The electron/hole transport layer can promote charge transfer and improve device performance, which is used in perovskite solar cells. The nanoarray structure transport layers can not only further promote carrier transport but also reduce recombination. It also has a great potential in enhancing perovskite light absorption, improving device stability and inhibiting the crack nucleation of different structure layers in perovskite solar cells. This paper reviewed the research progress of perovskite solar cells with different nanoarray structure transport layers. The challenges and development directions of perovskite solar cells based on nanoarray structure transport layers are also summarized and prospected.
In this paper, we modeled and simulated two tandem solar cell structures (a) and (b), in a two-terminal configuration based on inorganic and lead-free absorber materials. The structures are composed of sub-cells already studied in our previous work, where we simulated the impact of defect density and recombination rate at the interfaces, as well as that of the thicknesses of the charge transport and absorber layers, on the photovoltaic performance. We also studied the performance resulting from the use of different materials for the electron and hole transport layers. The two structures studied include a bottom cell based on the perovskite material CsSnI3 with a band gap energy of 1.3 eV and a thickness of 1.5 µm. The first structure has an upper sub-cell based on the CsSnGeI3 material with an energy of 1.5 eV, while the second has an upper sub-cell made of Cs2TiBr6 with a band gap energy of 1.6 eV. The theoretical model used to evaluate the photocurrent density, current-voltage characteristic, and photovoltaic parameters of the constituent sub-cells and the tandem device was described. Current matching analysis was performed to find the ideal combination of absorber thicknesses that allows the same current density to be shared. An efficiency of 29.8% was obtained with a short circuit current density Jsc = 19.92 mA/cm2, an open circuit potential Voc = 1.46 V and a form factor FF = 91.5% with the first structure (a), for a top absorber thickness of CsSnGeI3 of 190 nm, while an efficiency of 26.8% with Jsc = 16.74, Voc = 1.50 V and FF = 91.4% was obtained with the second structure (b), for a top absorber thickness of Cs2TiBr6 of 300 nm. The objective of this study is to develop efficient, low-cost, stable and non-toxic tandem devices based on lead-free and inorganic perovskite.
In this paper, a solar tracking device that can continuously track the sun by adjusting the direction and angle of the solar panel in real time is designed and fabricated to improve the power generation efficiency of the solar cell panel. The mechanical parts as well as the automatic control part of the passive sun-tracking system are described, and the efficiency enhancement with the sun-tracking solar panel is characterized in comparison with the fixed panel system. The test results show that in the spring season in Qingdao city of eastern China, the sun-tracking system can improve the solar cell power generation efficiency by 28.5%–42.9% when comparing to the direction and elevation angle fixed system in sunny days. Even in partly cloudy days, the PV power output can increased by 37% with using the passive sun-tracking system. Economic analysis results show the cost-benefit period is about 10 years, which indicates that the passive sun tracking device can substantially contribute to the solar energy harvest practices.
This comprehensive review explores the forefront of nanohybrid materials, focusing on the integration of coordination materials in various applications, with a spotlight on their role in the development of flexible solar cells. Coordination material-based nanohybrids, characterized by their unique properties and multifunctionality, have garnered significant attention in fields ranging from catalysis and sensing to drug delivery and energy storage. The discussion investigates the synthesis methods, properties, and potential applications of these nanohybrids, underscoring their versatility in materials science. Additionally, the review investigates the integration of coordination nanohybrids in perovskite solar cells (PSCs), showcasing their ability to enhance the performance and stability of next-generation photovoltaic devices. The narrative further expands to encompass the synthesis of luminescent nanohybrids for bioimaging purposes and the development of layered, two-dimensional (2D) material-based nanostructured hybrids for energy storage and conversion. The exploration culminates in an examination of the synthesis of conductive polymer nanostructures, elucidating their potential in drug delivery systems. Last but not least, the article discusses the cutting-edge realm of flexible solar cells, emphasizing their adaptability and lightweight design. Through a systematic examination of these diverse nanohybrid materials, this review sheds light on the current state of the art, challenges, and prospects, providing valuable insights for researchers and practitioners in the fields of materials science, nanotechnology, and renewable energy.
Given the increasing demand for sustainable energy sources and the challenges associated with the limited efficiency of solar cells, this review focuses on the application of gold quantum dots (AuQDs) in enhancing solar cell performance. Gold quantum dots, with their unique properties such as the ability to absorb ultraviolet light and convert it into visible light expand the utilization of the solar spectrum in solar cells. Additionally, these quantum dots, through plasmonic effects and the enhancement of localized electric fields, improve light absorption, charge carrier generation (electrons and holes), and their transfer. This study investigates the integration of quantum dots with gold plasmonic nanoparticles into the structure of solar cells. Experimental results demonstrate that using green quantum dots and gold plasmonic nanoparticles as intermediate layers leads to an increase in power conversion efficiency. This improvement highlights the significant impact of this technology on solar cell performance. Furthermore, the reduction in charge transfer resistance and the increase in short-circuit current are additional advantages of utilizing this technology. The findings of this research emphasize the high potential of gold quantum dots in advancing next-generation solar cell technology.
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