In this study, the effect of roasting and boiling on the yield and oxidative stability of soya bean oil was investigated. The oil was soxhlet extracted and the oxidative stability was determined by the free fatty acid value, acid value and peroxide value. The results showed that the oil yield, free fatty acid value, acid value and peroxide value were significantly affected by roasting, boiling, and the thermal treatment time. The percentage oil yield in the control oil sample was 18.51%, which increased to 20.24% and 20.73% after boiling and roasting respectively, at 40mins. The corresponding free fatty acid and the peroxide value of the control oil sample were 0.14% and 2.04 meqO2/kg, which increased to 0.82% and 6.60 meqO2/kg by roasting, and 0.47% and 5.62 meqO2/kg by boiling respectively. Thus the oil yield, free fatty acid value, peroxide value, and acid value increased with increasing roasting and boiling time.
The results indicate that roasting provides a higher oil yield than boiling, but boiled oil has higher oxidative stability than roasted oil.
Potassium dihydrogen phosphate, KH2PO4 (KDP) crystal is an excellent electro-optical nonlinear optical crystal with large electro-optical nonlinear coefficient, high laser damage threshold, and laser frequency doubling effect, electro-optical effect , Piezoelectric effects and other special features, widely used in inertial confinement fusion engineering (ICF) and electro-optical switching devices. Therefore, its growth mechanism, growth process and performance have been systematically studied. In the process of KDP crystal growth, it is found that the stability of the growth solution is an important factor affecting the quality of crystal growth. Therefore, in recent years, more and more research on the stability of the solution, such as the study of ph, doping, supersaturation, overheating time on the stability of the solution. Among them, the research on the doping is mostly reported, and the research on this aspect is mainly focused on two aspects. On the one hand, it is the study of the stability of the solution under doping, and the other is the effect of doping on the optical quality of the crystal. In fact, the stability of the growth solution and the quality of crystal growth is directly related to the quality, but the existing research to isolate the two researches. Therefore, the experiment will be carried out in the case of double-doped KDP solution stability, KDP crystal growth and crystal optical quality and other experiments, and in-depth analysis of the impact of solution stability and crystal optical quality of the reasons, while the solution stability and The relationship between the optical quality of the crystal is briefly analyzed.
Polymer waste drilling fluid has extremely high stability, and it is difficult to separate solid from liquid, which has become a key bottleneck problem restricting its resource recycling. This study aims to reveal the stability mechanism of polymer waste drilling fluid and explore the destabilization effect and mechanism of ultrasonic waste drilling fluid. Surface analysis techniques such as X-ray energy spectrum and infrared spectrum were used in combination with colloidal chemical methods to study the spatial molecular structure, stability mechanism, and ultrasonic destabilization mechanism of drilling fluid. The results show that the particles in the drilling fluid exist in two forms: uncoated particles and particles coated by polymers, forming a high molecular stable particle system. Among them, rock particles not coated by polymer follow the vacancy stability and Derjaguin-Landau-Verwey-Overbeek (DLVO) stability mechanism, and the weighting material coated by the polymer surface follows the space stability and DLVO stability mechanism. The results of ultrasonic destabilization experiments show that after ultrasonic treatment at 1000 W power for 5 min, coupled with the addition of 0.02% cationic polyacrylamide, the dehydration rate is as high as 81.0%, and the moisture content of the mud cake is as low as 29.3%, achieving an excellent solid-liquid separation effect. Ultrasound destabilizes polymer waste drilling fluid by destroying the long-chain structure of the polymer. This study provides theoretical support and research direction for the research and development of polymer waste drilling fluid destabilization technology.
Synthetic membranes play a crucial role in a wide range of separation processes, including dialysis, electrodialysis, ultrafiltration, and pervaporation, with growing interest in synthetic emulsion membranes due to their precision, versatility, and ion exchange capabilities. These membranes enable tailored solutions for specific applications, such as water and gas separation, wastewater treatment, and chemical purification, by leveraging their multi-layered structures and customizable properties. Emulsion membrane technology, particularly in pressure-driven methods like reverse osmosis (RO) and nanofiltration (NF), has shown great potential in overcoming traditional challenges, such as fouling and energy inefficiency, by improving filtration efficiency and selectivity. This review explores the latest advancements in emulsion membrane development, their adaptability to various industrial needs, and their contribution to addressing long-standing limitations in membrane separation technologies. The findings underscore the promise of emulsion membranes in advancing industrial processes and highlight their potential for broader applications in water treatment, environmental management, and other key sectors.
The Middle East and North Africa (MENA) region faces unique challenges and opportunities in integrating sustainability into sovereign credit assessments. This research study examines environmental, social, and governance (ESG) factors embedded in the lending policies of jurisdictional institutions in MENA. By analyzing existing literature and case studies, we identify key drivers and barriers to ESG integration in sovereign lending. Our findings suggest a growing recognition of sustainability’s importance in financial stability and credit, driven by global climate guarantees and local socio-economic development. However, challenges such as data availability, regulatory frameworks, and market acceptance persist. This paper provides an overview of current practices, highlights best practices, and offers recommendations to enhance ESG integration in sovereign debt reviews in the MENA region. The study concludes that a robust ESG framework is necessary to accurately reflect the long-term risks and opportunities associated with sovereign debt, ultimately contributing to sustainable economic growth regionally.
In the present work, a series of butyl methacrylate/1-hexene copolymers were synthesized, and their efficiency as viscosity index improvers, pour point depressants, and shear stabilizers of lube oil was investigated. The effect of 1-hexene molar ratio, type, and concentration of Lewis acids on the incorporation of 1-hexene into the copolymer backbone was investigated. The successful synthesis of the copolymers was confirmed through FTIR and 1H NMR spectroscopy. Results obtained from quantitative 1H NMR and GPC revealed that an increase in the molar ratio of 1-hexene to butyl methacrylate, along with concentration of Lewis acids led to an increase in 1-hexene incorporation and a reduction in Mn and Ð. Similar trends were observed when the Lewis acid changed from AlCl3 to organometallic acids. The maximum 1-hexene incorporation (26.4%) was achieved for sample BHY3, with a [1-hexene/BMA] ratio of 4 mol% and a [Yb(OTf)3/BMA] ratio of 2.5 mol%. Evaluation of the synthesized copolymers as lube oil additives demonstrated that the viscosity index was more significantly influenced by samples with higher molecular weight. Sample BHA13 represents maximum VI of 137. The copolymer containing Yb(OTf)3 as a catalyst exhibited superior efficiency as a pour point depressant. Furthermore, sample BHY3 showed the lowest shear stability index (6.4).
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