An α, α^′-dipyridyl adduct of a complex compound hexaaquatribenzene-1,2,4,5-tetracarbonatotetra iron (III) with porous structure was synthesized for the first time. According to the results of elemental, X-ray, IR-spectroscopic and differential-thermal analyses the individuality, chemical formula, thermal destruction, and form of coordination of acidic anion and dipyridyl were established. During interaction of a complex compound with dipyridyl, it completely loses all crystallization molecule of water resulting in a compound with a chemical formula of Fe₄(C₆H₂(COO)₄)₃(dpy)₂(dipyridyl). Using the identification of diffraction pattern the parameters of lattice cell of the complex compound were determined.

The objective of this work was to evaluate the effect of potassium concentrations applied via fertigation on the growth, yield and chemical composition of eggplant ‘Ciça’ in a distroferric red Latosol. The treatments were composed of five concentrations of K₂O (0, 36, 72, 108 and 144 kg ha^-1 supplied via fertigation), using potassium chloride as a source, divided into six applications. The irrigation system was of the drip type and irrigation management was done via a “Class A” evaporometer tank. Harvest started at 62 days after transplanting (DAT) and lasted for five months. The variables evaluated were: plant height, number of leaves, fresh fruit mass, number of fruits per plant, yield per plant, productivity and classification of the fruits according to their length and diameter. At 85 DAT, fruit were collected for characterization as to the percentage of lipids, proteins and fibers. Although the potassium fertigation in cover provided a reduction in the production and productivity, the concentrations of 36 kg ha^-1 and 72 kg ha^-1 of K₂O applied via fertigation, increased the physical-chemical characteristics of the fruits.

In the current work, it was investigated to the K X-ray fluorescence efficiency and chemical effect on vacancy transfer probability for some tin compounds. We used Br₂Tin, TinI₂, SeTin, TinF₂, TinSO₄, TinCl₂, TinO and TinS compounds for experimental study. The target samples were irradiated with ²⁴¹Am annular radioactive source at the intensity of 5 Ci which emits gamma rays at wavelength of 0.2028 nm. The characteristic x-rays emitted because of the excitation are collected by a high-resolution HPGe semiconductor detector. It has been determined that the experimental calculations of the tin (Sn) element are compatible with the theoretical calculation. In addition, we have calculated the experimental intensity ratios, fluorescence yields and total vacancy transfer probabilitiesfor other Sn compounds. 

Water splitting, the process of converting water into hydrogen and oxygen gases, has garnered significant attention as a promising avenue for sustainable energy production. One area of focus has been the development of efficient and cost-effective catalysts for water splitting. Researchers have explored catalysts based on abundant and inexpensive materials such as nickel, iron, and cobalt, which have demonstrated improved performance and stability. These catalysts show promise for large-scale implementation and offer potential for reducing the reliance on expensive and scarce materials. Another avenue of research involves photoelectrochemical (PEC) cells, which utilize solar energy to drive the water-splitting reaction. Scientists have been working on designing novel materials, including metal oxides and semiconductors, to enhance light absorption and charge separation properties. These advancements in PEC technology aim to maximize the conversion of sunlight into chemical energy. Inspired by natural photosynthesis, artificial photosynthesis approaches have also gained traction. By integrating light-absorbing materials, catalysts, and membranes, these systems aim to mimic the complex processes of natural photosynthesis and produce hydrogen fuel from water. The development of efficient and stable artificial photosynthesis systems holds promise for sustainable and clean energy production. Tandem cells, which combine multiple light-absorbing materials with different bandgaps, have emerged as a strategy to enhance the efficiency of water-splitting systems. By capturing a broader range of the solar spectrum, tandem cells optimize light absorption and improve overall system performance. Lastly, advancements in electrocatalysis have played a critical role in water splitting. Researchers have focused on developing advanced electrocatalysts with high activity, selectivity, and stability for the oxygen evolution reaction (OER) and hydrogen evolution reaction (HER). These electrocatalysts contribute to overall water-splitting efficiency and pave the way for practical implementation.

Objective: To study the growth, accumulation and soil nutrient content of each overseeded species under different interharvesting intensity treatments of Eucalyptus, and to explore the best re-cultivation method suitable for mixed overseeded species after Eucalyptus interharvesting. Methods: In Guangxi state-owned Qipo forest, Eucalyptus tailorii with different planting densities (DH32-29) were mixed with Castanopsis hystrix, Mytilaria laosensis and Michelia macclurei, and four different treatments (CK, LT, MT and HT) were established for re-cultivation of Eucalyptus near-mature forests with different logging intensities, and the differences in growth conditions and soil physicochemical properties of each species were analyzed. Results: (1) As the proportion of Eucalyptus allocation decreased, the growth of Eucalyptus diameter at breast height, tree height and individual wood volume could be promoted; the growth of the three parameters of HT and MT Eucalyptus were significantly different from LT and CK. (2) The average wood volume per plant of the set species in the CK and LT treatments was Mytilaria laosensis > Michelia macclurei > Castanopsis hystrix, while in the MT and HT treatments it was Mytilaria laosensis > Castanopsis hystrix > Michelia macclurei. (3) The differences in soil aeration, total saturated water holding capacity, capillary water holding capacity, and field water holding capacity in soil layers of different depth varied. In the same soil layer, soil aeration, total porosity and capillary porosity were HT > CK > LT > MT; saturated water holding capacity and capillary water holding capacity were HT > CK > LT > MT, while field water holding capacity was CK > HT > LT > MT. (4) Organic matter, pH, total nitrogen, total phosphorus, total potassium, fast-acting nitrogen, fast-acting phosphorus, and fast-acting potassium changed with varying soil depth in each treatment.

The growing of plants hydroponically is a soilless form of growing in modern day agriculture. It helps to make feed available for animals throughout the season since it is not affected by what is faced by field grown crops. The use of animal waste, that is, their faeces, in the growth of forage was compared with commercial hydroponics solutions as a way of looking for a reduction in the cost incurred in the purchase of commercial hydroponics solutions. The study evaluated the use of organic nutrient solutions (ONS) alongside a standard/commercial nutrient solution in growing crops hydroponically on the growth, dry matter yield, water use efficiency, and chemical composition of hydroponic maize fodder. The ONS used were formulated from the dried faeces of cattle, poultry, rabbits, and swine. The prepared organic nutrient solutions with the control were used in growing the maize seeds for 10 days, and growth, yield, and chemical composition were determined. Results show the highest (196 g) dry matter yield for maize hydroponic fodder irrigated with poultry ONS. Similarly, maize irrigated with poultry ONS was significantly (P < 0.05) higher in CP content, while it was not significantly different from maize irrigated with cattle, swine, and commercial solutions. A lower water use efficiency value (0.19 kg DM/m³) was recorded for maize irrigated with cattle ONS. According to the study, irrigating maize with different organic nutrient solutions produced maize fodder with a higher yield and a similar chemical composition as the commercial nutrient solution.