Magnetite magnetic nanoparticles (MNP) exhibit superparamagnetic behavior, which gives them important properties such as low coercive field, easy superficial modification and acceptable magnetization levels. This makes them useful in separation techniques. However, few studies have experimented with the interactions of MNP with magnetic fields. Therefore, the aim of this research was to study the influence of an oscillating magnetic field (OMF) on polymeric monolithic columns with vinylated magnetic nanoparticles (VMNP) for capillary liquid chromatography (cLC). For this purpose, MNP were synthesized by coprecipitation of iron salts. The preparation of polymeric monolithic columns was performed by copolymerization and aggregation of VMNP. Taking advantage of the magnetic properties of MNP, the influence of parameters such as resonance frequency, intensity and exposure time of a OMF applied to the synthesized columns was studied. As a result, a better separation of a sample according to the measured parameters was obtained, so that a column resolution (R_s) of 1.35 was achieved. The morphological properties of the columns were evaluated by scanning electron microscopy (SEM). The results of the chromatographic properties revealed that the best separation of the alkylbenzenes sample occurs under conditions of 5.5 kHz and 10 min of exposure in the OMF. This study constitutes a first application in chromatographic separation techniques for future research in nanotechnology.

Shore line change is considered as one of the most dynamic processes, which were mapped along the coast of Tiruvallur district by using topographic maps of 1976 and multi-temporal satellite images. The satellite images pertaining to 1988, 1991, 2006, 2010, 2013 and 2016 were used to extract the shorelines. It is important to map and monitor the HTL (High Tide Line) at frequent time intervals as the shoreline was demarcated by using visual interpretation technique from satellite images and topographic maps. Followed by this, an overlay analysis was performed to calculate areas of erosion and accretion in the study area. The results revealed that the coast of Tiruvallur district lost 603 ha and gained 630 ha due to erosion and accretion respectively. It was confirmed after the ground truth survey carried out in the study area. The high accretion of 178 ha was found nearby Pulicat Lake and low accretion of 19 ha was seen between Pulicat Lake and Kattupali Port. The high erosion area was found along the Pulicat Lake, Kattupali and Ennore ports, and Ennore creek mouth and southern Ennore such as Periya Kuppam, Chinna Kuppam, Kasi Koil Kuppam, and Thyagarajapuram. It may be concluded that the coastal erosion and accretion in the study area were mainly caused by anthropogenic and natural factors, which altered the coastal environment.