Thermodynamic study of the adsorption of an azoic dye by a lignocellulosic residue in an aqueous medium

Gina Hincapié Mejía ,Sebastián Cardona Cuervo ,Luis Alberto Ríos

doi:10.24294/tse.v5i1.1531

Home - TSE - Volume 5 - Issue 1

Submit to TSE

Journal Browser

Volume | Year

Issue

• Current lssue

View All

News and Announcements

View All

Thermodynamic study of the adsorption of an azoic dye by a lignocellulosic residue in an aqueous medium

Gina Hincapié Mejía

Sebastián Cardona Cuervo

Luis Alberto Ríos

Thermal Science and Engineering 2022, 5(1), 74-82; https://doi.org/10.24294/tse.v5i1.1531

Submitted：29 Mar 2022

Accepted：17 May 2022

Published：24 May 2022

Download PDF(558.99KB)

XML

Abstract

Roasted and ground coffee residue was investigated as an adsorbent lignocellulosic material capable of removing methyl orange dye from aqueous solutions by means of batch adsorption experiments. The effects of experimental parameters on the adsorption behavior, such as initial dye concentration, adsorbent dosage, initial pH and temperature were studied. A better adsorption of the dye was observed at acid pH, low temperature and with an adsorbent dosage of 6 g/L. A Pseudo-second order kinetics was found according to the Lagergren kinetic model. A maximum adsorption capacity of 1.3 mg methyl orange per gram of adsorbent was calculated by fitting the Langmuir model. The adsorption of methyl orange on the adsorbent analyzed was found to be exothermic in nature. The roasted and ground coffee residue was found to be viable for the primary treatment of wastewater contaminated with azoic-type compounds.

Keywords

References

Kushwaha AK, Gupta N, Chattopadhyaya MC. Removal of cationic methylene blue and malachite green dyes from aqueous solution by waste materials of Daucus carota. Journal of Saudi Chemical Society 2014; 18(3): 200-207.

Smitha T, Santhi T, Prasad AL, et al. Cucumis sativus used as adsorbent for the removal of dyes from aqueous solution. Arabian Journal of Chemistry 2012; 10(1): S244-S251.

Inyinbor AA, Adekola FA, Olatunji GA. Kinetics, isotherms and thermodynamic modeling of liquid phase adsorption of Rhodamine B dye onto Raphia hookerie fruit epicarp. Water Resources and Industry 2016; 15: 14-27.

Etim UJ, Umoren SA, Eduok UM. Coconut coir dust as a low-cost adsorbent for the removal of cationic dye from aqueous solution. Journal of Saudi Chemical Society 2012; 20(1): S67-S76.

Reddy MSC, Nirmala V, Ashwini C. Bengal Gram Seed Husk as an adsorbent for the removal of dye from aqueous solutions—Batch studies. Arabian Journal of Chemistry 2013; 10(2): S2554-S2566.

Guechi EK, Hamdaoui O. Sorption of malachite green from aqueous solution by potato peel: Kinetics and equilibrium modeling using non-linear analysis method. Arabian Journal of Chemistry 2011; 9(1): S416-S424.

Acosta H, Barraza C, Albis A. Adsorption of chromium (VI) using cassava peel (Manihot es-culenta) as biosorbent: A kinetic study. Ingeniería y Desarrollo 2017; 35(1): 58-76.

Ahmad R, Kumar R, Haseeb S. Adsorption of Cu2+ from aqueous solution onto iron oxide coated eggshell powder: Evaluation of equilibrium, isotherms, kinetics, and regeneration capacity. Arabian Journal of Chemistry 2012; 5(3): 353-359.

Gupta N, Kushwaha AK, Chattopadhyaya MC. Application of potato (Solanum tuberosum) plant wastes for the removal of methylene blue and malachite green dye from aqueous solution. Ara-bian Journal of Chemistry 2011; 9(1): S707-S716.

Shen K, Gondal MA. Removal of hazardous Rhodamine dye from water by adsorption onto exhausted coffee ground. Journal of Saudi Chemical Society 2013; 21(1): S120-S127.

Slimani R, Ouahabia IE, Abidi F, et al. Calcined eggshells as a new biosorbent to remove basic dye from aqueous solutions: Thermodynamics, kinetics, isotherms and error analysis. Journal of the Taiwan Institute of Chemical Engineers 2014; 45(4): 1578-1587.

Shirzad-Siboni M, Khataee A, Hassani A, et al. Preparation, characterization and application of a CTAB-modified nanoclay for the adsorption of an herbicide from aqueous solutions: Kinetic and equilibrium studies. Comptes Rendus Chimie 2015; 18(2): 203-216.

Abdelwahab O, Amin NK. Adsorption of phenol from aqueous solutions by Luffa cylindrica fibers: Kinetics, isotherm and thermodynamic studies. Egyptian Journal of Aquatic Research 2013; 39(4): 215-223.

Netzahuatl-Muñoz AR, Pineda-Camacho G, Barragán-Huerta BE, et al. Removal of hexavalent chromium and total chromium by the bark of Pyrus communis. Chemical Sciences 2010; 41: 1-10.

Alicia L, Llamas R, Azuara AJ. et al. Adsorption of methyl orange in aqueous solution on lamellar double hydroxides. Acta Universitaria 2015; 25(3): 3-12.

Dahri MK, Kooh MRRR, Lim LBL. Application of Casuarina equisetifolia needle for the removal of methylene blue and malachite green dyes from aqueous solution. Alexandria Engineering Journal 2015; 54(4): 1253-1263.

Postai DL, Demarchi CA, Zanatta F, et al. Adsorption of rhodamine B and methylene blue dyes using waste of seeds of Aleurites Moluccana, a low-cost adsorbent. Alexandria Engineering Journal 2016; 55(2): 1713-1723.

Sejie FP, Nadiye-Tabbiruka MS. Removal of Methyl Orange (MO) from Water by adsorption onto Modified Local Clay (Kaolinite). Physical Chemistry 2016; 6(2): 39-48.

Previous
article in this issue

Next
article in this issue