In order to explore the influence of the ferroelectric surface on the structure and properties of semiconductor oxides, the growth of CdS nanocrystals was regulated and controlled by taking single-crystal perovskite PbTiO₃ nanosheets as the substrate through a simple hydrothermal method. Through composition design, a series of PbTiO₃-CdS nanocomposite materials with different loading concentrations were prepared, and their microstructure and photocatalytic properties were systematically analyzed. Studies show that in the prepared product, CdS nanoparticles selectively grow on the surfaces of PbTiO₃ nanosheets, and their morphology is affected by the exposed surfaces of PbTiO₃ nanosheets. There is a clear interface between the PbTiO₃ substrate and CdS nanoparticles. The concentration of the initial reactant and the time of hydrothermal reaction also significantly affect the crystal morphology of CdS. Photocatalysis studies have shown that the prepared PbTiO₃-CdS nanocomposite material has a significant degradation effect on 10 mg/L of Rhodamine B aqueous solution. The degradation efficiency rises with the increase of CdS loading concentration. When degrading 10 mg/L Rhodamine B aqueous solution, the PbTiO₃-CdS sample with a mass fraction of 3% can reach a degradation rate of 72% within 120 min.

High-quality implementation of cross-border mergers and acquisitions (cross-border M&As) is an important pathway for emerging-market multinational enterprises (EMNEs) to enhance their international competitiveness. However, in comparison to developed countries, cross-border M&As by EMNEs are often prohibited by the liability of origin caused by negative political coverage. How and why negative political coverage affect the completion of cross-border M&As by EMNEs? What are the contextual constraints that moderate the impact of negative political coverage on cross-border M&As completion? Based on the “liability of origin” theory, this paper addresses these questions using data from the Zephyr database on cross-border M&As by EMNEs in the United States from 2016 to June 2021 and employing a logit model for estimation. The research findings are as follows: (1) Negative political coverage leads to negative perceptions of emerging market countries by host country stakeholders, creating the liability of origin and stigmatizing the corporate nationality, thereby reducing the success rate of cross-border M&As by EMNEs. (2) Increasing geographical distance leads to information asymmetry, reinforcing the negative impact of negative political coverage on the completion of cross-border M&As by EMNEs. (3) Relevant mergers and acquisitions exacerbate the negative effect of negative political coverage on the success rate of cross-border M&As by EMNEs. (4) Being a publicly traded firm and having successful experience in cross-border M&As both intensify the negative impact of negative political coverage on the success rate of cross-border M&As by EMNEs.

In order to understand the finishing effect of Waterborne Acrylic Paint under different painting methods and amount, bamboo-laminated lumber for furniture was coated with waterborne acrylic paint, then the effects of different painting methods and amount on the drying rate, smoothness, hardness, adhesion and wear resistance of the paint film were investigated. Further, the mechanism of film formation was described by thermal property analysis using thermogravimetry and differential scanning calorimeter. The results show that different painting methods have little effect on film properties, the drying time of primer and topcoat are not affected by them, which is 8/8.5 min for primer surface/solid and 6.5/7 min for topcoats. The film surface hardness and adhesion can reach B and 0 grade, the best wear resistance of the film is 51.24 mg·100 r⁻¹ when using one-layer primer one-layer topcoat. Different coating amount has great influence on film properties, the drying speed of the film increases with the increase of the painting amount. The film properties reach the best when the painting amount is 80 g/m², while too little painting amount leads to the decrease of hardness, and too much leads to the wear resistance weaken. Thermal analysis of the primer and topcoat show that water decomposition occurs at 100 ℃ and thermal decomposition of organic components occur at 350 ℃. Topcoats have better thermal stability than primers higher than that of topcoat, the topcoat displayed better thermal stability than the primer.

This article reports the development of an index of culturality in Chile. Fifteen quantitative variables indicative of local cultural development are used to measure the access to cultural opportunities in each Chilean district. This approach was adopted from the theoretical framework of cultural materialism theorized by Marvin Harris in the seventies. Using this framework, a ranking is developed among 164 districts to determine the degree of cultural development exists in each and the variables that are the influential on the enhancement of this indicator. The results showed that the districts of Rancagua, Providencia, La Reina, El Bosque, and Valparaíso have better cultural opportunities based on their material forms, which are mainly driven by obtaining funds for cultural projects, workers’ salaries, civic activity, and public libraries. Based on the results of this ranking, a baseline is proposed to develop it using new data. In addition, recommendations are provided regarding public policies that have promoted cultural development in the communities with unsuccessful results. The article provides significant information for decision makers in Chile and a quantitative method for exploring cultural materialism in specific territories.

All ophiolite associations mark epochs of active tectonic movements, which lead to significant petrological processes and modification of the relief of the Earth's crust. Here we present a geological-petrographical characterization of one ophiolitic associations composed of: a) serpentinites; b) amphibolites-metamorphosed volcanic rocks and tuffs; c) metagabbros and metagabbrodiabases, placed among the Proterozoic metamorphic complex in the Rhodope Massif of Bulgaria on the Balkan Peninsula, South-Eastern Europе. The goal is to clarify the paleogeographical and geological setting during its creation. The methods of lithostratigraphic profiling and correlations on the database of geological field mapping were used, supplemented by microscopic, geochemical and isotopic studies of numerous rock samples. The summarized results confirm a certain stratigraphic level of the Ophiolite Association among the metamorphic complex and a complicated and protracted heterogenetic development, which is typical for the ophiolite associations created in eras of closing oceans, opposite movement of tectonic plates, subduction-obduction environment with appearance of autochthonous Neoproterozoic magmatism. Obducted fragments of serpentinites mark an old erosional continental surface, subsequently covered by transgressively deposited pelitic-carbonate sediments. The general conclusion of our study confirms the concept that the metamorphic complex of the Rhodope Massif represents a unified stratigraphic system consisting of two petrographic groups of different ages, with which we oppose the idea of a trust construction, launched by a group of geologists.

This paper proposes a floating-interest-rate infrastructure bond, where the interest of a government bond is paid to investors during the period of construction and the early period of operation. Unlike the usual government bond, which provides a fixed interest rate, the proposed floating-interest-rate infrastructure bond pays a floating interest, the rate of which depends on spillover tax revenues. Effective infrastructure projects have a positive effect on the economic growth of a region, known as the spillover effect. When user charges and the return from spillover tax revenues are below the fixed rate of the government bond, the interest rate will equal to the fixed rate of the government bond. In this case, investors in the infrastructure will receive interest on the government bond at the minimum rate. As the spillover effect of the infrastructure increases, the rate of return for infrastructure investment will become greater than the fixed rate of the government bond. The success of the floating-interest-rate infrastructure bond depends on the spillover effect and on transparency and accountability. Policy recommendations are provided in this paper on how to increase the spillover effect and improve transparency and accountability.