Magnesium hydroxide/melamine phosphate borate (nano MH/MPB), a novel nano-composition intumescent flame retardant, was synthesized with the in-situ reaction method from MgCl₂·6H₂O sodium hydroxide (NaOH) and melamine phosphate borate (MPB) in the absence of H₂O. The structure of the product was confirmed by EDAX IR and XRD. The effects of reaction temperature and time on the dimension of magnesium hydroxide were observed. The effects of mass ratio of magnesium hydroxide to MPB on the flame retardancy of nano-MH/MPB/EP were examined with the limiting oxygen test. The results show that the optimal condition of synthesis of MH/MPB is m_MH/m_MPB = 0.25, reacting under 75 ℃ for 30 minutes. Finally, the mechanism for flame retardancy of nano-MH/MPB/EP was pilot studied by means of IR of char layer and TG of MH/MPB.

The problem of the synthesis of new type nanomaterials in the form of nano-coatings with sub-nanometric heterogeneity has been formulated. It has been presented an analysis of influences of physical vapor deposition in ultrahigh vacuum on the process of intermixing a film with a substrate, including the results, which has been obtained under the formation of transition metal – silicon interface. The generalization of the obtained experimental results develops an approach to the development of new nano-coatings with low-dimensional heterogeneity. The principles of constructing such low-dimensional nano-coatings, their properties and possible applications are considered. 

This study focuses on the use of the Soil and Water Assessment Tool (SWAT) model for water budgeting and resource planning in Oued Cherraa basin. The combination of hydrological models such as SWAT with reliable meteorological data makes it possible to simulate water availability and manage water resources. In this study, the SWAT model was employed to estimate hydrological parameters in the Oued Cherra basin, utilizing meteorological data (2012–2020) sourced from the Moulouya Hydraulic Basin Agency (ABHM). The hydrology of the basin is therefore represented by point data from the Tazarhine hydrological station for the 2009–2020 period. In order to optimize the accuracy of a specific model, namely SWAT-CUP, a calibration and validation process was carried out on the aforementioned model using observed flow data. The SUFI-2 algorithm was utilized in this process, with the aim of enhancing its precision. The performance of the model was then evaluated using statistical parameters, with particular attention being given to Nash-Sutcliffe efficiency (NSE) and coefficient of determination (R²). The NSE values for the study were 0.58 for calibration and 0.60 for validation, while the corresponding R² values were 0.66 and 0.63. The study examined 16 hydrological parameters for Oued Cherra, determining that evapotranspiration accounted for 89% of the annual rainfall, while surface runoff constituted only 6%. It also showed that groundwater recharge was pretty much negligible. This emphasized how important it is to manage water resources effectively. The calibrated SWAT model replicated flow patterns pretty well, which gave us some valuable insights into the water balance and availability. The study’s primary conclusions were that surface water is limited and that shallow aquifers are a really important source of water storage, especially for irrigation during droughts.

Every production day in Nigeria, and in other oil producing countries, millions of barrels of produced water is generated. Being very toxic, remediation of the produced water before discharge into environment or re-use is very essential. An eco-friendly and cost effective approach is hereby reported for remediative pre-treatment of produced water (PW) obtained from Nigerian oilfield. In this approach, Telfairia occidentalis stem extract-silver nanoparticles (TOSE-AgNPs) were synthesized, characterized and applied as bio-based adsorbent for treating the PW in situ. The nanoparticles were of average size 42.8 nm ± 5.3 nm, spherical to round shaped and mainly composed of nitrogen and oxygen as major atoms on the surface. Owing to the effect of addition of TOSE-AgNPs, the initially high levels (mg/L) of Total Dissolved Solids (TDS), Biological Oxygen Demand (BOD) and TSS of 607, 3.78 and 48.4 in the PW were reduced to 381, 1.22 and 19.6, respectively, whereas DO and COD improved from 161 and 48.4 to 276 and 19.6 respectively, most of which fell within WHO and US-EPA safe limits. Particularly, the added TOSE-AgNPs efficiently removed Pb (II) ions from the PW at temperatures between 25 ℃ to 50 ℃. Removal of TOSE-AgNPs occurred through the adsorption mechanism and was dependent contact time, temperature and dose of TOSE-AgNPs added. Optimal remediation was achieved with 0.5 g/L TOSE-AgNPs at 30 ℃ after 5 h contact time. Adsorption of Pb (Ⅱ) ions on TOSE-AgNPs was spontaneous and physical in nature with remediation efficiency of over 82% of the Pb (Ⅱ) ions in solution. Instead of discarding the stem of Telfairia occidentalis, it can be extracted and prepared into a new material and applied in the oilfield as reported here for the first time.