A metakaolin-based geopolymer was fabricated with 5 ratios of two different nanomaterials. On the one hand, silicon carbide nanowhiskers and, on the other hand, titanium dioxide nanoparticles. Both were placed in water and received ultrasonic energy to be dispersed. The effects on mechanical properties and reaction kinetics were analyzed. Compared to the reference matrix, the results showed a tendency to increase the flexural strength. Probably due to the geometry of the SiC nanowhiskers and the pore refinement by the nano-TiO₂ particles. The calorimetry curves showed that incorporating TiO₂ nanoparticles resulted in a 92% reduction in total heat, while SiC nanowhiskers produced a 25% reduction in total heat.

Root turnover is a key process of terrestrial ecosystem carbon cycle, which is of great significance to the study of soil carbon pool changes and global climate change. However, because there are many measurement and calculation methods of root turnover, the results obtained by different methods are quite different, and the current research on root turnover of forest ecosystem on the global regional scale is not sufficient, so the change law of root turnover of global forest ecosystem is still unclear. By collecting literature data and unifying the calculation method of turnover rate, this study integrates the spatial pattern of fine root turnover of five forest types in the world, and obtains the factors affecting fine root turnover of forest ecosystem in combination with soil physical and chemical properties and climate data. The results showed that there were significant differences in fine root turnover rate among different forest types, and it gradually decreased with the increase of latitude; the turnover rate of fine roots in forest ecosystem is positively correlated with annual average temperature and annual average precipitation; fine root turnover rate of forest ecosystem is positively correlated with soil organic carbon content, but negatively correlated with soil pH value. This study provides a scientific basis for revealing the law and mechanism of fine root turnover in forest ecosystem.

Tropical dry forests are complex and fragile ecosystems with high anthropogenic intervention and restricted reproductive cycles. They harbor unique richness, structural, physiological and phenological diversity. This research was carried out in the upper Magdalena valley, in four forest fragments with different successional stages. In each fragment, four permanent plots of 0.25 ha were established and the light habitat associated with species richness, relative abundance and rarity was evaluated, as well as the forest dynamics that included mortality, recruitment and diameter growth for a period of 5.25 years. In mature riparian forest, species richness was found to be higher than that reported in other studies for similar areas in the Cauca Valley and the Atlantic coast. Values of species richness, heterogeneity and rarity are higher than those found in drier areas of Tolima. Forest structure, diversity and dynamics were correlated with light habitat, showing differences in canopy architecture and its role in the capture and absorption of radiation. The utilization rate of photosynthetic effective radiation in the forest underlayer with high canopy density is low, which is related to the low species richness, while the underlayer under light is more abundant and heterogeneous.

The study examined the socio-demographic factors affecting access to and utilization of social welfare services in Yenagoa Local Government Area of Bayelsa State, Nigeria. Quantitative and qualitative approaches were adopted to select 570 respondents from the study area. Probability and non-probability sampling techniques were adopted in the selection of communities, and respondents. The quantitative data were analyzed using frequency distribution tables and percentages, while chi-square statistic was used to determine the relationship between socio-demographic variables and access to and utilization of social welfare services. The qualitative data were analyzed in themes as a complement to the quantitative data. This study reveals that although all the respondents reported knowing available social welfare services, 44.3% reported not having access to existing social services due to factors connected to serendipity variables, such as terrain condition, ethnicity and knowing someone in government. Therefore, the study recommends that the government and other stakeholders should push for the massive delivery of much-needed social welfare services to address the issue of welfare service deficit across the nation, irrespective of the ethnic group and whether the community is connected to the government of the day or not, primarily in rural areas.

Surface-enhanced Raman scattering (SERS) spectrum has the characteristics of fast-detection, high-sensitivity and low-requirements for sample pretreatment. It plays a more and more important role in the detection of organic pollutants. In this study, MIL-101 and Au nanoparticles were prepared by hydrothermal method and aqueous solution reduction method respectively, and MIL-101/Au composite nanoparticles were prepared by electrostatic interaction. The SERS properties of the composite substrate were optimized by adjusting the size of Au nanoparticles and the surface distribution density of MIL-101 nanoparticles. The detection limit of Rhodamine 6G (R6G) for the composite substrate with the optimal ratio was investigated, which was as low as 10^–11 M. It is proved that MIL-101/Au composite nanoparticles have high sensitivity to probe molecules. When they are applied to the detection of persistent organic pollutants, the detection limit for fluoranthene can reach 10^–9 M and for 3,3’,4,4’-tetrachlorobiphenyl (PCB-77) can reach 10^–5 M.

Based on the population change data of 2005–2009, 2010–2014, 2015–2019 and 2005–2019, the shrinking cities in Northeast China are determined to analyze their spatial distribution pattern. And the influencing factors and effects of shrinking cities in Northeast China are explored by using multiple linear regression method and random forest regression method. The results show that: 1) In space, the shrinking cities in Northeast China are mainly distributed in the “land edge” areas represented by Changbai Mountain, Sanjiang Plain, Xiaoxing’an Mountain and Daxing’an Mountain. In terms of time, the contraction center shows an obvious trend of moving northward, while the opposite expansion center shows a trend of moving southward, and the shrinking cities gather further; 2) in the study of influencing factors, the results of multiple linear regression and random forest regression show that socio-economic factors play a major role in the formation of shrinking cities; 3) the precision of random forest regression is higher than that of multiple linear regression. The results show that per capita GDP has the greatest impact on the contraction intensity, followed by the unemployment rate, science and education expenses and the average wage of on-the-job workers. Among the four influencing factors, only the unemployment rate promotes the contraction, and the other three influencing factors inhibit the formation of shrinking cities to various degrees.