In this review are developed insights from the current research work to develop the concept of functional materials. This is understood as real modified substrates for varied applications. So, functional and modified substrates focused on nanoarchitectures, microcapsules, and devices for new nanotechnologies highlighting life sciences applications were revised. In this context, different types of concepts to proofs of concepts of new materials are shown to develop desired functions. Thus, it was shown that varied chemicals, emitters, pharmacophores, and controlled nano-chemistry were used for the design of nanoplatforms to further increase the sizes of materials. In this regard, the prototyping of materials was discussed, affording how to afford the challenge in the design and fabrication of new materials. Thus, the concept of optical active materials and the generation of a targeted signal through the substrate were developed. Moreover, advanced concepts were introduced, such as the multimodal energy approach by tuning optical coupling from molecules to the nanoscale within complex matter composites. These approaches were based on the confinement of specific optical matter, considering molecular spectroscopics and nano-optics, from where the new concept nominated as metamaterials was generated. In this manner, fundamental and applied research by the design of hierarchical bottom-up materials, controlling molecules towards nanoplatforms and modified substrates, was proposed. Therefore, varied accurate length scales and dimensions were controlled. Finally, it showed proofs of concepts and applications of implantable, portable, and wearable devices from cutting-edge knowledge to the next generation of devices and miniaturized instrumentation.

In this study, robust and defect-free thin film composite (TFC) forward osmosis (FO) membranes have been successfully fabricated using ceramic hollow fibers as the substrate. Polydopamine (PDA) coating under controlled conditions is effective in reducing the surface pores of the substrate and making the substrate smooth enough for interfacial polymerization. The pure water permeability (A), solute permeability (B), and structural parameter (S) of the resultant FO membrane are 0.854 L·m^–2·h⁻¹·bar⁻¹ (LMH/Bar), 0.186 L·m^–2·h⁻¹ (LMH), and 1720 µm, respectively. The water flux and reverse draw solute flux are measured using NaCl and proprietary ferric sodium citrate (FeNaCA) draw solutions at low and high osmotic pressure ranges. As the osmotic pressure increases, a higher water flux is obtained, but its increase is not directly proportional to the increase in the osmotic pressure. At the membrane surface, the effect of dilutive concentration polarization is much less serious for FeNaCA-draw solutions. At an osmotic pressure of 89.6 bar, the developed TFC membrane generates water fluxes of 11.5 and 30.0 LMH using NaCl and synthesized FeNaCA draw solutions. The corresponding reverse draw solute flux is 7.0 g·m^–2·h⁻¹ (gMH) for NaCl draw solution, but it is not detectable for FeNaCA draw solution. This means that the developed TFC FO membranes are defect-free and their surface pores are at the molecular level. The performance of the developed TFC FO membranes is also demonstrated for the enrichment of BSA protein.

The agronomic use of mushroom post-harvest substrates (SPCHs) in horticultural seedbeds could be an interesting alternative for the reuse of these wastes in line with the European circular economy strategy. This work evaluates the potential use of four treatments with different SPCHs, mushroom (-Ch), mushroom (-St), mushroom compost (-CO), and a mixture (SPCH-Ch and SPCH-St) as substrates for lettuce and chili pepper seed germination. The trial was carried out in a germination chamber using commercial compost as a control treatment. The evaluation was based on its chemical (salinity, N and C content), physical (bulk and real density, porosity and water retention) and plant effect (germination and biomass) characteristics. Of the chemical properties studied, the high salinity in SPCH-Ch and SPCH-CO was a limiting factor for the development of the horticultural species evaluated (electrical conductivity 1:2.5; p/v; ~11 dS m^-1), and low germination percentages were observed. Regarding physical properties, porosity and water retention, the SPCH-CO, SPCH-St and mixture treatments presented some values outside the optimal range established for germination substrates. In the case of SPCH-St, its high C/N ratio could be a limitation for supplying N to the crop. In relation to biomass production (aerial and root) of lettuce and chili pepper, all the treatments evaluated obtained similar values to the control treatment. The mixed treatment presented the highest biomass values, significantly higher in the lettuce crop. In general, the mixed treatment proved to be the best alternative for use in the seedbed.

Studies related to the use of steel mill slag have become essential, because of the possibility of its use as a component of substrates in the production of seedlings and because this use minimizes the risk of environmental contamination, resulting from inadequate disposal. Thus, the objective of this work was to evaluate the effect of increasing levels of steel slag in substrates composed of soil with tanned bovine manure and sand, on the growth variables and the quality of “Dedo-de-moça” pepper (Capsicum baccatum L.) seedlings. A randomized block design was used with five slag concentrations (0%, 2.5%, 5%, 10% and 20%) and four repetitions. Evaluations occurred at 55 days after sowing, consisting of counting the number of leaves, measuring plant height and collar diameter, quantifying the dry mass of leaves and roots and determining the Dickson Quality Index. Regression models were fitted (P < 0.05) to treatments with increasing levels of steel slag. The addition around 10% of slag to the substrate provided the highest values of growth variables, in seedlings of Dedo-de-moça pepper.

This work aimed to evaluate the effects of using three different substrates in the semi-hydroponic culture of lettuce (Lactuca sativa L.) using two different nutrient solutions. A first trial was performed with a nutrient solution rich in macronutrients and micronutrients suitable for lettuce culture, and a second trial with a nutrient solution with pretreated wastewater from effluents of a cheese factory. The experimental design was in randomized blocks with three repetitions and three substrates were used: perlite, coconut fiber, and expanded clay, in both trials. The following parameters were observed: number of leaves, diameter of the cabbage, fresh and dry weight of the aerial part, chlorophyll index and mineral composition of the lettuce. For the first trial, the highest result for the number of leaves (20 leaves), fresh weight (142.0 g) and dry weight (7.2 g) of the aerial part was obtained in the plants growing on perlite. In the second trial, the highest result for the number of leaves (28 leaves), diameter of cabbage (26.7 cm), fresh weight (118.8 g) and dry weight (9.5 g) of the aerial part were achieved by the plants that were grown in coconut fiber. The nutrient solutions were analyzed after each irrigation cycle to verify the possibility of their discharge into the environment. Several parameters were analyzed: pH, conductivity, redox potential, nitrates, nitrites, ammoniacal nitrogen, chlorides, hardness, calcium, phosphates, sodium, potassium, chemical oxygen demand (COD) and magnesium. Ammoniacal nitrogen was found to be the only nutrient that can limits the discharge of nutrient solutions into the environment. It was also proven that the plants, besides obtaining the nutrients necessary for their development in the semi-hydroponic system with the nutrient solution with pre-treated residual water, also functioned as a purification system, allowing the said nutrient solution to be discharged into the environment at the end of each cycle.