In order to explore the influence of the ferroelectric surface on the structure and properties of semiconductor oxides, the growth of CdS nanocrystals was regulated and controlled by taking single-crystal perovskite PbTiO3 nanosheets as the substrate through a simple hydrothermal method. Through composition design, a series of PbTiO3-CdS nanocomposite materials with different loading concentrations were prepared, and their microstructure and photocatalytic properties were systematically analyzed. Studies show that in the prepared product, CdS nanoparticles selectively grow on the surfaces of PbTiO3 nanosheets, and their morphology is affected by the exposed surfaces of PbTiO3 nanosheets. There is a clear interface between the PbTiO3 substrate and CdS nanoparticles. The concentration of the initial reactant and the time of hydrothermal reaction also significantly affect the crystal morphology of CdS. Photocatalysis studies have shown that the prepared PbTiO3-CdS nanocomposite material has a significant degradation effect on 10 mg/L of Rhodamine B aqueous solution. The degradation efficiency rises with the increase of CdS loading concentration. When degrading 10 mg/L Rhodamine B aqueous solution, the PbTiO3-CdS sample with a mass fraction of 3% can reach a degradation rate of 72% within 120 min.
Municipal authorities in industrialized and in developing countries face unceasingly the issues of congestion, insufficiency of transport means capacity, poor operability of transport systems and a growing demand for reliable and effective urban transport. While the expansion of infrastructure is generally considered as an undesirable option, in specific cases, when short links or ring roads are missing, new infrastructure projects may provide beneficial solutions. The upgrading and renewal of existing networks is always a challenge to the development of a modern city and the welfare of citizens. Central governance and management of transport systems, the establishment of smart and digital infrastructure, advanced surveillance and traffic monitoring, and intra-city energy-harvesting policy are some of the steps to be taken during the transition to a green and sustainable urban future.
Municipal authorities have also to consider other options and strategies to create a citizen-friendly setting for mobility: diminish the need for trips (digitalization of services, e-commerce, etc.), shift from private to public transport and transform the urban form to promote non-motorized transport in favor of the natural environment and public health. A citizen-friendly policy based on the anticipation of future needs and technological development seems to be a requisite for European cities searching for a smooth integration of their networks into urban space.
This paper presents the state of displacement of a multilayered composite laminate subjected to transverse static load with varying balance, symmetric and anti-symmetric angle-ply and cross-ply staking sequences. Higher-order shear deformation theory (HSDT) is considered in the finite element formulation of nine-noded isoparametric element with seven degrees of freedom at each node. The finite element formulation is transformed into computer codes. A convergence study is carried out first to obtain the optimal mesh size for minimizing the computational time. The maximum deflection at the center of plate for both fixed and simply supported edges is verified with reported literature and a good conformity is found. An attempt has been made to observe the minimum value of maximum deflection in the laminate for attaining the maximum strength of laminate with a suitable combination of stacking sequences with a constant volume of material.
This paper qualitatively analyzes the connotation of woodland welfare and the changes of woodland welfare that may be caused by the transfer of the right to use, and interprets the welfare improvement caused by the transfer of the right to use of woodland in the ideal state by using the relevant theories and models of microeconomics. Based on the prospect theory and psychological account theory of behavioral economics, this paper analyzes the reasons why the transfer of forestland use right has not been carried out on a large scale in China.
An α, α′-dipyridyl adduct of a complex compound hexaaquatribenzene-1,2,4,5-tetracarbonatotetra iron (III) with porous structure was synthesized for the first time. According to the results of elemental, X-ray, IR-spectroscopic and differential-thermal analyses the individuality, chemical formula, thermal destruction, and form of coordination of acidic anion and dipyridyl were established. During interaction of a complex compound with dipyridyl, it completely loses all crystallization molecule of water resulting in a compound with a chemical formula of Fe4(C6H2(COO)4)3(dpy)2(dipyridyl). Using the identification of diffraction pattern the parameters of lattice cell of the complex compound were determined.
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