The low V-notch impact toughness is a notable limitation of the PBT/PA6 blend. In this study, we maintained a fixed PBT/PA6 ratio of 50/50 while varying the proportion of PP in the given blend at levels of 0%, 70%, 80%, 90%, and 100% neat PP. The results from the unnotched impact toughness tests for the PP/PBT/PA6 blends showed favorable outcomes. Specifically, the impact toughness of the PP/PBT/PA6 samples progressively increased with the rise in PP content. Initially, the toughness dropped from 10.13 kJ/m² in the 0% PP sample to 8.6 kJ/m² in the 70% PP sample, before increasing gradually from 8.6 kJ/m² in the 70% PP sample to 17.45 kJ/m² in the 90% PP sample to 17.45 kJ/m² in the 90% PP sample, which represents an increase of about 72% relative to the 0% PP sample. These positive results demonstrate that the addition of PP significantly enhances the impact toughness of the blend compared to formulations without PP.