ polymerization in a supercritical fluid, and solution coating processes, are described here briefly. The merits and demerits of these methods are mentioned here. The reaction mechanisms of chemical and electrochemical polymerization proposed by the different researchers are described. Different factors affecting the kinetics of chemical and electrochemical polymerization are accounted for. The influence of textile materials on the kinetics of chemical polymerization is reviewed and reported.
The effect of foliar treatment with brassinosteroid (BR) on gender distribution in flowers of walnut (Juglans regia L. cv. Chandler) was investigated. Grafted walnut saplings (‘Chandler’) on the wild walnut (Juglans regia L.) rootstock were planted into 70-liter pots with a soil: peat: perlite medium and grown in pots between 2016–2020. BRs (24-epibrassinolide; EBR and 22(S), 23(S)-homobrassinolide; HBR) were applied at a concentration of 1 mg L–1 for four consecutive years at the time of flower differentiation. The experimental design was completely randomized with three replicates. The results show that BR applications could alter the sexual distribution of the walnut’s flower. BRs application significantly increased the number of total flowers and female flowers per tree. The number of female flowers was also increased by the season. The highest number of female flowers (20.9) was observed in the trees in 2020 and the application of 1 mg L–1 of HBR. It was determined that the annual growth of the plant and the increase in the number of females and total flowers were positively related. The effect of BRs indicated that the response was BR-type specific.
The effects of climate change are already being felt, including the failure to harvest several agricultural products. On the other hand, peatland requires good management because it is a high carbon store and is vulnerable as a contributor to high emissions if it catches fire. This study aims to determine the potential for livelihood options through land management with an agroforestry pattern in peatlands. The methods used are field observation and in-depth interviews. The research location is in Kuburaya Regency, West Kalimantan, Indonesia. Several land use scenarios are presented using additional secondary data. The results show that agroforestry provides more livelihood options than monoculture farming or wood. The economic contribution is very important so that people reduce slash-and-burn activities that can increase carbon emissions and threaten the sustainability of peatland.
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