The porous carbon/Ni nanoparticle composite was prepared by a freeze-drying method using NaCl as the template. It was applied in the effect of the concentration, adsorption time, and temperature of adsorption on the adsorption behavior. The kinetic model and the adsorption isothermic fitting results show that the adsorption behavior fits with the pseudo-secondary dynamics and the Langmuir isothermal model, indicating that the adsorption process is monolayer adsorption. Thermodynamic results indicate that the adsorption process is spontaneous physicochemical adsorption. The fitting showed that the porous carbon/Ni nanoparticle composites reach 217.17 mg·g^-1, at 313 K indicates good adsorption for Congo red.

Learning from experience to improve future infrastructure public-private partnerships is a focal issue for policy makers, financiers, implementers, and private sector stakeholders. An extensive body of case studies and “lessons learned” aims to improve the likelihood of success and attempts to avoid future contract failures across sectors and geographies. This paper examines whether countries do, indeed, learn from experience to improve the probability of success of public-private partnerships at the national level. The purview of the paper is not to diagnose learning across all aspects of public-private partnerships globally, but rather to focus on whether experience has an effect on the most extreme cases of public-private partnership contract failure, premature contract cancellation. The analysis utilizes mixed-effects probit regression combined with spline models to test empirically whether general public-private partnership experience has an impact on reducing the chances of contract cancellation for future projects. The results confirm what the market intuitively knows, that is, that public-private partnership experience reduces the likelihood of contract cancellation. But the results also provide a perhaps less intuitive finding: the benefits of learning are typically concentrated in the first few public-private partnership deals. Moreover, the results show that the probability of cancellation varies across sectors and suggests the relative complexity of water public-private partnerships compared with energy and transport projects. An estimated $1.5 billion per year could have been saved with interventions and support to reduce cancellations in less experienced countries (those with fewer than 23 prior public-private partnerships).

In this study, we define the unrestricted Pell and Pell-Lucas quaternions. We give generating functions, Binet formulas and some generalizations of well-known identities such as Vajda’s, Catalan’s, Cassini’s d’Ocagne’s identities.

Dust is one of the atmospheric pollutants that have adverse environmental effects and consequences. Dust fall contains particles of 100 microns or even smaller ones, which fall from the atmosphere onto the earth surface. The aim of this study is to determine the concentration of lead in dust fall samples in order to study the pollution level of this element in Zahedan, Sistan and Baluchistan Province, Iran. Therefore, sampling was carried out using 30 marble dust collectors (MDCO) for 3 months in the spring of 2015 to investigate the quantitative variation and spatial analysis of lead content in dust fall. These dust collectors were placed at 30 stations on the building roofs with a height of approximately 1.5 meters across the city. According to the results, the mean lead concentration in the spring was 90.16 mg/kg. In addition, the zoning map of lead content shows that the lowest level of lead was measured at Imam Khomeini station while the highest amount of lead appeared in Mostafa Khomeini station.