The importance of improving industrial transformation processes for more efficient ones is part of the current challenges. Specifically, the development of more efficient processes in the production of biofuels, where the reaction and separation processes can be intensified, is of great interest to reduce the energy consumption associated with the process. In the case of Biodiesel, the process is defined by a chemical reaction and by the components associated to the process, where the thermochemical study seeks to develop calculations for the subsequent understanding of the reaction and purification process. Thus, the analysis of the mixture of the components using the process simulator Aspen Plus V9^® unravels the thermochemical study. The UNIFAC-DMD thermodynamic method was used to estimate the binary equilibrium parameters of the reagents using the simulator. The analyzed aspects present the behavior of the components in different temperature conditions, the azeotropic behavior and the determined thermochemical conditions.

In order to study the temperature change trend of the surrounding geotechnical soil during the operation and thermal recovery of the medium-deep geothermal buried pipe and the influence of the geotechnical soil on the operational stability of the vertical buried pipe after thermal recovery. Based on the data of geological stratum in Guanzhong area and the actual engineering application of medium-deep geothermal buried pipe heating system in Xi’an New Area, the influence law of medium-deep geothermal buried pipe heat exchanger on surrounding geotechnical soil is simulated and analyzed by FLUENT software. The results show that: after four months of heating operation, in the upper layer of the geotechnical soil, the reverse heat exchange zone appears due to the higher fluid temperature; in the lower layer of the geotechnical soil, the temperature decreases more with the increase of depth and shows a linear increase in the depth direction; without considering the groundwater seepage, after eight months of thermal recovery of the geotechnical soil after heating, the maximum temperature difference after recovery is 3.02 ℃, and the average temperature difference after recovery is 1.30 ℃ The maximum temperature difference after recovery was 3.02 ℃ and the average temperature difference after recovery was 1.30 ℃. The geotechnical thermal recovery temperature difference has no significant effect on the long-term operation of the buried pipe, and it can be operated continuously and stably for a long time. Practice shows that due to the influence of various factors such as stratigraphic structure, stratigraphic pressure, radioactive decay and stratigraphic thermal conductivity, the actual stratigraphic temperature below 2000m recovers rapidly without significant temperature decay, fully reflecting the characteristics of the Earth’s constant temperature body.

Quartz sand was used as bed material in a small fluidized bed reactor with 1 kg/h feed. Corn straw powder with particle size of 20–40 mesh, 40–60 mesh, 60–80 mesh and 80–120 mesh was used as raw material for rapid pyrolysis at reaction temperatures of 400 °C, 450 °C, 500 °C and 550 °C. The bio-oil obtained after liquefaction of pyrolysis gas was analyzed. The variation trend of bio-oil composition in pyrolysis of corn straw powder with different reaction temperatures and raw material sizes was compared. The results show that: (1) the content of 3-hydroxyl-2-phenyl-2-acrylic acid in bio-oil increases with the decrease of raw material particle size, but it is less at 450 °C; (2) with the increase of reaction temperature, the content of hydroxyacetaldehyde in bio-oil increases at first and then decreases: the content of hydroxyacetaldehyde in bio-oil is the highest at 500 °C when the particle size is 20–40 mesh, and the highest at 450 °C with the other three particle sizes. Compared with other particle sizes, raw material with the particle size of 60–80 mesh is not conducive to the formation of aldehyde compounds; (3) the reaction temperature of 500 °C and the particle size of 60–80 mesh of raw materials are more conducive to the formation of phenolic compounds in bio-oil; (4) the ester compounds with particle size of 20–40 mesh in bio-oil is 20% higher than that of other particle sizes; (5) the reaction temperature and the particle size of raw materials had no significant effect on the formation of ketones, alcohols and alkane compounds in bio-oils.

In order to explore the influence of the ferroelectric surface on the structure and properties of semiconductor oxides, the growth of CdS nanocrystals was regulated and controlled by taking single-crystal perovskite PbTiO₃ nanosheets as the substrate through a simple hydrothermal method. Through composition design, a series of PbTiO₃-CdS nanocomposite materials with different loading concentrations were prepared, and their microstructure and photocatalytic properties were systematically analyzed. Studies show that in the prepared product, CdS nanoparticles selectively grow on the surfaces of PbTiO₃ nanosheets, and their morphology is affected by the exposed surfaces of PbTiO₃ nanosheets. There is a clear interface between the PbTiO₃ substrate and CdS nanoparticles. The concentration of the initial reactant and the time of hydrothermal reaction also significantly affect the crystal morphology of CdS. Photocatalysis studies have shown that the prepared PbTiO₃-CdS nanocomposite material has a significant degradation effect on 10 mg/L of Rhodamine B aqueous solution. The degradation efficiency rises with the increase of CdS loading concentration. When degrading 10 mg/L Rhodamine B aqueous solution, the PbTiO₃-CdS sample with a mass fraction of 3% can reach a degradation rate of 72% within 120 min.