In this review are developed insights from the current research work to develop the concept of functional materials. This is understood as real modified substrates for varied applications. So, functional and modified substrates focused on nanoarchitectures, microcapsules, and devices for new nanotechnologies highlighting life sciences applications were revised. In this context, different types of concepts to proofs of concepts of new materials are shown to develop desired functions. Thus, it was shown that varied chemicals, emitters, pharmacophores, and controlled nano-chemistry were used for the design of nanoplatforms to further increase the sizes of materials. In this regard, the prototyping of materials was discussed, affording how to afford the challenge in the design and fabrication of new materials. Thus, the concept of optical active materials and the generation of a targeted signal through the substrate were developed. Moreover, advanced concepts were introduced, such as the multimodal energy approach by tuning optical coupling from molecules to the nanoscale within complex matter composites. These approaches were based on the confinement of specific optical matter, considering molecular spectroscopics and nano-optics, from where the new concept nominated as metamaterials was generated. In this manner, fundamental and applied research by the design of hierarchical bottom-up materials, controlling molecules towards nanoplatforms and modified substrates, was proposed. Therefore, varied accurate length scales and dimensions were controlled. Finally, it showed proofs of concepts and applications of implantable, portable, and wearable devices from cutting-edge knowledge to the next generation of devices and miniaturized instrumentation.
This study focused on the formulation and characterization of silver nanoparticles (AgNP) functionalized with d-limonene. The nanoparticles were functionalized by phase inversion and the synthesis of the nanoparticles was performed in situ; particle size was determined by laser diffraction, zeta potential and optical colloidal stability using Multiscan 20 for a period of 24 hours at 37 °C; the minimum inhibitory concentration (MIC) and minimum bactericidal concentration (MBC) of the formulated material on Escherichia coli ATCC 25922, Staphylococcus aureus ATCC 29213, Klebsiella oxytoca ATCC 700324, Enterococcus casseliflavus ATCC 700327, Escherichia coli BLEE, carbapenem-resistant Pseudomona aeruginosa were determined. The nanoparticles showed colloidal stability at a d-limonene concentration of 3.93%, silver ions at 1.61 × 10−3%, non-ionic adjuvant at 24% and ascorbic acid at 5.88%; citric acid/citrate (1:1) 0.48M for a pH of 4.5 was used as a buffer system. The formulation was classified as a polydisperse system (PD = 0.0851), with a zeta potential of −11.6 mV and average particle size of 81.5 ± 0.9 nm. A particle migration velocity of −0.199 ± 0.006 mm∙h−1, a constant transmission profile and backscattering profile with variations of 10% were evidenced, which represents a stable formulation. The nanoparticles presented an MIC and an MBC of 28 μg∙mL−1 (5.6 × 10−2% d-limonene and 4.7 × 10−5% AgNP) against all tested bacteria.
The ways of developing functional textiles based on nanomaterials were introduced, and the latest research achievements of nanomaterials in such aspects as flame retardancy, antibacterial, super-hydrophobic, self-cleaning, UV resistance, and anti-static textiles were reviewed. The main technical obstacles to the large-scale application of nanomaterials in functional textiles were pointed out, the possible solutions were discussed, and the development of functional textiles by nanomaterials has been prospected.
The world has complex mega-cities and interdependent infrastructures. This complication in infrastructure relations makes it sensitive to disasters and failures. Cascading failure causes blackouts for the whole system of infrastructures during disasters and the lack of performance of the emergency management stakeholders is clear during a disaster due to the complexity of the system. This research aimed to develop a new concurrent engineering model following the total recovery effort. The objectives of this research were to identify the clustered intervention utilized in the field of resilience and developing a cross-functional intervention network to enhance the resilience of societies during a disaster. Content analysis was employed to classify and categorize the intervention in the main divisions and sub-divisions and the grouping of stakeholders. The transposing system was employed to develop an integrated model. The result of this research showed that the operations division achieved the highest weight of information interchange during the response to improve the resilience of the system. The committee of logistics and the committee of rescue and relief needed the widest bandwidth of information flow in the concurrent engineering (CE) model. The contributed CE model helped the stakeholders provide a resilient response system. The final model and the relative share value of exchanging information for each workgroup can speed up recovery actions. This research found that concurrent engineering (CE) is a viable concept to be implemented as a strategy for emergency management. The result of this research can help policymakers achieve a collaborative teamwork environment and to improve resilience factors during emergency circumstances for critical infrastructures.
The electro-magnetic (EM) waves transmitted through a thin object with fine structures are observed by a microsphere located above the thin object. The EM radiation transmitted through the object produces both evanescent waves, which include information on the fine structures of the object (smaller than a wavelength), and propagating waves, which include the large image of the object (with dimensions larger than a wavelength). The super-resolutions are calculated by using the Helmholtz equation. According to this equation, evanescent waves have an imaginary component of the wavevector in the z direction, leading the components of the wavevector in the transversal directions to become very large so that the fine structures of the object can be observed. Due to the decay of the evanescent waves, only a small region near the contact point between the thin object and the microsphere is effective for producing the super resolution effects. The image with super-resolution can be increased by a movement of the microsphere over the object or by using arrays of microspheres. Both propagating and evanescent waves arrive at the inner surface of the microsphere. A coupling between the transmitted EM waves and resonances produced in the dielectric sphere, possibly obtained by the Mie method, leads to a product of the EM distribution function with the transfer function. While this transfer function might be calculated by the Mie method, it is also possible to use it as an experimental function. By Fourier transform of the above product, we get convolution between the EM spatial modes and those of the transfer function arriving at the nano-jet, which leads the evanescent waves to become propagating waves with effective very small wavelengths and thus increase the resolution.
Copyright © by EnPress Publisher. All rights reserved.